Microhardness, wear resistance, and corrosion resistance of AlxCrFeCoNiCu high-entropy alloy coatings on aluminum by laser cladding

2021 ◽  
Vol 134 ◽  
pp. 106632
Author(s):  
Yanzhou Li ◽  
Yan Shi
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Laser Cladding ◽  
High Entropy Alloy ◽  
High Entropy

scholarly journals Wear and Corrosion Resistance of Al0.5CoCrCuFeNi High-Entropy Alloy Coating Deposited on AZ91D Magnesium Alloy by Laser Cladding

Entropy ◽  
2018 ◽  
Vol 20 (12) ◽  
pp. 915 ◽  
Author(s):  
Kaijin Huang ◽  
Lin Chen ◽  
Xin Lin ◽  
Haisong Huang ◽  
Shihao Tang ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Laser Cladding ◽  
Alloy Coating ◽  
High Entropy Alloy ◽  
High Entropy ◽  
Az91d Magnesium Alloy ◽  
Wear And Corrosion ◽  
Wear And Corrosion Resistance

In order to improve the wear and corrosion resistance of an AZ91D magnesium alloy substrate, an Al0.5CoCrCuFeNi high-entropy alloy coating was successfully prepared on an AZ91D magnesium alloy surface by laser cladding using mixed elemental powders. Optical microscopy (OM), scanning electron microscopy (SEM), and X-ray diffraction were used to characterize the microstructure of the coating. The wear resistance and corrosion resistance of the coating were evaluated by dry sliding wear and potentiodynamic polarization curve test methods, respectively. The results show that the coating was composed of a simple FCC solid solution phase with a microhardness about 3.7 times higher than that of the AZ91D matrix and even higher than that of the same high-entropy alloy prepared by an arc melting method. The coating had better wear resistance than the AZ91D matrix, and the wear rate was about 2.5 times lower than that of the AZ91D matrix. Moreover, the main wear mechanisms of the coating and the AZ91D matrix were different. The former was abrasive wear and the latter was adhesive wear. The corrosion resistance of the coating was also better than that of the AZ91D matrix because the corrosion potential of the former was more positive and the corrosion current was smaller.

scholarly journals Wear and Corrosion Resistance Analysis of FeCoNiTiAlx High-Entropy Alloy Coatings Prepared by Laser Cladding

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 155
Author(s):  
Zhaolei Sun ◽  
Mingyuan Zhang ◽  
Gaoqi Wang ◽  
Xuefeng Yang ◽  
Shouren Wang
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Wear Rate ◽  
Laser Cladding ◽  
Dendritic Structure ◽  
Wear Test ◽  
Corrosion Current ◽  
High Entropy Alloy ◽  
Nacl Solution ◽  
High Entropy

FeCoNiTiAlx (x = 0, 0.5, 1) high-entropy alloy coatings were prepared by laser cladding technology. The phase, microstructure, hardness, wear resistance and corrosion resistance were tested and analyzed. The results showed Al element promoted the conversion from the FCC phase to the BCC phase. The coating presented dendritic structure due to the addition of the Al element, while the number of dendrites increased. And the average hardness of the coating increased from 204 to 623 HV. The addition of the Al element increases the corrosion current density of the coating from 1.270 × 10−5 to 3.489 × 10−5 A/cm2. The wear rate of the coatings decreases with the increase of Al content according to dry friction and wear, which indicates the wear resistance of the coating was improved by adding the Al element. According to the corrosion wear test in 3.5% NaCl solution, it can be found that the wear rate of the coating increases firstly and then decreases with the addition of the Al element, which indicates that the addition of the Al element intensifies the wear of the coating in 3.5% NaCl solution.

Microstructures and Wear Resistance of Al1.5CrFeNiTi0.5 and Al1.5CrFeNiTi0.5W0.5 High Entropy Alloy Coatings Manufactured by Laser Cladding

2019 ◽  
Vol 956 ◽  
pp. 154-159 ◽  
Author(s):  
Hui Liang ◽  
Bing Yang Gao ◽  
Ya Ning Li ◽  
Qiu Xin Nie ◽  
Zhi Qiang Cao
Keyword(s):  
Wear Resistance ◽  
Laser Cladding ◽  
Dendritic Structure ◽  
Laves Phase ◽  
High Entropy Alloy ◽  
Second Phase ◽  
Laves Phases ◽  
High Entropy ◽  
Two Phases ◽  
Bcc Phase

For the purpose of expanding the application scope of HEA coating manufactured on the surface modification of materials, in this work, the Al1.5CrFeNiTi0.5 and Al1.5CrFeNiTi0.5W0.5 HEA coatings were successfully manufactured using laser cladding method on SUS304. The microstructures and wear resistance of coatings are researched systematically. It is found that the W0 and W0.5 HEA coatings all exhibit the dendritic structure, which are constituted by BCC phases and Laves phases. With W element addition, the phase structures of W0.5 coating remain unchanged. W is dissolved in both two phases, but the solid solubility in Laves phase is higher compared to that in BCC phase. W0.5 coating with the highest microhardness of 848.34 HV, and the W0 coating with the microhardness of 811.45 HV, both of whose microhardness are four times more than that of SUS304 substrate. Among all samples, the W0.5 coating shows the optimal wear performance because of its larger content of hard second phase ( Laves phase).

scholarly journals Microstructure Evolution and Properties of Laser Cladding CoCrFeNiTiAlx High-Entropy Alloy Coatings

Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 373 ◽  
Author(s):  
Yiku Xu ◽  
Zhiyuan Li ◽  
Jianru Liu ◽  
Yongnan Chen ◽  
Fengying Zhang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Laser Cladding ◽  
Laves Phase ◽  
High Entropy Alloy ◽  
Body Centered Cubic ◽  
Phase Constitution ◽  
High Entropy ◽  
Al Content ◽  
Wear And Corrosion ◽  
Wear And Corrosion Resistance

High-entropy alloy (HEA) coatings of CoCrFeNiTiAlx (x = 0, 0.5, 1, 1.5, 2) were prepared on the surface of AISI1045 steel by laser cladding. The effects of the Al content on the microstructure, composition, phase constitution, and wear and corrosion resistance of the coatings were investigated. The results showed that when increasing the Al element content from 0 to 0.5, the phase constitution of the CoCrFeNiTiAlx coating changed from a single Face-centered cubic (FCC) phase to Body-centered cubic 1 (BCC1) and Body-centered cubic 2 (BCC2) phases, with a small amount of Laves phase, which obviously improved the friction and corrosion resistance of the coating. With further enhancing of the Al content, the amount of BCC1 phase increased, while the BCC2 phase and the Laves phase decreased. The CoCrFeNiTiAl2 HEA coating transformed into a single BCC1 phase, with retrogressive wear and corrosion resistance. It was found that the Al0.5 alloy coating exhibits excellent wear resistance, high hardness, and corrosion resistance in a 3.5 wt.% NaCl solution. Furthermore, the effect of the Al content on the microstructure, phase, and the relating properties of the CoCrFeNiTiAlx HEA coatings is also discussed.

scholarly journals Microstructure and Properties of High-Entropy AlxCoCrFe2.7MoNi Alloy Coatings Prepared by Laser Cladding

Metals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1243 ◽  
Author(s):  
Minghong Sha ◽  
Chuntang Jia ◽  
Jun Qiao ◽  
Wenqiang Feng ◽  
Xingang Ai ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Laser Cladding ◽  
Pure Iron ◽  
Corrosion Potential ◽  
Nacl Solution ◽  
Σ Phase ◽  
High Entropy ◽  
Al Content ◽  
Crystal Phases

High-entropy AlxCoCrFe2.7MoNi (x = 0, 0.5, 1.0, 1.5, 2.0) alloy coatings were prepared on pure iron by laser cladding. The effects of Al content on the microstructure, hardness, wear resistance and corrosion resistance of the coatings were studied. The results showed that the crystal phases of the AlxCoCrFe2.7MoNi coatings changed from Mo-rich BCC1 + FCC to (Al, Ni)-rich BCC2 + Mo-rich BCC1 when x increased from 0 to 0.5, and the phase changed to an (Al, Ni)-rich BCC2 + (Mo, Cr)-rich σ phase as x increased further. The hardness of the coatings increased as the Al content increased. The Al2.0CoCrFe2.7MoNi coating exhibit best wear resistance. Addition of Al increased the corrosion potential in a 3.5 wt.% NaCl solution, and the coating with x = 1.0 exhibited the highest corrosion resistance.

scholarly journals Microstructures and Wear Resistance of FeCoCrNi-Mo High Entropy Alloy/Diamond Composite Coatings by High Speed Laser Cladding

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 300 ◽  
Author(s):  
Haijiang Wang ◽  
Wei Zhang ◽  
Yingbo Peng ◽  
Mingyang Zhang ◽  
Shuyu Liu ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Composite Coating ◽  
Laser Cladding ◽  
High Speed ◽  
Composite Coatings ◽  
Scanning Speed ◽  
High Entropy Alloy ◽  
Dilution Ratio ◽  
High Entropy ◽  
High Scanning Speed

FeCoCrNi-Mo high entropy alloy/diamond composite coatings were successfully prepared by high speed laser cladding. A high scanning speed was adopted (>30 mm/s), and the effects of laser power, scanning speed, and diamond content on the microstructure and wear resistance of the composite coating were studied. The processing parameters of laser cladding had significant influence on the dilution ratio, graphitization of diamond, and wear resistance of the composite coatings. When the laser cladding parameters were 3000 W of laser power and the high scanning speed of 50 mm/s, the composite coating exhibited a uniform microstructure, the lowest dilution ratio, and the best wear resistance. The wear resistance of the composite coating was enhanced with the addition of diamond, but microcracks also increased. When the amount of diamond was 15 wt.%, the best combination of microstructures and wear resistance was obtained.

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