Synergetic effect of potassium persulfate on photodegradation of para-arsanilic acid in Fe(III) oxalate system

Author(s):  
Yuliya E. Tyutereva ◽  
Petr S. Sherin ◽  
Evgeniya V. Polyakova ◽  
Vyacheslav P. Grivin ◽  
Victor F. Plyusnin ◽  
...  
1961 ◽  
Vol 20 (4) ◽  
pp. 768-773 ◽  
Author(s):  
I. D. Smith ◽  
E. M. Kiggins ◽  
H. S. Perdue ◽  
J. C. Holper ◽  
D. V. Frost

1988 ◽  
Vol 71 (3) ◽  
pp. 474-477 ◽  
Author(s):  
Duane D Hughes

Abstract A rapid method for the determination of dimetridazole and ipronidazole in feeds is described. The compounds are extracted from a borate buffer (pH 8.65) with benzene, partitioned into IN HC1, and then partitioned back into benzene from a basic aqueous phase. The benzene extract is concentrated and injected onto a nonpolar (Apiezon L) gas chromatographic column for determination by 63Ni electroncapture detection. Recoveries from feeds of various composition, spiked at 0.2 ppm with both dimetridazole and ipronidazole, ranged from 70 to 115%; for the same feeds spiked at 1 ppm or more, the recoveries were greater than 80%. Carbadox, furazolidone, levamisole, oxytetracycline, chlortetracycline, sulfamethazine, sulfaquinoxaline, arsanilic acid, piperazine, penicillin, and commonly added vitamins and minerals do not interfere. A 2-dimensional thin layer chromatographic system is presented as a means of additional identification.


Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 105
Author(s):  
Yifan Yang ◽  
Shiyong Tao ◽  
Zhichun Dong ◽  
Jing Xu ◽  
Xiang Zhang ◽  
...  

Because of the diversification of industries in developing cities, the phenomenon of the simultaneous contamination of various kinds of pollutants is becoming common, and the environmental process of pollutants in multi-contaminated environmental mediums has attracted attention in recent years. In this study, p-arsanilic acid (ASA), a kind of organic arsenic feed additive that contains the arsenic group in a chemical structure, is used as a typical contaminant to investigate its adsorption on iron oxides and its implication for contaminated soils. The adsorption kinetics on all solids can be fitted to the pseudo-second-order kinetic model well. At the same mass dosage conditions, the adsorption amount per unit surface area on iron oxides follows the order α-FeOOH > γ-Fe2O3 > α-Fe2O3, which is significantly higher than that for actual soil, because of the lower content of iron oxides in actual soil. Lower pH conditions favor ASA adsorption, while higher pH conditions inhibit its adsorption as a result of the electrostatic repulsion and weakened hydrophobic interaction. The presence of phosphate also inhibits ASA adsorption because of the competitive effect. Correlations between the amount of ASA adsorption in actual soil and the Fe2O3 content, total phosphorus content, arsenic content, and organic matter content of actual soil are also investigated in this work, and a moderate positive correlation (R2 = 0.630), strong negative correlation (R2 = 0.734), insignificant positive correlation (R2 = 0.099), and no correlation (R2 = 0.006) are found, respectively. These findings would help evaluate the potential hazard of the usage of organic arsenic feed additives, as well as further the understanding of the geochemical processes of contaminants in complicated mediums.


Author(s):  
Dolapo Bola Adelabu ◽  
Emile Bredenhand ◽  
Sean van der Merwe ◽  
Angelinus Cornelius Franke

Abstract To exploit the potential of ecological intensification during sunflower cropping, it is crucial to understand the potential synergies between crop management and ecosystem services. We therefore examined the effect of pollination intensification on sunflower yield and productivity under various levels of soil fertilization over two seasons in the eastern Free State, South Africa. We manipulated soil fertility with fertilizer applications and pollination with exclusion bags. We found a synergetic effect between pollination and soil fertilization whereby increasing pollination intensity led to a far higher impact on sunflower yield when the soil had been fertilized. Specifically, the intensification of insect pollination increased seed yield by approximately 0.4 ton/ha on nutrient poor soil and by approximately 1.7 ton/ha on moderately fertilized soil. Our findings suggest that sunflower crops on adequate balanced soil fertility will receive abundant insect pollination and may gain more from both synergies than crops grown in areas with degraded soil fertility.


Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 202
Author(s):  
Réka Barabás ◽  
Carmen Ioana Fort ◽  
Graziella Liana Turdean ◽  
Liliana Bizo

In the present work, ZrO2-based composites were prepared by adding different amounts of antibacterial magnesium oxide and bioactive and biocompatible hydroxyapatite (HAP) to the inert zirconia. The composites were synthesized by the conventional ceramic processing route and morpho-structurally analyzed by X-ray powder diffraction (XRPD) and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS). Two metallic dental alloys (i.e., Ni–Cr and Co–Cr) coated with a chitosan (Chit) membrane containing the prepared composites were exposed to aerated artificial saliva solutions of different pHs (i.e., 4.3, 5, 6) and the corrosion resistances were investigated by electrochemical impedance spectroscopy technique. The obtained results using the two investigated metallic dental alloys shown quasi-similar anticorrosive properties, having quasi-similar charge transfer resistance, when coated with different ZrO2-based composites. This behavior could be explained by the synergetic effect between the diffusion process through the Chit-composite layer and the roughness of the metallic electrode surface.


Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 118
Author(s):  
Bahaa Saleh ◽  
Ibrahem Maher ◽  
Yasser Abdelrhman ◽  
Mahmoud Heshmat ◽  
Osama Abdelaal

In this research, the effect of water-silica slurry impacts on polylactic acid (PLA) processed by fused deposition modeling (FDM) is examined under different conditions with the assistance of an adaptive neuro-fuzzy interference system (ANFIS). Building orientation, layer thickness, and slurry impact angle are considered as the controllable variables. Weight gain resulting from water, net weight gain, and total weight gain are the predicting variables. Results uncover the accomplishment of the ANFIS model to appropriately appraise slurry erosion in correlation with comparing real data. Both experimental and ANFIS results are almost identical with average percentage error less than 5.45 × 10−6. We observed during the slurry impacts tests that all specimens showed an increase in their weights. This weight gain was finally interpreted to the synergetic effect of water absorption and the solid particles fragmentations immersed within the specimens due to the successive slurry impacts.


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