Reactions of OH and OD Radicals with Ethanethiol and Diethylsulfide: Branching Ratio and Vibrational Energy Disposal for the Product Water Molecules

2021 ◽  
pp. 111404
Author(s):  
Nadehzda I. Butkovskaya ◽  
Donald W. Setser
Keyword(s):  
Vibrational Energy ◽  
Branching Ratio ◽  
Water Molecules ◽  
Product Water

Ion Association in Aqueous Solutions Probed through Vibrational Energy Transfers among Cation, Anion, and Water Molecules

2012 ◽  
Vol 117 (16) ◽  
pp. 4274-4283 ◽  
Author(s):  
Jiebo Li ◽  
Hongtao Bian ◽  
Hailong Chen ◽  
Xiewen Wen ◽  
Bryan T. Hoang ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Vibrational Energy ◽  
Ion Association ◽  
Water Molecules ◽  
Energy Transfers

scholarly journals Solvation of Potassium 5-Hydroxy Pentanoyl Trifluoroborate Salt in Aqueous Environment by Using FT-Raman and UV-Visible Spectra

2021 ◽  
Vol 12 (2) ◽  
pp. 2196-2215
Keyword(s):  
Aqueous Solution ◽  
Dipole Moment ◽  
Raman Spectra ◽  
Vibrational Energy ◽  
Basis Set ◽  
Water Molecules ◽  
Aqueous Environment ◽  
Solvation Energies ◽  
Visible Spectra ◽  
Ft Raman

The hydration process of potassium 5-hydroxypentanoyltrifluoroborate salt, K[C5H9BF3O2] and its 5-hydroxypentanoyltrifluoroborate [C5H9BF3O2]- anion have been studied by combining the experimental FT-Raman and ultraviolet-visible spectra in aqueous solution with hybrid B3LYP/6-311++G** calculations. Solvent effects have been considered with the self-consistent reaction field (SCRF) and solvation (SM) models. Here, the structures of [C5H9BF3O2].[H2O]n clusters of anion, with n from 1 to 5 implicit water molecules, were proposed in order to study the number of water molecules that could hydrate the anion. Calculations were performed in the gas phase and an aqueous solution to observe the effect of the medium on the dipole moment and volume values. Calculated solvation energies for all clusters were corrected by zero-point vibrational energy (ZPVE), non-electrostatic terms and by basis set superposition energy (BSSE). The dipole moment of salt in solution (10.19 D) suggests that the number of water molecules that could hydrate the anion vary between 3 and 4, in total agreement with the observed and predicted bands in the UV-Vis spectra for the salt and these two clusters in water between 180 and 400 nm. Comparisons among experimental and predicted Raman spectra show clearly the hydration effect because the bands attributed to OH, BF3 and C=O groups are shifted in solution, while, the predicted Raman spectra for all clusters in solution show strong changes in the intensities of many bands, in accordance with the corresponding experimental one. Evidently, the hydration occurs on the OH, BF3 and C=O groups.

Simply supported FPEDs connected by springs for broadband energy harvesting

2020 ◽  
Vol 64 (1-4) ◽  
pp. 201-210
Author(s):  
Yoshikazu Tanaka ◽  
Satoru Odake ◽  
Jun Miyake ◽  
Hidemi Mutsuda ◽  
Atanas A. Popov ◽  
...  
Keyword(s):  
Energy Harvesting ◽  
Evaluation Method ◽  
Energy Harvester ◽  
Vibrational Energy ◽  
Functional Materials ◽  
Vibration Energy ◽  
Theoretical Evaluation ◽  
Vibration Energy Harvester ◽  
Polyvinylidene Difluoride ◽  
Simply Supported

Energy harvesting methods that use functional materials have attracted interest because they can take advantage of an abundant but underutilized energy source. Most vibration energy harvester designs operate most effectively around their resonant frequency. However, in practice, the frequency band for ambient vibrational energy is typically broad. The development of technologies for broadband energy harvesting is therefore desirable. The authors previously proposed an energy harvester, called a flexible piezoelectric device (FPED), that consists of a piezoelectric film (polyvinylidene difluoride) and a soft material, such as silicon rubber or polyethylene terephthalate. The authors also proposed a system based on FPEDs for broadband energy harvesting. The system consisted of cantilevered FPEDs, with each FPED connected via a spring. Simply supported FPEDs also have potential for broadband energy harvesting, and here, a theoretical evaluation method is proposed for such a system. Experiments are conducted to validate the derived model.

Utilization of electrical charges in the pores of tofu waste for hydrogen production in water

2020 ◽  
pp. 124-135
Author(s):  
I. N. G. Wardana ◽  
N. Willy Satrio
Keyword(s):  
Magnetic Field ◽  
Hydrogen Production ◽  
Sodium Bicarbonate ◽  
Positive Charge ◽  
Electrical Energy ◽  
Hydrogen Sensor ◽  
Water Molecules ◽  
Partial Charge ◽  
Delocalized Electron ◽  
Water Hydrogen

Tofu is main food in Indonesia and its waste generally pollutes the waters. This study aims to change the waste into energy by utilizing the electric charge in the pores of tofu waste to produce hydrogen in water. The tofu pore is negatively charged and the surface surrounding the pore has a positive charge. The positive and negative electric charges stretch water molecules that have a partial charge. With the addition of a 12V electrical energy during electrolysis, water breaks down into hydrogen. The test was conducted on pre-treated tofu waste suspension using oxalic acid. The hydrogen concentration was measured by a MQ-8 hydrogen sensor. The result shows that the addition of turmeric together with sodium bicarbonate to tofu waste in water, hydrogen production increased more than four times. This is due to the fact that magnetic field generated by delocalized electron in aromatic ring in turmeric energizes all electrons in the pores of tofu waste, in the sodium bicarbonate, and in water that boosts hydrogen production. At the same time the stronger partial charge in natrium bicarbonate shields the hydrogen proton from strong attraction of tofu pores. These two combined effect are very powerful for larger hydrogen production in water by tofu waste.

PEMANFAATAN GLISERIN DARI RESIDU GLISERIN SEBAGAI PLASTICIZER UNTUK PEMBUATAN BIOPLASTIK DENGAN BAHAN BAKU PATI BONGGOL PISANG KEPOK

2017 ◽  
Vol 5 (4) ◽  
pp. 26-32 ◽  
Author(s):  
Azaria Robiana ◽  
M. Yashin Nahar ◽  
Hamidah Harahap
Keyword(s):  
Tensile Strength ◽  
Hydrogen Bonding ◽  
Fatty Acid ◽  
Maximum Yield ◽  
Sem Analysis ◽  
Water Molecules ◽  
Banana Weevil ◽  
Gelatinization Temperature ◽  
Recharge Area ◽  
Maximum Quantity

Glycerin residue is waste oleochemical industry that still contain glycerin. To produce quality and maximum quantity of glycerin, then research the effect of pH acidification using phosphoric acid. Glycerin analysis includes the analysis of pH, Fatty Acid and Ester (FAE), and analysis of the levels of glycerin. The maximum yield obtained at pH acidification 2 is grading 91,60% glycerin and Fatty Acid and Ester (FAE) 3,63 meq/100 g. Glycerin obtained is used as a plasticizer in the manufacture of bioplastics. Manufacture of bioplastics using the method of pouring a solution with varying concentrations of starch banana weevil (5% w/v and 7% w/v), variations of the addition of glycerin (1 ml, 3 ml, 5 ml and 7 ml), and a variety of gelatinization temperature (60°C, 70°C, and 80°C). Analysis of bioplastics include FTIR testing, tensile strength that is supported by SEM analysis. The results obtained in the analysis of FTIR does not form a new cluster on bioplastics starch banana weevil, but only a shift in the recharge area only, it is due to the addition of O-H groups originating from water molecules that enter the polysaccharide through a mechanism gelatinitation that generates interaction hydrogen bonding strengthened. The maximum tensile strength of bioplastics produced at a concentration of starch 7% w/v, 1 ml glycerine and gelatinization temperature of 80°C is 3,430 MPa. While the tensile strength bioplastic decreased with increasing glycerin which can be shown from the results of SEM where there is a crack, indentations and lumps of starch insoluble.

Simulation and Analysis of Two-Mass Suspension Modification Using MATLAB Programming

2019 ◽  
Vol 3 (1) ◽  
pp. 160-165
Author(s):  
Hendry D. Chahyadi
Keyword(s):  
Vibrational Energy ◽  
State Space Model ◽  
Mass System ◽  
Modeling And Analysis ◽  
The Road ◽  
Final Project ◽  
Quarter Car ◽  
Automotive Suspension ◽  
Mass Spring ◽  
Matlab Programming

The designs of automotive suspension system are aiming to avoid vibration generated by road condition interference to the driver. This final project is about a quarter car modeling with simulation modeling and analysis of Two-Mass modeling. Both existing and new modeling are being compared with additional spring in the sprung mass system. MATLAB program is developed to analyze using a state space model. The program developed here can be used for analyzing models of cars and vehicles with 2DOF. The quarter car modelling is basically a mass spring damping system with the car serving as the mass, the suspension coil as the spring, and the shock absorber as the damper. The existing modeling is well-known model for simulating vehicle suspension performance. The spring performs the role of supporting the static weight of the vehicle while the damper helps in dissipating the vibrational energy and limiting the input from the road that is transmitted to the vehicle. The performance of modified modelling by adding extra spring in the sprung mass system provides more comfort to the driver. Later on this project there will be comparison graphic which the output is resulting on the higher level of damping system efficiency that leads to the riding quality.

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