Probing boron thermite energy release at rapid heating rates

2021 ◽  
Vol 231 ◽  
pp. 111491
Author(s):  
Jennifer L. Gottfried ◽  
Elliot R. Wainwright ◽  
Sidi Huang ◽  
Yue Jiang ◽  
Xiaolin Zheng
2014 ◽  
Vol 2014 (1) ◽  
pp. 000100-000106
Author(s):  
Tom Colosimo ◽  
Horst Clauberg ◽  
Evan Galipeau ◽  
Matthew B. Wasserman ◽  
Michael Schmidt-Lange ◽  
...  

Advancements in electronic packaging performance and cost have historically been driven by higher integration primarily provided by fab shrinks that has followed the well-known Moore's law. However, due to the tremendous and continuously increasing cost of building new fabs, the performance/cost improvements achieved via node shrinks are negated. This leaves packaging innovation as the vehicle to achieve future cost-performance improvements. This has initiated a More-than-Moore idea that has led to vigorous R&D in packaging. Advanced packages which employ ultra-fine pitch flip chip technology for chip-to-substrate, chip-to-chip, or chip-to-interposer for the first level interconnect have been developed as an answer to obtaining higher performance. However, the costs are too high as compared to traditional wire bonding. The status today is that the fundamental technical hurdles of manufacturing the new advanced packages have been solved, but cost reduction and yield improvements have to be addressed for large-scale adoption into high volume manufacturing. In traditional flip chip assembly silicon chips are tacked onto a substrate and then the solder joints are melted and mass reflowed in an oven. This mass reflow technique is troublesome as the pitch of the solder bumps become finer. This is due to the large differences in the thermal expansion coefficient of the die and the substrate, which creates stress at the solder joints and warpage of the package when the die and substrate are heated and cooled together. To mitigate and resolve this issue, thermo-compression bonders have been developed which locally reflow the solder without subjecting the entire substrate to the heating and cooling cycle. This requires that the bondhead undergo heating past the melting point of solder and then cooling down to a low enough temperature to pick the next die from the wafer that is mounted to tape. Machines in the market today can accomplish this temperature cycle in 7 to 15 seconds. This is substantially slower than the standard flip chip process which leads to high cost and is delaying the introduction of these new packages. This paper shows a flip chip bonder with a new heating and cooling concept that will radically improve the productivity of thermo-compression bonding. Data and productivity cycles from this new bond head with heating rates of over 200°C/sec and cooling of faster than 100°C/sec are revealed. Experimental results are shown of exceptional temperature accuracy across the die of 5°C throughout the cycle and better than 3°C at the final heating stage. The high speed thermo-compression bonds are analyzed and the efficacy of the new concept is proven. Excellent temperature uniformity while heating rapidly is an absolute necessity for enabling good solder joints in a fast process. Without good temperature uniformity, additional dwell times need to be incorporated to allow heat to flow to all of the joints, negating any benefits from rapid heating. Whereas the current state-of-that-art is often to program temperature in steps, this bonder can be commanded and accurately follows more complex temperature profiles with great accuracy. Examples of how this profiling can be used to enhance the uniformity and integrity of the joints with non-conductive pastes, film, and without underfill along with the associated productivity improvements will be shown. Tests that show portability across platforms that will lead to set up time and yield improvements and are identified and quantified. Additionally new ideas for materials and equipment development to further enhance productivity and yield are explored.


Fuel ◽  
2017 ◽  
Vol 200 ◽  
pp. 467-480 ◽  
Author(s):  
Chinsung Mock ◽  
Hookyung Lee ◽  
Sangmin Choi ◽  
Vasilije Manovic

2010 ◽  
Vol 19 (7) ◽  
pp. 895 ◽  
Author(s):  
Craig B. Clements

High-frequency thermocouple measurements were made during an experimental grass fire conducted during ideal weather with overcast and windy conditions. Analysis of the thermodynamic structure of the fire plume showed that a maximum plume temperature of 295.2°C was measured directly above the combustion zone. Plume heating rates were on the order of 26–45 kW m–2 and occurred in the region just above the combustion zone between 10 and 15 m above ground level and were followed by cooling of approximately –37 and –44 kW m–2. The observed cooling was caused by strong entrainment that occurred behind the fire front and plume. The rapid heating and subsequent cooling indicate that the heating caused by a fire front is limited to a small volume around the flaming front and that the rates of heat gain occur for a short duration. The short duration of plume heating is due to the fast rate of spread of the fire front and ambient wind.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Touseef Habib ◽  
Nutan Patil ◽  
Xiaofei Zhao ◽  
Evan Prehn ◽  
Muhammad Anas ◽  
...  

Abstract Here we report for the first time that Ti3C2Tx/polymer composite films rapidly heat when exposed to low-power radio frequency fields. Ti3C2Tx MXenes possess a high dielectric loss tangent, which is correlated with this rapid heating under electromagnetic fields. Thermal imaging confirms that these structures are capable of extraordinary heating rates (as high as 303 K/s) that are frequency- and concentration-dependent. At high loading (and high conductivity), Ti3C2Tx MXene composites do not heat under RF fields due to reflection of electromagnetic waves, whereas composites with low conductivity do not heat due to the lack of an electrical percolating network. Composites with an intermediate loading and a conductivity between 10–1000 S m−1 rapidly generate heat under RF fields. This finding unlocks a new property of Ti3C2Tx MXenes and a new material for potential RF-based applications.


2016 ◽  
Vol 30 (12) ◽  
pp. 10809-10822 ◽  
Author(s):  
Chinsung Mock ◽  
Hookyung Lee ◽  
Sangmin Choi ◽  
Vasilije Manovic

2004 ◽  
Vol 467-470 ◽  
pp. 287-292 ◽  
Author(s):  
Leo Kestens ◽  
Ana Carmen C. Reis ◽  
Wlodzimierz Kaluba ◽  
Yvan Houbaert

A Ti-stabilized interstitial free steel was highly cold deformed to a reduction of 95% and subsequently submitted to extremely short annealing cycles with heating rates varying between 300°C/s and 4500°C/s followed by water quench at various temperatures. The microstructural and textural development was studied through various consecutive stages: partially recrystallized, fully recrystallized and after α→γ→α transformation. It was found that irrespective of the heating rate the recrystallization has completely terminated before the onset of the ferrite to austenite phase transformation. In the fully recrystallized condition, ultra-rapid heating gave rise to substantially refined structures with an average ferrite grain size of 6µm. It was also observed that this grain refinement saturates with heating rates beyond 1000°C/s. With regard to the texture formation, the characteristic {111} deep drawing fibre of cold rolled IF steels was observed, irrespective of the heating rate, in an annealing treatment as short as 0.3s. After the forward and reverse α→γ transformation, the ensuing ferrite texture displayed a strong memory effect, as the {111} fibre was even more intense after the double transformation than before.


2007 ◽  
Vol 539-543 ◽  
pp. 4720-4725 ◽  
Author(s):  
A. Nagao ◽  
K. Hayashi ◽  
K. Oi ◽  
S. Mitao ◽  
N. Shikanai

The precipitation behavior of cementite in low carbon steels at various heating rates from 0.3 to 100 K/s has been studied using a high-frequency induction heating apparatus. The materials used in this study were steel platesfor welded structures: 610 and 780 MPa class steel plates with a mixed microstructure of bainite and martensite.Cementite was observed using a carbon extraction replica method and the hardness and toughness were also examined. When heated at the conventional slow rate of 0.3 K/s, relatively large cementite particles with an average diameter of 72 nm precipitated at the lath boundaries, whereas when heated at a rapid rate over 3.0 K/s, cementite precipitated both within the laths and at the lath boundaries, and the cementite was refined down to an average diameter of 54 nm. With such refinement of the cementite, the toughness was improved. On the other hand, the hardness was irrespective of the heating rate and was dependent on the tempering parameter. TEM observations of the cementite precipitation behavior during the rapid heating process revealed that cementite begins to precipitate at the lath boundaries at about 773 K and within the laths at about 873 K. It is concluded that rapid heating especially from 773 to 873 K contributes to the cementite refinement and consequently the improvement in toughness. The effect of alloying elements such as chromium, molybdenum or silicon on the cementite growth during the rapid heating and tempering treatment is also discussed.


1955 ◽  
Vol 28 (3) ◽  
pp. 718-727 ◽  
Author(s):  
Donald E. Roberts ◽  
Leo Mandelkern

Abstract The existence of an equilibrium melting temperature, T0m, at 28 ± 1°, for unstretched natural rubber has been established, using dilatometric methods. The lower melting temperatures previously observed are a consequence of the low temperatures of crystallization and the rapid heating rates employed. From melting point studies of mixtures of the polymer with low molecular-weight diluents, the heat of fusion per repeating unit, ΔHu has been evaluated as 15.3 ± 0.5 cal./g. The values of ΔHu and T0m have then been combined with data of other workers to obtain the following information concerning natural rubber: (1) The variation of melting temperature with applied hydrostatic pressure has been calculated from the Clapeyron equation to be 0.0465° C/atm. (2) The degree of erystallinity resulting from maintaining a sample at 0° until the rate of crystallization is negligible has been calculated, by three independent methods, to be in the range 26 to 31 per cent. (3) Analysis of the stress-strain-temperature relationship has indicated that crystallization is the cause of the large internal energy changes that are observed at relatively high elongations.


Fuel ◽  
1982 ◽  
Vol 61 (10) ◽  
pp. 1014-1019 ◽  
Author(s):  
I MOCHIDA ◽  
Y MORIGUCHI ◽  
T SHIMOHARA ◽  
Y KORAI ◽  
H FUJITSU ◽  
...  

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