Polymeric-based deep eutectic solvents for effective extractive desulfurization of liquid fuel at ambient conditions

2017 ◽  
Vol 120 ◽  
pp. 271-283 ◽  
Author(s):  
Walaa S. Ahmed Rahma ◽  
Farouq S. Mjalli ◽  
Talal Al-Wahaibi ◽  
Abdul Aziz Al-Hashmi
2020 ◽  
Vol 22 (21) ◽  
pp. 7537-7542 ◽  
Author(s):  
Jikuan Qiu ◽  
Pengxin Guan ◽  
Yuling Zhao ◽  
Zhiyong Li ◽  
Huiyong Wang ◽  
...  

For the first time, a mild and green strategy is reported for the efficient syntheses of a series of 2D and 3D COFs using deep eutectic solvents as clean media under ambient conditions.


2021 ◽  
Vol 11 (4) ◽  
pp. 1601
Author(s):  
Henrik Palmelund ◽  
Jukka Rantanen ◽  
Korbinian Löbmann

Deep eutectic solvents (DESs) are formed by a hydrogen bond donor and an acceptor. The hydrogen bond interactions between these two components significantly depress the melting temperature of the mixture. DESs have been used as an alternative for organic solvents in various branches of the chemical industry. Many DESs are very hygroscopic and water is known to change the properties of DESs, but there has neven been a systematic study performed on the deliquesence behavior of DESs. Therefore, this study investigated the thermal and deliquescent behavior of four DESs. The DES mixtures were stored in desiccators at different relative humidities (RH) to investigate the critical RH (RH0) for deliquescence. It was found that, due to the formation of a eutonic mixture, the RH0 to induce deliquescence for a given DES mixture was lower compared to the individual components comprising the DES. The results showed that, even though all investigated DESs had eutectic melting temperatures above room temperature, but due to the low RH0, they were able to appear liquid at room temperature under ambient conditions. The eutonic and eutectic compositions were identified at different compositions for the DESs. The results emphasize that great care must be taken to control the process and storage conditions for DESs.


2017 ◽  
Vol 168 ◽  
pp. 225-234 ◽  
Author(s):  
Feiyan Ye ◽  
Guang Miao ◽  
Liqiong Wu ◽  
Ying Wu ◽  
Zhong Li ◽  
...  

Fuel ◽  
2021 ◽  
Vol 305 ◽  
pp. 121502
Author(s):  
Suman Tahir ◽  
Umair Yaqub Qazi ◽  
Zubera Naseem ◽  
Noor Tahir ◽  
Muhammad Zahid ◽  
...  

Author(s):  
Alessandro Zucca ◽  
Sergey Khayrulin ◽  
Natalya Vyazemskaya ◽  
Borys Shershnyov ◽  
Geoff Myers

Analysis of the Oil & Gas market segment showed that potential MS5002E customers could benefit from firing the gas turbine with distillate oil as a back-up fuel, mainly to provide power when the fuel gas is not available (e.g. when the plant itself is being commissioned). To address this customer need, the design of a dual fuel system for such mission should target simplicity, reliability and minimize the additional cost with respect to the single gas version. To achieve these targets, the development of the dual fuel system for the MS5002E leveraged the efforts made by GE for the design of a liquid fuel system for Frame 9F-1 series with no need of atomization air. Moreover, the emission capability during liquid fuel operation was enhanced allowing the mixing of water and fuel before injection in the combustion chamber and using of improved injection technology, thus improving the efficiency of water injection with a significant reduction in the required water flow rates; the importance of this achievement is related to both the increasingly stringent regulation on this subject and the often poor availability of water in the Oil & Gas market segment. The system is capable of continuous operation without water injection for applications where emissions are not critical; in these cases a small amount of demineralized water is employed occasionally for fuel line cooling and flushing, thus helping to guarantee constant performances of the injectors, and to maintain liquid fuel start-up capability over time. This paper presents the expected performance, in terms of ignition capability, emissions, operability and expected hardware durability on LF/water-fuel emulsion operation, based on a single can rig test campaign. The new liquid fuel cartridges were tested from ignition to base load at ISO and extreme simulated ambient conditions, both with and without water injection, showing promising performance in terms of combustor operability and emissions. All the combustor components were instrumented with thermocouples to assess variations in the hardware thermal levels with respect to the single gas conditions, and identify possible issues related to the transient and steady-state liquid fuel operation. Further development and testing will be carried out in the next phases of the development, and the performance will be confirmed by a dedicated engine test at the first commercial opportunity.


2018 ◽  
Vol 140 (7) ◽  
Author(s):  
Kumaran Kannaiyan ◽  
Reza Sadr

The gas-to-liquid (GTL) fuel, a liquid fuel synthesized from natural gas through Fischer–Tropsch process, exhibits better combustion and, in turn, lower emission characteristics than the conventional jet fuels. However, the GTL fuel has different fuel properties than those of regular jet fuels, which could potentially affect its atomization and combustion aspects. The objective of the present work is to investigate the near-nozzle atomization characteristics of GTL fuel and compare them with those of the conventional Jet A-1 fuel. The spray experiments are conducted at different nozzle operating conditions under standard ambient conditions. The near-nozzle macroscopic spray characteristics are determined from the shadowgraph images. Near the nozzle exit, a thorough statistical analysis shows that the liquid sheet dynamics of GTL fuel is different from that of Jet A-1 fuel. However, further downstream, the microscopic spray characteristics of GTL fuel are comparable to those of the Jet A-1 fuel.


Author(s):  
V. Mahendra Reddy ◽  
Darshan Sawant ◽  
Sudarshan Kumar

This paper presents experimental and numerical results on a single stage burner configuration with flameless/MILD combustion with liquid fuel. The proposed burner configuration is designed for 20 kW thermal input with heat intensity of ∼ 5 MW/m3 using kerosene as fuel and air at ambient conditions as the oxidizer. Air is injected through four tangential injection holes near the bottom of the combustor results high swirl flow in the combustor helps to enhance the internal recirculation of the combustion products. Computational and experimental analysis is carried out simultaneously for optimization of combustor configuration. In swirl combustor configurations the reactants dilution ration (recirculation) is function of combustor geometry, exit diameter and inlet velocity of air. In the first step of study four different combustor configurations are considered, one cylindrical and three conical combustors with diverging angles of 30°, 45° and 60°. In the second step the effect of exit port diameter on the recirculation and quality of flameless combustion is studied. The exit port diameter varied from 80 mm to 25 mm. In the third step the inlet velocities of air varied by inserting different inlet diameters of 2 to 7 mm in a step of 1mm. Based on combustion completeness and emission analysis, the 60° diverging angle combustor with air inlet diameter of 4 or 5 mm and 25 mm exit diameter is considered as optimistic configuration to obtain flameless combustion mode with liquid fuels. The acoustic emissions and the emissions of CO and NOX are measured for different configurations.


2018 ◽  
Vol 20 (13) ◽  
pp. 3112-3120 ◽  
Author(s):  
Zhiheng Li ◽  
Dong Liu ◽  
Zhuowu Men ◽  
Linhua Song ◽  
Yijun Lv ◽  
...  

The compatibility index (CI and PCI) as a new criterion is feasible to evaluate the removal efficiency of heterocycles in green and economic DESs.


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