Hydration and strength development in ternary portland cement blends containing limestone and fly ash or metakaolin

2013 ◽  
Vol 39 ◽  
pp. 93-103 ◽  
Author(s):  
Kirk Vance ◽  
Matthew Aguayo ◽  
Tandre Oey ◽  
Gaurav Sant ◽  
Narayanan Neithalath
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Strength Development

scholarly journals Strength Development and Elemental Distribution of Dolomite/Fly Ash Geopolymer Composite under Elevated Temperature

Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 1015 ◽  
Author(s):  
Emy Aizat Azimi ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Petrica Vizureanu ◽  
Mohd Arif Anuar Mohd Salleh ◽  
Andrei Victor Sandu ◽  
...  
Keyword(s):  
Elevated Temperature ◽  
Fly Ash ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Raw Materials ◽  
Liquid Sodium ◽  
Strength Development ◽  
Elemental Distribution ◽  
Distribution Analysis ◽  
Geopolymer Composites

A geopolymer has been reckoned as a rising technology with huge potential for application across the globe. Dolomite refers to a material that can be used raw in producing geopolymers. Nevertheless, dolomite has slow strength development due to its low reactivity as a geopolymer. In this study, dolomite/fly ash (DFA) geopolymer composites were produced with dolomite, fly ash, sodium hydroxide, and liquid sodium silicate. A compression test was carried out on DFA geopolymers to determine the strength of the composite, while a synchrotron Micro-Xray Fluorescence (Micro-XRF) test was performed to assess the elemental distribution in the geopolymer composite. The temperature applied in this study generated promising properties of DFA geopolymers, especially in strength, which displayed increments up to 74.48 MPa as the optimum value. Heat seemed to enhance the strength development of DFA geopolymer composites. The elemental distribution analysis revealed exceptional outcomes for the composites, particularly exposure up to 400 °C, which signified the homogeneity of the DFA composites. Temperatures exceeding 400 °C accelerated the strength development, thus increasing the strength of the DFA composites. This appears to be unique because the strength of ordinary Portland Cement (OPC) and other geopolymers composed of other raw materials is typically either maintained or decreases due to increased heat.

scholarly journals A Step by Step Methodology for Building Sustainable Cementitious Matrices

2020 ◽  
Vol 10 (8) ◽  
pp. 2955 ◽  
Author(s):  
Styliani Papatzani ◽  
Kevin Paine
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Silica Fume ◽  
Carbon Footprint ◽  
State Of The Art ◽  
Cost Effective ◽  
Strength Development ◽  
Low Carbon ◽  
Current State ◽  
First Time

In an effort to produce cost-effective and environmentally friendly cementitious binders. mainly ternary (Portland cement + limestone + pozzolanas) formulations have been investigated so far. Various proportions of constituents have been suggested, all, however, employing typical Portland cement (PC) substitution rates, as prescribed by the current codes. With the current paper a step by step methodology on developing low carbon footprint binary, ternary and quaternary cementitious binders is presented (PC replacement up to 57%). Best performing binary (60% PC and 40% LS (limestone)) and ternary formulations (60% PC, 20% LS, 20% FA (fly ash) or 43% PC, 20% LS 37% FA) were selected on the grounds of sustainability and strength development and were further optimized with the addition of silica fume. For the first time a protocol for successfully selecting and testing binders was discussed and the combined effect of highly pozzolanic constituents in low PC content formulations was assessed and a number of successful matrices were recommended. The present paper enriched the current state of the art in composite low carbon footprint cementitious binders and can serve as a basis for further enhancements by other researchers in the field.

scholarly journals Effects of Mixing and Curing Temperature on the Strength Development and Pore Structure of Fly Ash Blended Mass Concrete

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Ki-Bong Park ◽  
Takafumi Noguchi
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Pore Structure ◽  
Weather Conditions ◽  
Strength Loss ◽  
Curing Temperature ◽  
Strength Development ◽  
Mass Concrete ◽  
Term Strength

The aim of this work is to know clearly the effects of temperature in response to curing condition, hydration heat, and outside weather conditions on the strength development of high-performance concrete. The concrete walls were designed using three different sizes and three different types of concrete. The experiments were conducted under typical summer and winter weather conditions. Temperature histories at different locations in the walls were recorded and the strength developments of concrete at those locations were measured. The main factors investigated that influence the strength developments of the obtained samples were the bound water contents, the hydration products, and the pore structure. Testing results indicated that the elevated summer temperatures did not affect the early-age strength gain of concrete made using ordinary Portland cement. Strength development was significantly increased at early ages in concrete made using belite-rich Portland cement or with the addition of fly ash. The elevated temperatures resulted in a long-term strength loss in both belite-rich and fly ash containing concrete. The long-term strength loss was caused by a reduction in the degree of hydration and an increase in the total porosity and amount of smaller pores in the material.

Performances of Belite-Rich Cement Concrete with Fly Ash and Phosphorous Slag Powder

2012 ◽  
Vol 174-177 ◽  
pp. 1502-1506
Author(s):  
Hua Shan Yang ◽  
Sheng Jin Tu ◽  
Yin Long Jin ◽  
Wang Tao
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Outdoor Exposure ◽  
Hydration Heat ◽  
Strength Development ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Slag Powder ◽  
Exposure Site ◽  
Phosphorous Slag

This paper presents the results of laboratory and outdoor exposure site studies on belite-rich cement concrete with phosphorous slag powder and fly ash. The parameters studied included strength, hydration heat, ultimate elongation, Young’s modulus, and adiabatic in temperature. The experimental results showed that belite-rich cement resulted in a higher rate of strength development of mortar and concrete at later ages when compared with that of moderate-heat Portland cement. And the hydration heat of belite-rich cement is lower than that of reference. This is due to the different phase composition of the two cements. Belite-rich cement contains less C3S but more C2S than moderate-heat Portland cement. In addition, belite-rich cement concrete with phosphorous slag powder and fly ash exhibited better performances than those of moderate-heat Portland cement concrete.

scholarly journals Influences of Waste Concrete Powder on the Strength Development and Hydration Products of Mortar Containing Fly Ash

2021 ◽  
Author(s):  
Huashan YANG ◽  
Yujun CHE
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Cement Mortar ◽  
Setting Time ◽  
Flow Index ◽  
Strength Development ◽  
Test Results ◽  
Hydration Products ◽  
Waste Concrete ◽  
Time Flow

During recycling waste concrete, a large amount of waste concrete powder (WCP) is generated. However, efficient utilization of WCP remains an unresolved issue. This paper investigates the influences of WCP on the properties and hydration products of cement mortar containing fly ash (FA). This study used two different types of WCPs. One was made from an ordinary Portland cement mortar, and the other was derived from a Portland cement mortar. WCP replaced 10%, 20%, and 30% of FA. The water requirement, setting time, flow index, strength, hydration products, and microstructure of FA mortar incorporating WCP were investigated. Test results indicate that the WCP has no significant influence on the performances and hydration products of FA mortar. By adequately combining WCP and FA, the FA mortar with required performances could be reached.

scholarly journals Effect of Bogue Potential Phases of Clinker on the Mechanical Strength of Fly ash-Limestone Based Portland Composite Cement

2021 ◽  
Vol 2 (2) ◽  
pp. 1-6
Author(s):  
B N Mohapatra
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Natural Resources ◽  
Mechanical Strength ◽  
Cementitious Materials ◽  
Strength Development ◽  
Blended Cements ◽  
Current Production ◽  
Increasing Demand

Continuous rise in population coupled with infrastructural requirements leads to increasing demand of cement which is projected to be around 4.8 billion tons by 2030 and 6.0 billion tons annually by 2050 from current production level of more than 4.2 billion tons [1], and this further requires judicious use of natural resources, particularly limestone on one side and to mitigate carbon and energy footprints on other for sustainable development. Therefore, to bring down environmental impact during cement production, cement industries have been engaged over the years to substitute Portland cement with alternative cementitious materials; fly ash, granulated blast furnace slag, limestone etc individually or in combination of two-three mineral constituents in the manufacture of blended cements, which showed better durability characteristics in comparison to ordinary Portland cement. The formulation and commercialisation of these cements largely depends on the quality of Portland clinkers in terms of oxide constituents, potential as well as actual phase composition, morphology and granulometry of alite and belite grains, along with availability and quality of the cementing materials, prevalent standard norms and regulations. In view of above, present paper highlights the effect of different clinkers in terms of potential minerals as per Bogue calculations (CL-1:C3S-48.20%, C3A-6.30%; CL-2:C3S-54.20%, C3A-9.30% and CL-3: C3S-60.05%, C3A-9.0%) on mechanical strength of fly ash-limestone based ternary cement blends, Portland composite cements, similar to CEM-II/A, B-M as per EN-197-1, prepared with 15, 20, 25, 30 and 35% by weight fly ash and 5 & 10% by weight limestone, by inter-grinding of all cement constituents process, maintaining Blaine’s fineness at 370±10m2/kg, and the results of compressive strength at different curing ages showed optimum strength development in case of clinker CL-2 with potential phases, C3S-54.20% and C3A-9.30%, thus leading to better management of natural resources and extended mine life.

scholarly journals Strength Development and Strain Localization Behavior of Cemented Paste Backfills Using Portland Cement and Fly Ash

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3282 ◽  
Author(s):  
Zhao ◽  
Taheri ◽  
Soltani ◽  
Karakus ◽  
Deng
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Strain Localization ◽  
Image Correlation ◽  
Lateral Strain ◽  
Strength Development ◽  
Curing Time ◽  
Failure Patterns ◽  
Curing Period ◽  
Dic Technique

This study examines the combined performance of Portland cement (PC), the binder, and fly ash (FA), the additive, towards improving the mechanical performance of the South Australian copper-gold underground mine cemented paste backfill (CPB) system. A series of unconfined compressive strength (UCS) tests were carried out on various mix designs to evaluate the effects of binder and/or additive contents, as well as curing time, on the CPB’s strength, stiffness and toughness. Moreover, the failure patterns of the tested samples were investigated by means of the three-dimensional digital image correlation (DIC) technique. Making use of several virtual extensometers, the state of axial and lateral strain localization was also investigated in the pre- and post-peak regimes. The greater the PC content and/or the longer the curing period, the higher the developed strength, stiffness and toughness. The use of FA alongside PC led to further strength and stiffness improvements by way of inducing secondary pozzolanic reactions. Common strength criteria for CPBs were considered to assess the applicability of the tested mix designs; with regards to stope stability, 4% PC + 3% FA was found to satisfy the minimum 700 kPa threshold, and thus was deemed as the optimum choice. As opposed to external measurement devices, the DIC technique was found to provide strain measurements free from bedding errors. The developed field of axial and lateral strains indicated that strain localization initiates in the pre-peak regime at around 80% of the UCS. The greater the PC (or PC + FA) content, and more importantly the longer the curing period, the closer the axial stress level required to initiate localization to the UCS, thus emulating the failure mechanism of quasi-brittle materials such as rock and concrete. Finally, with an increase in curing time, the difference between strain values at the localized and non-localized zones became less significant in the pre-peak regime and more pronounced in the post-peak regime.

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