scholarly journals Impact of interseismic deformation on phase transformations and rock properties in subduction zones

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Sebastian Cionoiu ◽  
Evangelos Moulas ◽  
Lucie Tajčmanová

AbstractPhase transformations greatly affect physical properties of rocks and impose a first-order control on geodynamic processes. Under high deformation rates, rheological heterogeneities cause large spatial variations of stress in materials. Until now, the impact of higher deformation rates, rock heterogeneity and stress build up on phase transformations and material properties is not well understood. Here we show, that phase transitions are controlled by the stress build-up during fast deformation. In a deformation experiment (600 °C, 1.47 GPa), rock heterogeneity was simulated by a strong elliptical alumina inclusion in a weak calcite matrix. Under deformation rates comparable to slow earthquakes, calcite transformed locally to aragonite matching the distribution of maximum principal stresses and pressure (mean stress) from mechanical models. This first systematic investigation documents that phase transformations occur in a dynamic system during deformation. The ability of rocks to react during fast deformation rates may have serious consequences on rock rheology and thus provide unique information on the processes leading to giant ruptures in subduction zones.

2021 ◽  
Vol 13 (6) ◽  
pp. 1087
Author(s):  
Yiren Chang ◽  
Zhiyong Xiao ◽  
Yang Liu ◽  
Jun Cui

Self-secondaries are a population of background secondaries, and they have been observed on top of impact melt and ballistically emplaced ejecta deposits on various planetary bodies. Self-secondaries are formed by impacts of sub-vertically launched ejecta, but the launch mechanism is not confirmed. The potential threat of self-secondaries to the theoretical and applicable reliability of crater chronology has been noted, but not constrained. Hitherto discovered self-secondaries were located around complex impact craters, but their potential existence around simple craters has not been discovered. Here we report the first discovery of self-secondaries around lunar cold spot craters, which are an extremely young population of simple craters formed within the past ~1 million years on the Moon. Self-secondaries are widespread on layers of cascading flow-like ejecta deposits around cold spot craters. The spatial density of self-secondaries dwarfs that of potential primary craters. The spatial distribution of self-secondaries is highly heterogeneous across the ejecta deposits. With respect to the impactor trajectory that formed cold spot craters, self-secondaries formed at the downrange of the ejecta deposits have the largest spatial density, while those at the uprange have the smallest density. This density pattern holds for all cold spot craters that were formed by non-vertical impacts, but self-secondaries do not exhibit other systematic density variations at different radial distances or at other azimuths with respect to the impactor trajectory. Among known mechanics of ejecting materials to the exterior of impact craters, impact spallation is the most likely scenario to account for the required large ejection velocities and angles to form self-secondaries. The production population of self-secondaries is estimated based on the highly diverse crater size-frequency distributions across the ejecta deposits of cold spot craters. For a better understanding of the impact history on the Moon, a systematic investigation for the effect of self-secondaries on lunar crater chronology is required.


Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 336
Author(s):  
Deniz Zengel ◽  
Simon Barth ◽  
Maria Casapu ◽  
Jan-Dierk Grunwaldt

Positioning the catalysts in front of the turbocharger has gained interest over recent years due to the earlier onset temperature and positive effect of elevated pressure. However, several challenges must be overcome, like presence of higher pollutant concentrations due to the absence or insufficient diesel oxidation catalyst volume at this location. In this context, our study reports a systematic investigation on the effect of pressure and various hydrocarbons during selective catalytic reduction (SCR) of NOx with NH3 over the zeolite-based catalysts Fe-ZSM-5 and Cu-SSZ-13. Using a high-pressure catalyst test bench, the catalytic activity of both zeolite catalysts was measured in the presence and absence of a variety of hydrocarbons under pressures and temperatures resembling the conditions upstream of the turbocharger. The results obtained showed that the hydrocarbons are incompletely converted over both catalysts, resulting in numerous byproducts. The emission of hydrogen cyanide seems to be particularly problematic. Although the increase in pressure was able to improve the oxidation of hydrocarbons and significantly reduce the formation of HCN, sufficiently low emissions could only be achieved at high temperatures. Regarding the NOx conversion, a boost in activity was obtained by increasing the pressure compared to atmospheric reaction conditions, which compensated the negative effect of hydrocarbons on the SCR activity.


2016 ◽  
Author(s):  
V. Ndonhong ◽  
E. Belostrino ◽  
D. Zhu ◽  
A. D. Hill ◽  
R. E. Beckham ◽  
...  

2020 ◽  
Author(s):  
Satoru Baba ◽  
Shunsuke Takemura ◽  
Kazushige Obara ◽  
Akemi Noda

Author(s):  
R. J. Dennis ◽  
R. Kulka ◽  
O. Muransky ◽  
M. C. Smith

A key aspect of any numerical simulation to predict welding induced residual stresses is the development and application of an appropriate material model. Often significant effort is expended characterising the thermal, physical and hardening properties including complex phenomena such as high temperature annealing. Consideration of these aspects is sufficient to produce a realistic prediction for austenitic steels, however ferritic steels are susceptible to solid state phase transformations when heated to high temperatures. On cooling a reverse transformation occurs, with an associated volume change at the isothermal transformation temperature. Although numerical models exist (e.g. Leblond) to predict the evolution of the metallurgical phases, accounting for volumetric changes, it remains a matter of debate as to the magnitude of the impact of phase transformations on residual stresses. Often phase transformations are neglected entirely. In this work a simple phase transformation model is applied to a range of welded structures with the specific aim of assessing the impact, or otherwise, of phase transformations on the magnitude and distribution of predicted residual stresses. The welded structures considered account for a range of geometries from a simple ferritic beam specimen to a thick section multi-pass weld. The outcome of this work is an improved understanding of the role of phase transformation on residual stresses and an appreciation of the circumstances in which it should be considered.


2017 ◽  
Vol 15 (1) ◽  
pp. 70-76 ◽  
Author(s):  
Francesco Paolo La Mantia ◽  
Manuela Ceraulo ◽  
Maria Chiara Mistretta ◽  
Marco Morreale

Purpose Biodegradable polymers are currently gaining importance in several fields, because they allow mitigation of the impact on the environment related to disposal of traditional, nonbiodegradable polymers, as well as reducing the utilization of oil-based sources (when they also come from renewable resources). Fibers made of biodegradable polymers are of particular interest, though, it is not easy to obtain polymer fibers with suitable mechanical properties and to tailor these to the specific application. The main ways to tailor the mechanical properties of a given biodegradable polymer fiber are based on crystallinity and orientation control. However, crystallinity can only marginally be modified during processing, while orientation can be controlled, either during hot drawing or cold stretching. In this paper, a systematic investigation of the influence of cold stretching on the mechanical and thermomechanical properties of fibers prepared from different biodegradable polymer systems was carried out. Methods Rheological and thermal characterization helped in interpreting the orientation mechanisms, also on the basis of the molecular structure of the polymer systems. Results and conclusions It was found that cold drawing strongly improved the elastic modulus, tensile strength and thermomechanical resistance of the fibers, in comparison with hot-spun fibers. The elastic modulus showed higher increment rates in the biodegradable systems upon increasing the draw ratio.


2021 ◽  
pp. petgeo2020-095
Author(s):  
Michael J. Steventon ◽  
Christopher A-L. Jackson ◽  
Howard D. Johnson ◽  
David M. Hodgson ◽  
Sean Kelly ◽  
...  

The geometry, distribution, and rock properties (i.e. porosity and permeability) of turbidite reservoirs, and the processes associated with turbidity current deposition, are relatively well known. However, less attention has been given to the equivalent properties resulting from laminar sediment gravity-flow deposition, with most research limited to cogenetic turbidite-debrites (i.e. transitional flow deposits) or subsurface studies that focus predominantly on seismic-scale mass-transport deposits (MTDs). Thus, we have a limited understanding of the ability of sub-seismic MTDs to act as hydraulic seals and their effect on hydrocarbon production, and/or carbon storage. We investigate the gap between seismically resolvable and sub-seismic MTDs, and transitional flow deposits on long-term reservoir performance in this analysis of a small (<10 km radius submarine fan system), Late Jurassic, sandstone-rich stacked turbidite reservoir (Magnus Field, northern North Sea). We use core, petrophysical logs, pore fluid pressure, quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN), and 3D seismic-reflection datasets to quantify the type and distribution of sedimentary facies and rock properties. Our analysis is supported by a relatively long (c. 37 years) and well-documented production history. We recognise a range of sediment gravity deposits: (i) thick-/thin- bedded, structureless and structured turbidite sandstone, constituting the primary productive reservoir facies (c. porosity = 22%, permeability = 500 mD), (ii) a range of transitional flow deposits, and (iii) heterogeneous mud-rich sandstones interpreted as debrites (c. porosity = <10%, volume of clay = 35%, up to 18 m thick). Results from this study show that over the production timescale of the Magnus Field, debrites act as barriers, compartmentalising the reservoir into two parts (upper and lower reservoir), and transitional flow deposits act as baffles, impacting sweep efficiency during production. Prediction of the rock properties of laminar and transitional flow deposits, and their effect on reservoir distribution, has important implications for: (i) exploration play concepts, particularly in predicting the seal potential of MTDs, (ii) pore pressure prediction within turbidite reservoirs, and (iii) the impact of transitional flow deposits on reservoir quality and sweep efficiency.Supplementary material:https://doi.org/10.6084/m9.figshare.c.5313860


Author(s):  
Raquel P. Felix ◽  
Judith A. Hubbard ◽  
James D. P. Moore ◽  
Adam D. Switzer

ABSTRACT The frontal sections of subduction zones are the source of a poorly understood hazard: “tsunami earthquakes,” which generate larger-than-expected tsunamis given their seismic shaking. Slip on frontal thrusts is considered to be the cause of increased wave heights in these earthquakes, but the impact of this mechanism has thus far not been quantified. Here, we explore how frontal thrust slip can contribute to tsunami wave generation by modeling the resulting seafloor deformation using fault-bend folding theory. We then quantify wave heights in 2D and expected tsunami energies in 3D for both thrust splays (using fault-bend folding) and down-dip décollement ruptures (modeled as elastic). We present an analytical solution for the damping effect of the water column and show that, because the narrow band of seafloor uplift produced by frontal thrust slip is damped, initial tsunami heights and resulting energies are relatively low. Although the geometry of the thrust can modify seafloor deformation, water damping reduces these differences; tsunami energy is generally insensitive to thrust ramp parameters, such as fault dip, geological evolution, sedimentation, and erosion. Tsunami energy depends primarily on three features: décollement depth below the seafloor, water depth, and coseismic slip. Because frontal ruptures of subduction zones include slip on both the frontal thrust and the down-dip décollement, we compare their tsunami energies. We find that thrust ramps generate significantly lower energies than the paired slip on the décollement. Using a case study of the 25 October 2010 Mw 7.8 Mentawai tsunami earthquake, we show that although slip on the décollement and frontal thrust together can generate the required tsunami energy, &lt;10% was contributed by the frontal thrust. Overall, our results demonstrate that the wider, lower amplitude uplift produced by décollement slip must play a dominant role in the tsunami generation process for tsunami earthquakes.


2004 ◽  
Vol 120 ◽  
pp. 129-136
Author(s):  
M. Przyłęcka ◽  
W. Gęstwa ◽  
G. E. Totten

There are a variety of opinions regarding the influence of retained austenite and carbides on the properties exhibited by carbonitrided steels. In this paper, the development of a model marking relationship between phase composition, and properties of hardened carbonitrided steel has been presented. A summary of the impact of structure on properties is provided in Table 1. In the study reported here, the impact of thermal processing conditions on retained austenite and carbides was examined for carbonitrided and hardened 20 (C22), 20H (20Cr4), 15HN (17CrNi6-6) and 16HG (16MnCr5) steels. The models that are reported were experimentally validated. In particular, the results obtained for structure with respect to hardness and abrasive wear resistance were discussed for carbonitrided and hardened 20H (20Cr4) steel.


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