scholarly journals Computational simulation and modelling of uranium extraction using tributylphosphate through membrane extractor

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Rahmad Syah ◽  
Dadan Ramadan ◽  
Marischa Elveny ◽  
Yan Cao ◽  
Afrasyab Khan ◽  
...  

AbstractNon-disperse solvent extraction is an effective technique for the extraction of metal ions from aqueous solution. In this study, uranium extraction using n-dodecane solvent containing tributylphosphate extractant in a membrane contactor was investigated. A 2D mathematical model was developed for the fluid flow and mass transfer in the hollow fibre membrane extractor. The equations of the created model were solved using the finite element method. The uranium concentration distribution in the extractor at different extractant concentrations as well as feed acidity was studied. The results showed that there is reasonable good agreement between experimental uranium extraction and modelling outputs at different extractant concentrations. Increasing extractant concentration from 5 to 30% led to the enhancement of uranium extraction from 2.60 to 34.13%. Also, there was an increase in the uranium extraction with increasing feed acidity in the range of 1–3 M. Furthermore, based on the radial uranium concentration distribution, it was found that the main mass transfer resistance in the system was microporous membrane section. Finally, it was obtained that the uranium extraction efficiency could be improved significantly by increasing porosity-to-tortuosity ratio. It was concluded that the membrane specification plays the most important role as the dominant mass transfer resistant was in the membrane subdomain.

1992 ◽  
Vol 20 (4) ◽  
pp. 230-253 ◽  
Author(s):  
T. Akasaka ◽  
K. Kabe ◽  
M. Koishi ◽  
M. Kuwashima

Abstract The deformation behavior of a tire in contact with the roadway is complicated, in particular, under the traction and braking conditions. A tread rubber block in contact with the road undergoes compression and shearing forces. These forces may cause the loss of contact at the edges of the block. Theoretical analysis based on the energy method is presented on the contact deformation of a tread rubber block subjected to compressive and shearing forces. Experimental work and numerical calculation by means of the finite element method are conducted to verify the predicted results. Good agreement is obtained among these analytical, numerical, and experimental results.


2003 ◽  
Vol 3 (1-2) ◽  
pp. 201-207
Author(s):  
H. Nagaoka ◽  
T. Nakano ◽  
D. Akimoto

The objective of this research is to investigate mass transfer mechanism in biofilms under oscillatory flow conditions. Numerical simulation of turbulence near a biofilm was conducted using the low Reynold’s number k-ɛ turbulence model. Substrate transfer in biofilms under oscillatory flow conditions was assumed to be carried out by turbulent diffusion caused by fluid movement and substrate concentration profile in biofilm was calculated. An experiment was carried out to measure velocity profile near a biofilm under oscillatory flow conditions and the influence of the turbulence on substrate uptake rate by the biofilm was also measured. Measured turbulence was in good agreement with the calculated one and the influence of the turbulence on the substrate uptake rate was well explained by the simulation.


1985 ◽  
Vol 50 (3) ◽  
pp. 745-757 ◽  
Author(s):  
Andreas Zahn ◽  
Lothar Ebner ◽  
Kurt Winkler ◽  
Jan Kratochvíl ◽  
Jindřich Zahradník

The effect of two-phase flow regime on decisive hydrodynamic and mass transfer characteristics of horizontal-tube gas-liquid reactors (pressure drop, liquid holdup, kLaL) was determined in a cocurrent-flow experimental unit of the length 4.15 m and diameter 0.05 m with air-water system. An adjustable-height weir was installed in the separation chamber at the reactor outlet to simulate the effect of internal baffles on reactor hydrodynamics. Flow regime maps were developed in the whole range of experimental gas and liquid flow rates both for the weirless arrangement and for the weir height 0.05 m, the former being in good agreement with flow-pattern boundaries presented by Mandhane. In the whole range of experi-mental conditions pressure drop data could be well correlated as a function of gas and liquid flow rates by an empirical exponential-type relation with specific sets of coefficients obtained for individual flow regimes from experimental data. Good agreement was observed between values of pressure drop obtained for weirless arrangement and data calculated from the Lockhart-Martinelli correlation while the contribution of weir to the overall pressure drop was well described by a relation proposed for the pressure loss in closed-end tubes. In the region of negligible weir influence values of liquid holdup were again succesfully correlated by the Lockhart-Martinelli relation while the dependence of liquid holdup data on gas and liquid flow rates obtained under conditions of significant weir effect (i.e. at low flow rates of both phases) could be well described by an empirical exponential-type relation. Results of preliminary kLaL measurements confirmed the decisive effect of the rate of energy dissipation on the intensity of interfacial mass transfer in gas-liquid dispersions.


2021 ◽  
Vol 2 (3) ◽  
pp. 542-558
Author(s):  
Mohammadmehdi Shahzamanian ◽  
David Lloyd ◽  
Amir Partovi ◽  
Peidong Wu

The effect of the width to thickness ratio on the bendability of sheet metal is investigated using the finite element method (FEM) employing the Gurson–Tvergaard–Needleman (GTN) model. Strain path changes in the sheet with change in the width/thickness ratio. It is shown that bendability and fracture strain increase significantly by decrease in the width/thickness ratio. The stress state is almost uniaxial when the stress ratio (α) is close to zero for narrow sheets. Stress ratio is nothing but the major stress to minor stress ratio. This delays the growth and coalescence of micro-voids as the volumetric strain and stress triaxiality (pressure/effective stress) decrease. On the other hand, ductility decreases with increase in α for wider sheets. Fracture bending strain is calculated and, as expected, it increases with decrease in the width/thickness ratio. Furthermore, a brief study is performed to understand the effect of superimposed hydrostatic pressure on fracture strain for various sheet metals with different width/thickness ratios. It is found that the superimposed hydrostatic pressure increases the ductility, and that the effect of the width/thickness ratio in metals on ductility is as significant as the effect of superimposed hydrostatic pressure. Numerical results are found to be in good agreement with experimental observations.


1987 ◽  
Vol 109 (2) ◽  
pp. 89-93 ◽  
Author(s):  
P. Gandhidasan ◽  
M. Rifat Ullah ◽  
C. F. Kettleborough

Heat and mass transfer analysis between a desiccant-air contact system in a packed tower has been studied in application to air dehumidification employing liquid desiccant, namely calcium chloride. Ceramic 2 in. Raschig rings are used as the packing material. To predict the tower performance, a steady-state model which considers the heat and mass transfer resistances of the gas phase and the mass transfer resistance of the liquid phase is developed. The governing equations are solved on a digital computer to simulate the performance of the tower. The various parameters such as the effect of liquid concentration and temperature, air temperature and humidity and the rates of flow of air and liquid affecting the tower performance have been discussed.


Author(s):  
Виктор Григорьевич Чеверев ◽  
Евгений Викторович Сафронов ◽  
Алексей Александрович Коротков ◽  
Александр Сергеевич Чернятин

Существуют два основных подхода решения задачи тепломассопереноса при численном моделировании промерзания грунтов: 1) решение методом конечных разностей с учетом граничных условий (границей, например, является фронт промерзания); 2) решение методом конечных элементов без учета границ модели. Оба подхода имеют существенные недостатки, что оставляет проблему решения задачи для численной модели промерзания грунтов острой и актуальной. В данной работе представлена физическая постановка промерзания, которая позволяет создать численную модель, базирующуюся на решении методом конечных элементов, но при этом отражающую ход фронта промерзания - то есть модель, в которой объединены оба подхода к решению задачи промерзания грунтов. Для подтверждения корректности модели был проделан ряд экспериментов по физическому моделированию промерзания модельного грунта и выполнен сравнительный анализ полученных экспериментальных данных и результатов расчетов на базе представленной численной модели с такими же граничными условиями, как в экспериментах. There are two basic approaches to solving the problem of heat and mass transfer in the numerical modeling of soil freezing: 1) using the finite difference method taking into account boundary conditions (the boundary, for example, is the freezing front); 2) using the finite element method without consideration of model boundaries. Both approaches have significant drawbacks, which leaves the issue of solving the problem for the numerical model of soil freezing acute and up-to-date. This article provides the physical setting of freezing that allows us to create a numerical model based on the solution by the finite element method, but at the same time reflecting the route of the freezing front, i.e. the model that combines both approaches to solving the problem of soil freezing. In order to confirm the correctness of the model, a number of experiments on physical modeling of model soil freezing have been performed, and a comparative analysis of the experimental data obtained and the calculation results based on the provided numerical model with the same boundary conditions as in the experiments was performed.


2018 ◽  
Vol 82 (2) ◽  
pp. 21001
Author(s):  
Grzegorz Tytko ◽  
Leszek Dziczkowski

The paper examines the problem of an axially symmetric I-cored coil located above a three-layered plate with a hole in the middle layer. A cylindrical coordinate system was applied, wherein the solution domain was truncated in the radial direction. The employment of the truncated region eigenfunction expansion (TREE) method resulted in deriving the final formulas for the change of the coil impedance with regard to the air space, and also pertaining to the test object without a flaw. Formulas for various configurations of the test object, among others for a surface hole, a subsurface hole and a through hole, have been presented. For the purpose of defectoscopy, the influence of the hole in the plate on the impedance components was investigated. The calculations were made in Matlab for frequencies from 100 Hz to 50 kHz. The obtained results were verified using the finite element method (FEM) in Comsol Multiphysics package. A very good agreement was observed in the case of both the resistance and reactance.


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