scholarly journals Etch mechanism of an Al2O3 hard mask in the Bosch process

2021 ◽  
pp. 100102
Author(s):  
Martin Drost ◽  
Steffen Marschmeyer ◽  
Mirko Fraschke ◽  
Oksana Fursenko ◽  
Florian Bärwolf ◽  
...  
Keyword(s):  
Author(s):  
Jong Hak Lee ◽  
Jong Eun Kim ◽  
Chang Su Park ◽  
Nam Il Kim ◽  
Jang Won Moon ◽  
...  

Abstract In this work, a slightly unetched gate hard mask failure was analyzed by nano probing. Although unetched hard mask failures are commonly detected from the cross sectional view with FIB or FIB-TEM and planar view with the voltage contrast, in this case of the very slightly unetched hard mask, it was difficult to find the defects within the failed area by physical analysis methods. FIB is useful due to its function of milling and checking from the one region to another region within the suspected area, but the defect, located under contact was very tiny. So, it could not be detected in the tilted-view of the FIB. However, the state of the failure could be understood from the electrical analysis using a nano probe due to its ability to probe contact nodes across the fail area. Among the transistors in the fail area, one transistor’s characteristics showed higher leakage current and lower ON current than expected. After physical analysis, slightly remained hard mask was detected by TEM. Chemical processing was followed to determine the gate electrode (WSi2) connection to tungsten contact. It was also proven that when gate is floated, more leakage current flows compared to the state that the zero voltage is applied to the gate. This was not verified by circuit simulation due to the floating nodes.


Author(s):  
Zhigang Song ◽  
Jochonia Nxumalo ◽  
Manuel Villalobos ◽  
Sweta Pendyala

Abstract Pin leakage continues to be on the list of top yield detractors for microelectronics devices. It is simply manifested as elevated current with one pin or several pins during pin continuity test. Although many techniques are capable to globally localize the fault of pin leakage, root cause analysis and identification for it are still very challenging with today’s advanced failure analysis tools and techniques. It is because pin leakage can be caused by any type of defect, at any layer in the device and at any process step. This paper presents a case study to demonstrate how to combine multiple techniques to accurately identify the root cause of a pin leakage issue for a device manufactured using advanced technology node. The root cause was identified as under-etch issue during P+ implantation hard mask opening for ESD protection diode, causing P+ implantation missing, which was responsible for the nearly ohmic type pin leakage.


Nanoscale ◽  
2021 ◽  
Author(s):  
Haibin Ma ◽  
Zhiwen Chen ◽  
Zhili Wang

Electrochemical reduction of nitrogen (N2) to ammonia (NH3) has attracted attention as an emerging alternative to the traditional Haber-Bosch process to synthesize NH3. Unfortunately, currently electrocatalytic N2 reduction processes are...


2020 ◽  
Vol 1697 ◽  
pp. 012188
Author(s):  
E A Vyacheslavova ◽  
I A Morozov ◽  
D A Kudryashov ◽  
A S Gudovskikh

2008 ◽  
Author(s):  
Sang Il Hwang ◽  
Ki Jun Yun ◽  
Sang Wook Ryu ◽  
Kang Hyun Lee ◽  
Jae Won Han

2011 ◽  
Vol 20 (5-6) ◽  
pp. 707-710 ◽  
Author(s):  
Warren McKenzie ◽  
John Pethica ◽  
Graham Cross

2012 ◽  
Vol 195 ◽  
pp. 143-145 ◽  
Author(s):  
Emanuel I. Cooper ◽  
Rekha Rajaram ◽  
Makonnen Payne ◽  
Steven Lippy

Titanium nitride (TiN) is widely used as a hard mask film protecting the inter-level dielectric (ILD) before metal or plating seed layer deposition steps. It is common practice to use a wet etch in order to remove residues formed during the ILD dry-etch step, and at the same time to remove some or all of the exposed TiN. From its thermochemical properties, it might be predicted that wet etching of TiN should be easy, since it is quite unstable with respect to both plain and oxidative hydrolysis. For example, in acidic solutions at 25°C [1, :


Author(s):  
Peng Qiu ◽  
Cong Huang ◽  
Gang Dong ◽  
Feiyang Chen ◽  
Feifan Zhao ◽  
...  

Photocatalytic nitrogen fixation is a desirable approach to future sustainable nitrogen conversion and might consider as a potential alternative to the traditional Haber-Bosch process. However, the activation of nitrogen molecules...


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