Poly(phenylene thioether)s with Fluorene-Based Cardo Structure toward High Transparency, High Refractive Index, and Low Birefringence

2016 ◽  
Vol 49 (16) ◽  
pp. 5849-5856 ◽  
Author(s):  
Kazuhiro Nakabayashi ◽  
Takayuki Imai ◽  
Mao-Chun Fu ◽  
Shinji Ando ◽  
Tomoya Higashihara ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (6) ◽  
pp. 4377-4381 ◽  
Author(s):  
Chih-Yuan Hsu ◽  
Wei-Gang Han ◽  
Shu-Jen Chiang ◽  
Wen-Chiung Su ◽  
Ying-Ling Liu

Multi-functional branched polysiloxanes exhibiting good thermal stability, high thermal resistance, self-extinguishing properties, high transparency at ultraviolet to blue light region, and relatively high RI value (1.59).


2010 ◽  
Vol 20 (25) ◽  
pp. 5186 ◽  
Author(s):  
Woo Jin Bae ◽  
Markos Trikeriotis ◽  
Jing Sha ◽  
Evan L. Schwartz ◽  
Robert Rodriguez ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 515
Author(s):  
Kyungkuk Koh ◽  
Honglae Sohn

In this study, a fast curable polysiloxane-silphenylene hybrimer (PSH) was synthesized by the nonhydrolytic sol–gel condensation of phenyl-vinyl-oligosiloxane (PVO) and tris(dimethylhydrosilyl)benzene (TDMSB) under a Pt catalyst to investigate its optical property and thermal stability. The combination of PVO and tripod-type TDMSB results in a hybrimer with a fast curing time of 30 min. The PSH exhibited a high refractive index of 1.60, 1.59, and 1.58 at 450, 520, and 635 nm, respectively. High transmittance of 97% at 450 nm was obtained. The PSH exhibited a very high transmittance of 97% before thermal aging. The high optical transmittance of the PSH was only slightly decreased by 0.5% of the transmittance at 180 °C for 72 h after thermal aging, and high transparency was maintained almost constant even after 72 h of high-temperature treatment.


2019 ◽  
Author(s):  
Mohammad Atif Faiz Afzal ◽  
Mojtaba Haghighatlari ◽  
Sai Prasad Ganesh ◽  
Chong Cheng ◽  
Johannes Hachmann

<div>We present a high-throughput computational study to identify novel polyimides (PIs) with exceptional refractive index (RI) values for use as optic or optoelectronic materials. Our study utilizes an RI prediction protocol based on a combination of first-principles and data modeling developed in previous work, which we employ on a large-scale PI candidate library generated with the ChemLG code. We deploy the virtual screening software ChemHTPS to automate the assessment of this extensive pool of PI structures in order to determine the performance potential of each candidate. This rapid and efficient approach yields a number of highly promising leads compounds. Using the data mining and machine learning program package ChemML, we analyze the top candidates with respect to prevalent structural features and feature combinations that distinguish them from less promising ones. In particular, we explore the utility of various strategies that introduce highly polarizable moieties into the PI backbone to increase its RI yield. The derived insights provide a foundation for rational and targeted design that goes beyond traditional trial-and-error searches.</div>


2013 ◽  
Vol 28 (6) ◽  
pp. 671-676 ◽  
Author(s):  
Yu-Qing ZHANG ◽  
Li-Li ZHAO ◽  
Shi-Long XU ◽  
Chao ZHANG ◽  
Xiao-Ying CHEN ◽  
...  

Author(s):  
Zhiyou Li ◽  
Zao Yi ◽  
Tinting Liu ◽  
Li Liu ◽  
Xifang Chen ◽  
...  

In this paper, we designed a three-band narrowband perfect absorber based on Bulk Dirac semimetallic (BDS) metamaterials. The absorber consists of a hollow Dirac semimetallic layer above, a gold layer...


2021 ◽  
Author(s):  
Nicole Ziegenbalg ◽  
Ruth Lohwasser ◽  
Giovanni D’Andola ◽  
Torben Adermann ◽  
Johannes Christopher Brendel

Polyethersulfones are an interesting class of polymers for industrial applications due to their unusual properties such as a high refractive index, flame-retardant properties, high temperature and chemical resistance. The common...


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