Reducing the NOx emissions during NH3 oxidation with Nickel modified Fe2O3-a promising cost-effective and environmentally friendly catalyst for NH3 combustion

2022 ◽  
Vol 237 ◽  
pp. 111845
Author(s):  
Ye Wu ◽  
Jian Mei ◽  
Tianyi Cai ◽  
Wei Wang ◽  
Hang Zhu ◽  
...  
2021 ◽  
Author(s):  
M. C. van Leeuwen ◽  
P. M. Gangé ◽  
B. Duran ◽  
F. Prenger

<p>Metallic zinc coatings are well established as cost-effective corrosion protection for steel bridges. The zinc coating acts first as barrier protection, isolating the base steel from corrosive elements, and secondly by cathodic protection, acting as a sacrificial anode to protect the steel should the coating be compromised. Bridge operators can be confronted by disproportional high maintenance costs for bridges in use as removal of (in)organic paint systems with hazardous and toxic compounds require expensive waste disposal and environmental protection measures. Metallic zinc coatings are recognized as environmentally friendly, sustainable, and low maintenance, providing the lowest life cycle cost corrosion protection. Various case studies with bridges protected with metallic zinc coatings in and outside Europe are illustrated.</p>


2017 ◽  
Vol 53 (77) ◽  
pp. 10664-10667 ◽  
Author(s):  
Ye Wu ◽  
Guodong Jiang ◽  
Hongbo Zhang ◽  
Zhao Sun ◽  
Yuan Gao ◽  
...  

Fe2O3is found to be a cost-effective and environmentally friendly catalyst for chemical looping generation of NH3– a future fuel.


Author(s):  
K. Michael Du¨sing ◽  
Andrea Ciani ◽  
Adnan Eroglu

Alstoms GT24 and GT26 engines feature a unique sequential combustion system [1, 2]. This system consists of a premixed combustor (called EV), which is followed by a high pressure turbine, a reheat combustor (called SEV) and a low pressure turbine (Figure 1). Recently improvements in NOx performance of the SEV have been demonstrated. Starting with relatively simple methods numerous design variants have been tested and down selected. Further down-selection has been done with methods of increased complexity. Overall a fast and cost effective development process has been assured. During the development process the variation coefficient and unmixedness measured and calculated for mixing only systems (CFD and water channel) has proven to be a reliable indicators for low NOx emissions for the real combustion system on atmospheric and high pressure test rigs. To demonstrate this a comparison of both quantities against NOx emissions is shown. The paper focuses on the NOx results achieved during this development and its relation to mixing quantities. Using this relation, together with a detailed understanding of the flow characteristic in the SEV burner, reductions in NOx emissions for GT24 and GT26 SEV burner and lance hardware can be reached using relatively simple methods.


2019 ◽  
Vol 102 (3) ◽  
pp. 942-951 ◽  
Author(s):  
Danni Yang ◽  
Yi Yang ◽  
Yongxin Li ◽  
Shuo Yin ◽  
Yaling Chen ◽  
...  

Abstract Background: Consistent toxicological evidence indicate that phthalates can cause adverse effects on human health. The concern over phthalate pollution and exposure has been emphasized in recent years. Therefore, the sensitive, reliable, and rapid detection of phthalates in water is of great importance. Objective: In this study, dispersive liquid–liquid microextraction based on solidification of floating organic droplet (DLLME-SFO) combined with HPLC-UV detection was established and applied in the preconcentration and detection of 15 phthalates in drinking and river water samples. Methods: A mixture of acetonitrile (dispersant) and 1-dodecanol (extractant) was injected into water samples, which had been added with sodium chloride. The cloudy solution was formed by hand-shaking. After centrifugation, the sample solution was cooled in a refrigerator, and the solidified organic droplet was collected. It melted at room temperature and was injected into the HPLC system for analysis. The quantification was based on the working curves. Results: Under optimum conditions, this method showed good linearity in the range of 0.1–100 or 0.5–100 μg/L with correlation coefficients greater than 0.999. The method had the LODs ranging from 0.013 to 0.16 μg/L with the enrichment factors of 102–218. The recoveries of the method ranged from 86.8 to 119% with RSDs less than 12.6%. The interday and intraday RSDs were 6.35–13.5% and 3.00–13.7%, respectively. The established method has been successfully applied to the analysis of phthalates in drinking and river waters. Conclusions: The established method is rapid, sensitive, cost-effective, and environmentally friendly. It can be applied to the analysis of 15 phthalates in drinking and river water samples. Highlights: A method of DLLME-SFO combined with HPLC-UV detection has been established for the analysis of 15 phthalates in drinking and river water samples. The established method was rapid, sensitive, accurate, cost-effective, and environmentally friendly. The established method was successfully applied to the analysis of 15 phthalates in bottled, tap, and river water samples.


2017 ◽  
Vol 79 (2) ◽  
Author(s):  
Muhammad Roslan Rahim ◽  
Mohammad Nazri Mohd Jaafar

Combustion of liquid fuel sprays produces NOX, CO and other emissions that have an adverse impact on the environment and humans. This study is conducted to produce low-emission combustion with the use of double radial swirler. Swirling flow burning will enhance the mixing of fuel and air to produce a flame that is more stable and efficient. In this study, weak swirler with an angle of 30º is set as a primary swirler and strong swirlers each with an angle of 40º, 50º and 60º are set as the secondary swirler. Combinations of these swirlers helped the mixing of fuel and air during combustion. The results show, the combination of swirlers 30º/60º produced the highest temperature profile, the best flames, more stable and shorter than other combinations. NOX emissions for the combination of swirlers 30º/60º at stoichiometric are 15.6% lower than the combinations of swirlers 30º/40º. Other emissions such as CO, also shows 8.4% of reduction in the combination of swirlers 30º/60º. These results indicated that double swirlers helped in reducing emissions during combustion and also producing an environmentally friendly combustion system.


2019 ◽  
Vol 54 (5) ◽  
pp. 443-451
Author(s):  
Nodir Madrahimov ◽  
Ruslan Natanov ◽  
Abdurasul Khalikov ◽  
Erin C Boyle ◽  
Danny Jonigk ◽  
...  

Hypothermia is a treatment strategy for different clinical conditions and an essential part of cardiopulmonary bypass in complex cardiac procedures. Clinically, cooling patients is achieved via a mattress and heat exchanger integrated into a membrane oxygenator connected to a waterbed using a refrigerator system based on volatile and toxic liquids. Peltier elements are known as environmentally friendly thermoelectric generators that enable rapid warming and cooling. In this paper, we describe the construction of a novel device for rapid and precise control of mouse warming and cooling using thermoelectric Peltier elements. Six male BALB/c mice were subjected to deep hypothermia and were rewarmed under full physiological monitoring. After rewarming, all animals were observed for two hours, and pathology was evaluated in several organs. All animals tolerated the rapid cooling process well and remained active after rewarming. Temperature-relevant changes were seen via electrocardiography, with heart-rate patterns showing a strong linear correlation to body temperature. No myocardial ischaemia was seen. However, two animals experienced bradycardic atrial fibrillation which spontaneously converted to normal sinus rhythm during rewarming. No histological damage was seen in the heart, liver, kidney or lungs. Our device can effectively be used for heat shock and hypothermia studies in mice, and we foresee no obstacles for its application to other small rodents such as hamsters and young rats. In comparison to known experimental and clinical methods of hypothermia, our device is environmentally friendly, cost-effective and easy to handle, allowing precise control and maintenance of body temperatures ranging from 18℃ to 42℃.


RSC Advances ◽  
2015 ◽  
Vol 5 (89) ◽  
pp. 72849-72856 ◽  
Author(s):  
Ketan P. Gattu ◽  
Kalyani Ghule ◽  
Anil A. Kashale ◽  
V. B. Patil ◽  
D. M. Phase ◽  
...  

Using a novel, cost-effective and environmentally friendly biosynthesis method, Ni-doped SnO2 nanoparticles have been synthesized. Gas sensing results suggest that the Ni-dopant is a promising additive to fabricate low cost SnO2 based sensors.


Author(s):  
David Oh ◽  
Jean-Sébastien Plante

A hydrogen-fueled two-stroke prototype demonstrator based on a 9.9 hp (7.4 kW) production gasoline marine outboard engine is presented, which, while matching the original engine's rated power output on hydrogen, achieves a best-point gross indicated thermal efficiency (ITE) of 42.4% at the ICOMIA mode 4 operating point, corresponding to 80% and 71.6% of the rated engine speed and torque, respectively. The brake thermal efficiency (BTE) at the rated power is 32.3%. Preliminary exhaust gas measurements suggest that the engine could also meet the most stringent CARB 5-Star marine spark-ignition emission standards limiting HC + NOx emissions to 2.5 g/kWh without any after-treatment. These are realized in a cost-effective concept around a proven two-stroke base engine and a low-pressure direct-injected gaseous hydrogen (LPDI GH2) system, which employs no additional fuel pump and is uniquely adapted from volume production components. Later fuel injection is found to improve thermal efficiency at the expense of increased NOx emissions and, at the extreme, increased cyclic variation. These observations are hypothesized and supported by phenomenological inferences of the observed trends of combustion duration, NOx concentration, and indicated mean effective pressure (IMEP) variance to be due to increasing charge stratification with the later timings. This work outlines the pathway—including investigations of several fuel delivery strategies with limited success—leading to the current status, including design, modeling with GT-POWER, delivery of lube oil, lubrication issues using hydrogen, and calibration sweeps. The experimental results comprising steady-state dynamometer performance, cylinder pressure traces, NOx emission measurements, along with heat release analyses, support the reported numbers and the key finding that late fuel injection timing and charge stratification drive the high efficiencies and the NOx trade-off; this is discussed and forms the basis for future work.


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