Comparative study on the isothermal aging of bare Cu and ENImAg surface finish for Sn-Ag-Cu solder joints

2018 ◽  
Vol 740 ◽  
pp. 958-966 ◽  
Author(s):  
M.A. Rabiatul Adawiyah ◽  
O. Saliza Azlina
Author(s):  
Anand Kannabiran ◽  
Sreekanth Varma Penmatsa ◽  
S. Manian Ramkumar ◽  
Reza Ghaffarian

The primary objective of this experimental research is to understand the common issues faced in a manufacturing environment that assembles products containing a variety of fine-pitch devices. The testing phase of the research, relates to characterizing the thermo-mechanical integrity of surface mount mixed (Sn-Pb & lead-free) assembly solder joints. The investigation involves both forward and backward compatibility in electronics assemblies on Pb-free PWB surface finishes. A full factorial design is used in the investigation, with 3 factors — solder paste, component finish and PWB surface finish. Eutectic Sn-Pb paste (63–37% wt) and SAC305 (Sn 3.0%Ag0.5%Cu) paste are used as Pb-containing and Pb-free levels respectively. For component finish metallization, Sn-Pb termination finish/bump composition is used for Pb-containing level while Sn termination/SAC 405 bump composition represents the Pb-free level. Immersion Silver (ImAg) and Electroless Nickel Immersion Gold (ENIG) surface finish on printed wiring board (PWB) is used for testing and analysis. The testing was aimed at providing results for a wide variety of fine-pitch components commonly used in surface mount solder assemblies. Hence, a PWB containing flip chip (0.4mm pitch), Ultra chip scale package (UCSP), micro-lead frame (MLF) or quad flat pack no-lead (QFN), thin small outline package (TSOP −0.5 mm pitch) and plastic ball grid array (PBGA −1156 I/O and 256 I/O −1 mm pitch) devices was designed and used for testing. The test vehicle also includes resistors (0201, 0402 & 0603). The stencil thickness and openings were selected to accommodate both the large PBGA (1156 I/O) and finer pitch components. The reflow profile was designed taking into account the component maximum temperature exposure limitations, due to non-uniformity in heating, determined from thermocouples during initial assembly. Lessons learned from the design, reflow process optimization and manufacturing are presented in this paper. The solder joints were subjected to isothermal aging followed by mechanical shock test, attempting to establish a relationship between the intermetallic growth at the solder/PWB interface and the mechanical integrity of the solder joint. The compounding of test, unlike singular test methods, provides a more realistic estimate of the reliability and life of the joint in the field. The assemblies were cross-sectioned after the tests and the microstructure of the solder joints will be analyzed to study the intermetallic growth upon isothermal aging.


2021 ◽  
Vol 127 ◽  
pp. 114388
Author(s):  
Yang Liu ◽  
Boqiao Ren ◽  
Yuxiong Xue ◽  
Min Zhou ◽  
Rongxing Cao ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 936 ◽  
Author(s):  
Min-Soo Kang ◽  
Do-Seok Kim ◽  
Young-Eui Shin

This study investigated the suppression of the growth of the intermetallic compound (IMC) layer that forms between epoxy solder joints and the substrate in electronic packaging by adding graphene nano-sheets (GNSs) to 96.5Sn–3.0Ag–0.5Cu (wt %, SAC305) solder whose bonding characteristics had been strengthened with a polymer. IMC growth was induced in isothermal aging tests at 150 °C, 125 °C and 85 °C for 504 h (21 days). Activation energies were calculated based on the IMC layer thickness, temperature, and time. The activation energy required for the formation of IMCs was 45.5 KJ/mol for the plain epoxy solder, 52.8 KJ/mol for the 0.01%-GNS solder, 62.5 KJ/mol for the 0.05%-GNS solder, and 68.7 KJ/mol for the 0.1%-GNS solder. Thus, the preventive effects were higher for increasing concentrations of GNS in the epoxy solder. In addition, shear tests were employed on the solder joints to analyze the relationship between the addition of GNSs and the bonding characteristics of the solder joints. It was found that the addition of GNSs to epoxy solder weakened the bonding characteristics of the solder, but not critically so because the shear force was higher than for normal solder (i.e., without the addition of epoxy). Thus, the addition of a small amount of GNSs to epoxy solder can suppress the formation of an IMC layer during isothermal aging without significantly weakening the bonding characteristics of the epoxy solder paste.


Metals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 791 ◽  
Author(s):  
Kaipeng Wang ◽  
Fengjiang Wang ◽  
Ying Huang ◽  
Kai Qi

Sn-58Bi eutectic solder is the most recommended low temperature Pb-free solder but is also limited from the interfacial embrittlement of Bi segregation. Since the quaternary Sn-38Bi-1.5Sb-0.7Ag solder provides a similar melting point as Sn-58Bi eutectic, this paper systematically investigated the properties of this solder from wettability, bulk tensile properties, interfacial microstructure in solder joints with a Cu substrate, interfacial evolution in joints during isothermal aging and the shear strength on ball solder joints with effect of aging conditions. The results were also compared with Sn-58Bi solder. The wettability of solder alloys was evaluated with wetting balance testing, and the quaternary Sn-38Bi-1.5Sb-0.7Ag solder had a better wettability than Sn-58Bi solder on the wetting time. Tensile tests on bulk solder alloys indicated that the quaternary Sn-38Bi-1.5Sb-0.7Ag solder had a higher tensile strength and similar elongation compared with Sn-58Bi solder due to the finely distributed SnSb and Ag3Sn intermetallics in the solder matrix. The tensile strength of solder decreased with a decrease in the strain rate and with an increase in temperature, while the elongation of solder was independent of the temperature and strain rate. When soldering with a Cu substrate, a thin Cu6Sn5 intermetallic compound (IMC) is produced at the interface in the solder joint. Measurement on IMC thickness showed that the quaternary Sn-38Bi-1.5Sb-0.7Ag had a lower IMC growth rate during the following isothermal aging. Ball shear test on solder joints illustrated that the quaternary Sn-38Bi-1.5Sb-0.7Ag solder joints had higher shear strength than Sn-58Bi solder joints. Compared with the serious deterioration on shear strength of Sn-58Bi joints from isothermal aging, the quaternary Sn-38Bi-1.5Sb-0.7Ag solder joints presented a superior high temperature stability. Therefore, the quaternary Sn-38Bi-1.5Sb-0.7Ag solder provides better performances and the possibility to replace Sn-58Bi solder to realize low temperature soldering.


Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 831 ◽  
Author(s):  
Di Zhao ◽  
Keke Zhang ◽  
Ning Ma ◽  
Shijie Li ◽  
Chenxiang Yin ◽  
...  

Dynamic observation of the microstructure evolution of Sn2.5Ag0.7Cu0.1RE/Cu solder joints and the relationship between the interfacial intermetallic compound (IMC) and the mechanical properties of the solder joints were investigated during isothermal aging. The results showed that the original single scallop-type Cu6Sn5 IMC gradually evolved into a planar double-layer IMC consisting of Cu6Sn5 and Cu3Sn IMCs with isothermal aging. In particular, the Cu3Sn IMC grew towards the Cu substrate and the solder seam sides; growth toward the Cu substrate side was dominant during the isothermal aging process. The growth of Cu3Sn IMC depended on the accumulated time at a certain temperature, where the growth rate of Cu3Sn was higher than that of Cu6Sn5. Additionally, the growth of the interfacial IMC was mainly controlled by bulk diffusion mechanism, where the activation energies of Cu6Sn5 and Cu3Sn were 74.7 and 86.6 kJ/mol, respectively. The growth rate of Cu3Sn was slightly faster than that of Cu6Sn5 during isothermal aging. With increasing isothermal aging time, the shear strength of the solder joints decreased and showed a linear relationship with the thickness of Cu3Sn. The fracture mechanism of the solder joints changed from ductile fracture to brittle fracture, and the fracture pathway transferred from the solder seam to the interfacial IMC layer.


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