scholarly journals Experimental realization of strain-induced room-temperature ferroelectricity in SrMnO3 films via selective oxygen annealing

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Hyunji An ◽  
Young-Gyun Choi ◽  
Yong-Ryun Jo ◽  
Hyo Jin Hong ◽  
Jeong-Kyu Kim ◽  
...  

AbstractAntiferromagnetic-paraelectric SrMnO3 (SMO) has aroused interest because of the theoretical strong coupling between the ferroelectric and ferromagnetic states with increasing epitaxial strain. In strained SMO films, the <110> polarized state and polar distortions have been observed, although high leakage currents and air degradation have limited their experimental verification. We herein provide a conclusive demonstration of room-temperature ferroelectricity and a high dielectric constant (εr = 138.1) in tensile-strained SMO by securing samples with insulating properties and clean surfaces using selective oxygen annealing. Furthermore, a paraelectricity and low dielectric constant (εr = 6.7) in the strain-relaxed SMO film have been identified as properties of the bulk SMO, which directly proves that the ferroelectricity of the tensile-strained SMO film is due to strain-induced polarization. We believe that these findings not only provide a cornerstone for exploring the physical properties of multiferroic SMO but also inspire new directions for single-phase multiferroics.

2020 ◽  
Vol 49 (7) ◽  
pp. 2218-2224 ◽  
Author(s):  
Siqian Chai ◽  
Jianbo Xiong ◽  
Yongshen Zheng ◽  
Rongchao Shi ◽  
Jialiang Xu

The as-synthesized 2D perovskite [C5H12N]2PbCl4 undergoes an above-room-temperature dielectric phase transition with a reversible pentahedral to octahedron transformation and a high dielectric constant being over twice of the low dielectric constant.


2012 ◽  
Vol 1397 ◽  
Author(s):  
Juan Li ◽  
Dengren Jin ◽  
Lixin Zhou ◽  
Jinrong Cheng

ABSTRACTHigh dielectric tunability, low dielectric loss tangent and appropriate level of dielectric constant are the basic requirements for applications as electrically tunable dielectric microwave devices. In our experiments, the SrTiO3 green compacts made of the powder mixtures with various particle sizes were infiltrated with a BaTiO3 precursor solution and sintered at different temperatures between 1280 and 1350 ºC for 2 hours and 1350 ºC for 6 hours. The sintering, microstructural and dielectric properties were investigated. Results showed that the relative density of SrTiO3 ceramics could reached 93% when sintered at 1280 ºC for 2 hours. When sintered for 6 hours at 1350 °C, the room temperature dielectric constant of SrTiO3 reaches 900 at a frequency of 1MHz. It has only weak temperature dependence between 100 and 500K. The reason of the low sintering temperature for the dense SrTiO3 ceramics and the effects of sintering scheme on the dielectric properties from 100 K to 500 K are discussed in this paper.


2018 ◽  
Vol 6 (9) ◽  
pp. 2370-2378 ◽  
Author(s):  
Yang Liu ◽  
Cheng Zhang ◽  
Benyuan Huang ◽  
Xu Wang ◽  
Yulong Li ◽  
...  

A novel skin–core structured fluorinated MWCNT nanofiller was prepared to fabricate epoxy composite with broadband high dielectric constant and low dielectric loss.


Author(s):  
Gyuseung Han ◽  
In Won Yeu ◽  
Kun Hee Ye ◽  
Seung-Cheol Lee ◽  
Cheol Seong Hwang ◽  
...  

Through DFT calculations, a Be0.25Mg0.75O superlattice having long apical Be–O bond length is proposed to have a high bandgap (>7.3 eV) and high dielectric constant (∼18) at room temperature and above.


RSC Advances ◽  
2017 ◽  
Vol 7 (38) ◽  
pp. 23309-23312 ◽  
Author(s):  
Ting Yang ◽  
Wenhui Xu ◽  
Xinwen Peng ◽  
Haoqing Hou

Crown ether-containing polyimides possess high dielectric constant and low dielectric loss, without sacrificing other properties.


2021 ◽  
Author(s):  
Shashwat Shukla ◽  
Gerald Wesley Patterson

&lt;p&gt;One of the unique candidates to explore the evolution of physical surface processes on the Moon is Tycho, a dark haloed impact crater representing well-preserved bright ray pattern and intact crater morphology. Sampling of the central peak in such complex crater formation proves significant in terms of unraveling intriguing science of the lunar interior. With the current state-of-the-art radar technology, it is possible to evaluate the response of the geologic features constrained in the near surface and subsurface regolith environments. This can be achieved by modelling the dielectric constant of media, which is a physical parameter crucial for furthering our knowledge about the distribution of materials within different stratigraphic layers at multiple depths. Here, we used the applicability of Mini-RF S-band data augmented with a deep learning based inversion model to retrieve the dielectric variations over the central peak of the Tycho crater. A striking observation is made in certain regions of the central peak, wherein we observe anomalously high dielectric constant, not at all differentiated in the hyperspectral image and first Stokes parameter image, which usually is a representation of retrieved backscatter of the target. The results are also supported by comparing the variations in the scattering mechanisms. We found those particular regions to be associated with high degree of depolarization, thereby attributing to the presence of cm- to m- scale scatterers buried within a low dielectric layer that are not big enough to produce even-bounce geometry for the radar wave. Moreover, we also observe high rock concentration in the central peak slopes from DIVINER data and NAC images, indicating the exposure of clasts ranging in size from 10 meter to 100s of meter. Furthermore, from surface temperature data, these distinctive outcrops sense warmer temperature at night than the surrounding, which suggests the existence of thermal skin depth in such vicinities. Interestingly, we are able to quantify the pessimistic dielectric constant limit of the large boulder in the middle of the central peak, observable at the Mini-RF radar wavelength, as 4.54 + j0.077. Compared to the expected dielectric constant of rocks, this value is lowered significantly. One probable reason could be the emergence of small radar shadows due to the rugged surface of the boulder on the radar illuminated portion. From our analysis, we showcase the anomalous dielectric variability of Tycho central peak, thereby providing new insights into the evolution of the impact cratering process that could be important for both science and necessary for framing human or robotic exploration strategies.&amp;#160;&amp;#160;&lt;/p&gt;


2012 ◽  
Vol 2012 (1) ◽  
pp. 000609-000616
Author(s):  
Beihai Ma ◽  
Manoj Narayanan ◽  
Shanshan Liu ◽  
Sheng Tong ◽  
U. (Balu) Balachandran

Ceramic film capacitors with high dielectric constant and high breakdown strength are promising for use in advanced power electronics, which would offer higher performance, improved reliability, and enhanced volumetric and gravimetric efficiencies. We have grown lead lanthanum zirconate titanate (PLZT) on nickel foils and platinized silicon (PtSi) substrates by chemical solution deposition. A buffer layer of LaNiO3 (LNO) was deposited on the nickel foils prior to the deposition of PLZT. We measured the following electrical properties for PLZT films grown on LNO buffered Ni and PtSi substrates, respectively: remanent polarization, ≈25.4 μC/cm2 and ≈10.1 μC/cm2; coercive electric field, ≈23.8 kV/cm and ≈27.9 kV/cm; dielectric constant at room temperature, ≈1300 and ≈1350; and dielectric loss at room temperature, ≈0.06 and ≈0.05. Weibull analysis determined the mean breakdown strength to be 2.6 MV/cm and 1.5 MV/cm for PLZT films grown on LNO buffered Ni and PtSi substrates, respectively. Residual stress analysis by x-ray diffraction revealed compressive stress of ≈-520 MPa in the ≈2-μm-thick PLZT grown on LNO buffered Ni foil, but a tensile stress of ≈210 MPa in the ≈2-μm-thick PLZT grown on PtSi substrates.


2016 ◽  
Vol 34 (2) ◽  
pp. 322-329 ◽  
Author(s):  
Wan Q. Cao ◽  
Ling F. Xu ◽  
Mukhlis M. Ismail ◽  
Li L. Huang

AbstractBaTiO3 ceramics doped with 0.40 mol% NaNbO3 were prepared using a traditional approach by sintering at temperature of 1250 °C to 1290 °C. The prepared ceramics was characterized by very good dielectric properties, such as high dielectric constant (1.5 × 105), low dielectric loss (0.1), and good dielectric temperature stability in the −40 °C to 100 °C range for the sample sintered below 1270 °C. The dielectric characteristics obtained with XPS confirmed that Ti4+ ions remain in the state without any change. The huge increase in dielectric constant in NaNbO3 doped BaTiO3 samples occurs when large amount of Ba2+ ions are excited to a high energy bound state of Ba2+ − e or Ba+ to create electron hopping conduction. For samples with the content of NaNbO3 higher than 0.40 mol%, or sintering temperature higher than 1280 °C, compensation effect is dominated by cation vacancies with sharply decreasing dielectric constant and increased dielectric loss. The polaron effect is used to explain the relevant mechanism of giant dielectric constant appearing in the ferroelectric phase.


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