Measurement of soluble reactive phosphorus concentration profiles and fluxes in river-bed sediments using DET gel probes

2008 ◽  
Vol 350 (3-4) ◽  
pp. 261-273 ◽  
Author(s):  
Helen P. Jarvie ◽  
Robert J.G. Mortimer ◽  
Elizabeth J. Palmer-Felgate ◽  
Katherine St. Quinton ◽  
Sarah A. Harman ◽  
...  
Keyword(s):  
Soluble Reactive Phosphorus ◽  
Phosphorus Concentration ◽  
Concentration Profiles ◽  
Bed Sediments ◽  
River Bed ◽  
Reactive Phosphorus ◽  
Soluble Reactive Phosphorus Concentration

Sediment Control of Soluble Reactive Phosphorus in Hoxie Gorge Creek, New York

1988 ◽  
Vol 45 (11) ◽  
pp. 2026-2034 ◽  
Author(s):  
R. L. Klotz
Keyword(s):  
New York ◽  
Stream Water ◽  
Soluble Reactive Phosphorus ◽  
Low Flow ◽  
Phosphorus Concentration ◽  
Sediment Control ◽  
Al Content ◽  
Exchangeable Al ◽  
Reactive Phosphorus ◽  
Highly Correlated

Stream sediments were found to regulate the soluble reactive phosphorus (SRP) of stream water by geochemical processes. This conclusion was based on sediment analysis, laboratory sorption experiments, and measurement of the equilibrium phosphorus concentration (EPC). EPC is the concentration of P in the water at which there is neither sorption nor desorption of P by the sediments. At low flow conditions, streamwater SRP was highly correlated with EPC at six sites along Hoxie Gorge Creek (r = 0.979). EPC was inversely related to the ionic strength of the equilibrating solution, with Ca2+ producing larger changes than Na+. Minimum EPC values occurred near the neutral pH of the stream water and increased sharply in acidic and basic solutions. Also, EPC was negatively correlated with the exchangeable Al content of the sediments at the six sites. These data are consistent with a mechanism previously verified for soils in which solution cations displace exchangeable Al(III) from sediments; hydrolyzed Al(III) reacts with phosphate and removes it from solution. EPC and streamwater SRP were lower at sites with sediments that had higher concentrations of P-binding sites, despite also having higher sediment P.

scholarly journals Long-Term Study of Soluble Reactive Phosphorus Concentration in Fall Creek and Comparison to Northeastern Tributaries of Cayuga Lake, NY: Implications for Watershed Monitoring and Management

Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2075 ◽  
Author(s):  
O’Leary ◽  
Johnston ◽  
Gardner ◽  
Penningroth ◽  
Bouldin
Keyword(s):  
Flow Rate ◽  
Algal Blooms ◽  
Soluble Reactive Phosphorus ◽  
Phosphorus Concentration ◽  
Term Study ◽  
Long Term Study ◽  
Cayuga Lake ◽  
Significant Difference ◽  
Reactive Phosphorus

This study focuses on soluble reactive phosphorus (SRP), a key driver of eutrophication worldwide and a potential contributor to the emerging global environmental problem of harmful algal blooms (HABs). Two studies of tributary SRP concentrations were undertaken in sub-watersheds of Cayuga Lake, NY, the subject of a total maximum daily load (TMDL) development process, due to phosphorus impairment of its southern shelf. The long-term study compared SRP concentration in Fall Creek in the 1970s with that in the first decade of the 2000s, thus spanning a period of change in phosphorus sources, as well as in regional climate. The spatial study used data collected between 2009 and 2018 and compared SRP concentrations in Fall Creek to levels in northeastern tributaries that flow into the lake close to areas where HABs have been problematic. SRP was measured using standard procedures. Flow-weighted mean SRP concentration ranged between 15.0 µg/L and 30.0 µg/L in all years studied in both the 1970s and 2000s, with the exception of 2010. Annual discharge in Fall Creek showed no trend between 1970 and 2018, but a higher proportion of high streamflow samples was captured in the 2000s compared to the 1970s, which resulted in proportionally increased SRP concentration in the latter time period. There was no significant difference in the SRP concentration—flow rate relationship between the two time periods. Adjusted for flow rate, SRP concentrations in Fall Creek have not changed over many decades. Increasing phosphorus contributions from growing population and urbanization since the 1970s may have been counterbalanced by improvements in wastewater treatment and agricultural practices. Mean SRP concentration in northeastern tributaries was significantly (p < 0.001) higher than in Fall Creek, likely reflecting more intense agricultural use and higher septic system density in the watersheds of the former. This finding justifies continued monitoring of minor northern tributaries. Future monitoring must emphasize the capture of high flow conditions. Historical stability and highly variable hydrology will slow the watershed response to management and confound the ability to detect changes attributable to decreased phosphorus inputs. Large scale monitoring on decadal timescales will be necessary to facilitate watershed management.

Adsorption-Desorption of Phosphate on Hohhot Dust in Yellow River Water

2013 ◽  
Vol 807-809 ◽  
pp. 219-222
Author(s):  
Xiao Li Wang ◽  
Hui Juan Wang
Keyword(s):  
River Water ◽  
Yellow River ◽  
Soluble Reactive Phosphorus ◽  
Phosphorus Concentration ◽  
Overlying Water ◽  
P Adsorption ◽  
Isotherm Equation ◽  
Langmuir Isotherm Equation ◽  
Reactive Phosphorus ◽  
Adsorption Desorption

The Equilibrium Phosphorus Concentration (EPC0) of Hohhot dust (HD) of Inner mongolia was measured to examine whether the HD acted as sources or sinks of soluble reactive phosphorus (SRP) to the Yellow River water column. The modified Langmuir isotherm equation was modified to describe phosphorus (P) adsorption on the HD in Yellow River water. The EPC0 was higher than P concentration in the overlying water, which indicates that the HD acted as sources of phosphate. In addition, solid concentration (Cs) effect existed obviously in P adsorption experiment and the hysteresis got bigger as Cs increased.

Submerged macrophyte Ceratophyllum demersum affects phosphorus exchange at the sediment–water interface

2015 ◽  
Vol 71 (6) ◽  
pp. 913-921 ◽  
Author(s):  
Yanran Dai ◽  
Shuiping Cheng ◽  
Wei Liang ◽  
Zhenbin Wu
Keyword(s):  
Submerged Macrophytes ◽  
Soluble Reactive Phosphorus ◽  
Mean Value ◽  
Submerged Macrophyte ◽  
Ceratophyllum Demersum ◽  
Phosphorus Concentration ◽  
Water Interface ◽  
Adsorption Parameters ◽  
Overlying Water ◽  
Reactive Phosphorus

Substantial research efforts were made to assess the effects of submerged macrophytes on water quality improvement, but information on the mechanism of submerged macrophytes relative to the exchange of phosphorus (P) at the sediment–water interface is very limited. To help fill the void, a popular species, Ceratophyllum demersum L. was chosen to address the effects and mechanisms of submerged macrophyte growth on the processes of P exchange across the sediment­–water interface. In treatment mesocosms (planted), equilibrium phosphorus concentration (EPC0) value falls from 68.4 to 36.0 µg/L, with a mean value of 52.5 µg/L. Conversely, the distribution coefficient (Kd) value has a predominantly increasing trend. But they are both significantly higher than an unplanted control (p &lt; 0.05). Also, in the planted mesocosm, maximum phosphate sorption capacity (Qmax) was significantly reduced (4,721–3,845 mg/kg), and most of the linear correlations between different forms of phosphorus and sediment P adsorption parameters were affected (p &lt; 0.05). The EPC0 Percentage Saturation percentages (EPCsat) in planted groups were 325% higher than that in control (p &lt; 0.05). We conclude that C. demersum could promote the release of P from sediments, and soluble reactive phosphorus concentration in overlying water is probably the driving force for P exchange at the sediment–water interface.

Longitudinal and seasonal development of planktonio chlorophyll a in the Rideau River, Ontario

1995 ◽  
Vol 52 (4) ◽  
pp. 804-815 ◽  
Author(s):  
B. K. Basu ◽  
F. R. Pick
Keyword(s):  
Chlorophyll A ◽  
Total Phosphorus ◽  
Soluble Reactive Phosphorus ◽  
Seasonal Development ◽  
Phosphorus Concentration ◽  
Total Phosphorus Concentration ◽  
Chlorophyll A Concentration ◽  
Chl A ◽  
Reactive Phosphorus ◽  
Rideau River

Planktonic chlorophyll a (chl-a) concentrations in the Rideau River, Ontario showed longitudinal and seasonal variation and ranged from 2 to 19 μg∙L−1. Chlorophyll a concentrations in the river were not simply a reflection of the concentrations in the headwaters. On movement from the lentic headwaters into the lotic river waters there was usually a significant decrease in chl-a concentration. Downstream there were reaches of net increase in chl-a (sources), reaches of no change in concentration, and reaches of net decrease (sinks). Increases in concentration only occurred over reaches with retention times of 72 h or longer. No increases in chl-a concentration occurred over a reach with a retention time less than 50 h. Chlorophyll a concentration was not significantly correlated with discharge. Chlorophyll a concentration was positively related to total phosphorus concentration (R2 = 0.15, p = 0.016). About 50% of the variation in chl-a concentration could be accounted for by a combination of total phosphorus, nitrate, and soluble reactive phosphorus concentrations.

scholarly journals Effects of Lanthanum Modified Bentonite and Polyaluminium Chloride on the Environmental Variables in the Water and Sediment Phosphorus Form in Lake Yanglan, China

Water ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 1947
Author(s):  
Ling Su ◽  
Chen Zhong ◽  
Lei Gan ◽  
Xiaolin He ◽  
Jinlei Yu ◽  
...  
Keyword(s):  
Suspended Solids ◽  
Soluble Reactive Phosphorus ◽  
Particulate Phosphorus ◽  
Modified Bentonite ◽  
Combined Application ◽  
Water And Sediment ◽  
Phosphorus Form ◽  
Labile P ◽  
Reactive Phosphorus ◽  
Polyaluminium Chloride

The application of lanthanum modified bentonite (Phoslock®) and polyaluminium chloride (PAC) is popular in the restoration of European temperate lakes; however, the effects of the application on the concentrations of phosphorus (P) in both the water and the sediments have been poorly evaluated to date. We studied the effects of the application of Phoslock® + PAC on the concentrations of total phosphorus (TP), particulate phosphorus (PP), soluble reactive phosphorus (SRP), total suspended solids (TSS) and chlorophyll a (Chla) in the water, and different P forms in the sediments, in an isolated part of Lake Yanglan. The results showed that the concentrations of TP, PP, SRP, TSS and Chla decreased significantly after the addition of Phoslock® + PAC. Moreover, the concentrations of labile-P, reductant-soluble-P and organic-P in the sediments were also significantly decreased after the Phoslock® + PAC application. However, the concentrations of both the stable apatite-P and residual-P in the sediments after application of Phoslock® + PAC were much higher than the pre-addition values, while the concentrations of metal-oxide-P did not differ significantly between the pre- and post- application conditions. Our findings imply that the combined application of Phoslock® and PAC can be used in the restoration of subtropical shallow lakes, to reduce the concentrations of P in the water and suppress the release of P from the sediments.

scholarly journals Seasonal Variations of Phosphorus Species in the Overlying and Pore Waters of the Tuohe River, China

2019 ◽  
Vol 2019 ◽  
pp. 1-9
Author(s):  
Qing Xu ◽  
Xiaoping Yu ◽  
Yafei Guo ◽  
Tianlong Deng ◽  
Yu-Wei Chen ◽  
...  
Keyword(s):  
Seasonal Variations ◽  
Yangtze River ◽  
Algal Bloom ◽  
Soluble Reactive Phosphorus ◽  
Pore Waters ◽  
Phosphorus Species ◽  
Dissolved Phosphorus ◽  
Vertical Distributions ◽  
Reactive Phosphorus ◽  
Main Factor

Overlying sediment and pore waters were collected in summer and winter at upstream (Jintang) and downstream (Neijiang) sites of the Tuohe River, which is one of the five largest tributaries of the Yangtze River in China. Phosphorus species, including soluble reactive phosphorus (SRP), soluble unreactive phosphorus (SUP), and total dissolved phosphorus (TDP), and some diagenetic constituents including dissolved Fe(II), Mn(II), and sulfide in overlying and pore waters, were measured systematically. The seasonal variations and vertical distributions of phosphorus species in overlying and pore waters at both sampling sites were obtained to elucidate some aspects of the transport and transformations of phosphorus. Based on the profiles of pore and overlying waters as well as the TDN/TDP data during an algal bloom in 2007, it was clearly demonstrated that phosphorus was the main factor limiting the phytoplankton growth in the Tuohe River.

Impact of hydro-sedimentary processes on the dynamics of soluble reactive phosphorus in the Seine River

2014 ◽  
Vol 122 (2-3) ◽  
pp. 229-251 ◽  
Author(s):  
Lauriane Vilmin ◽  
Najla Aissa-Grouz ◽  
Josette Garnier ◽  
Gilles Billen ◽  
Jean-Marie Mouchel ◽  
...  
Keyword(s):  
Soluble Reactive Phosphorus ◽  
Sedimentary Processes ◽  
Seine River ◽  
Reactive Phosphorus

The effect of the reunification of Germany on the water chemistry and ecology of selected rivers

1996 ◽  
Vol 23 (1) ◽  
pp. 35-43 ◽  
Author(s):  
Michael S. Adams ◽  
Hartmut Kausch ◽  
Thomas Gaumert ◽  
Karl-Ernst Krüger
Keyword(s):  
Czech Republic ◽  
Species Diversity ◽  
Water Chemistry ◽  
Total Nitrogen ◽  
Chlorinated Hydrocarbons ◽  
The Czech Republic ◽  
Bed Sediments ◽  
Potash Mining ◽  
River Bed ◽  
Substantial Decline

SummaryWe review several studies and provide new data previously unpublished to show that there has been a substantial decline in pollution of German riverine waters since the beginning of German political reunification in 1989. This reduction is notable in the Elbe, which originates in eastern Germany and the Czech Republic. Pollutants such as many of the chlorinated hydrocarbons have fallen substantially in concentration, while others such as arsenic have declined only slightly. Total nitrogen has declined by only a small amount, but ammonium has fallen substantially, while nitrates have increased. Nitrification is no longer a significant drain on oxygen in the tidal stretch of the Elbe, but decomposition of algae from the middle Elbe is now a greater problem in the lower Elbe. The river-bed sediments of the middle Elbe have a higher species diversity. Fisheries are improving, and concentrations of pollutants in fish such as eel and bream have declined significantly. The river Werra has also improved in quality due to reduction in salt loadings from earlier potash mining.

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