K+ located in 6-membered rings of low-silica CHA enhancing the lifetime and propene selectivity in MTO

Author(s):  
Jingyan Zhang ◽  
Ren Li ◽  
Yangyang Mi ◽  
Peng Luo ◽  
Hao Xu ◽  
...  

Methanol-to-olefin (MTO) technology presently serves as a key to convert coal or natural gas to valuable hydrocarbons in particular lower olefins. This work focuses on developing low cost and environmentally...

Author(s):  
André Perpignan V. de Campos ◽  
Fernando L. Sacomano Filho ◽  
Guenther C. Krieger Filho

Gas turbines are reliable energy conversion systems since they are able to operate with variable fuels and independently from seasonal natural changes. Within that reality, micro gas turbines have been increasing the importance of its usage on the onsite generation. Comparatively, less research has been done, leaving more room for improvements in this class of gas turbines. Focusing on the study of a flexible micro turbine set, this work is part of the development of a low cost electric generation micro turbine, which is capable of burning natural gas, LPG and ethanol. It is composed of an originally automotive turbocompressor, a combustion chamber specifically designed for this application, as well as a single stage axial power turbine. The combustion chamber is a reversed flow type and has a swirl stabilized combustor. This paper is dedicated to the diagnosis of the natural gas combustion in this chamber using computational fluid dynamics techniques compared to measured experimental data of temperature inside the combustion chamber. The study emphasizes the near inner wall temperature, turbine inlet temperature and dilution holes effectiveness. The calculation was conducted with the Reynolds Stress turbulence model coupled with the conventional β-PDF equilibrium along with mixture fraction transport combustion model. Thermal radiation was also considered. Reasonable agreement between experimental data and computational simulations was achieved, providing confidence on the phenomena observed on the simulations, which enabled the design improvement suggestions and analysis included in this work.


Author(s):  
Peter A. Napoli ◽  
Lindsey Sampson ◽  
Robin Davidov ◽  
Bettina Kamuk

This topic is important because of the growing need for us to produce and supply low cost energy for public consumption. Demand has increased exponentially, and in order to reduce dependence on foreign oil, coal, and natural gas we need to utilize waste to its full potential. Three major waste to energy plant expansions are happening now at Olmstead WTE, Minnesota and at Lee and Hillsborough Counties, in Florida. New “Greenfield” construction is planned at Harford, Carroll, and Fredrick Counties, in Maryland.


Author(s):  
Derek Johnson ◽  
Mahdi Darzi ◽  
Chris Ulishney ◽  
Mehar Bade ◽  
Nima Zamani

Two-stroke engines are often used for their low cost, simplicity, and power density. However, these engines suffer efficiency penalties due to fuel short-circuiting. Increasing power density has previously been an area of focus for performance two-stroke engines — such as in dirt bikes. Smaller-displacement engines have also been used to power remote controlled cars, boats, and aircraft. These engines typically rely on gasoline or higher-octane liquid fuels. However, natural gas is an inherently knock-resistant fuel and small natural gas engines and generators could see increased market penetration. Power generators typically operate at a fixed frequency with varied load, which can take advantage of intake and exhaust system tuning. In addition, stationary engines may not be subject to size restrictions of optimal intake and exhaust systems. This paper examines methods to improve combustion stability, efficiency, and power density of a 29cc air-cooled two-stroke engine converted to operate on natural gas. Initial conversion showed significant penalties on delivery ratio, which lowered power density and efficiency. To overcome these issues a tuned intake pipe, two exhaust resonators, and a combustion dome were designed and tested. The engine was operated at 5400 RPM and fueling was adjusted to yield maximum brake-torque (MBT). All tests were conducted under wide-open throttle conditions. The intake and exhaust systems were designed based on Helmholtz resonance theory and empirical data. The engine utilized a two-piece cylinder head with removable combustion dome. The combustion dome was modified for optimal compression ratio while decreasing squish area and volume. With all designs incorporated, power increased from 0.22 kW to 1.07 kW — a factor of 4.86. Efficiency also increased from 7% to 12%. In addition to these performance gains, the coefficient of variation (COV) of indicated mean effective pressure (IMEP) decreased from just above 11% to less than 4%.


Author(s):  
Fábio C. Barbosa

Freight rail carriers have been continuously challenged to reduce costs and comply with increasingly stringent environmental standards, into a continuously competing and environmentally driven industry. In this context, current availability and relative abundance of clean and low cost non conventional gas reserves have aroused a comprehensive reevaluation of rail industry into fuel option, especially where freight rail are strongly diesel based. Countries in which rail sector is required to play an important role in transport matrix, where fuel expenditures currently accounts for a significant share of operational costs, like Australia, Brazil, United States and other continental countries, can be seen as strong candidates to adopt fuel alternatives to diesel fueled freight railways. Moreover, from an environmental perspective, the use of alternative fuels (like natural gas) for locomotive traction may allow rail freight carriers to comply with emission standards into a less technologically complex and costly way. In this context, liquefied natural gas (LNG) fueled freight locomotives are seen as a strong potential near-term driver for natural gas use in rail sector, with its intrinsic cost and environmental benefits and with the potential to revolutionize rail industry much like the transition from steam to diesel experienced into the fifties, as well as the more recent advent of use of alternating current diesel-electric locomotives. LNG rail fueled approach has been focused on both retrofitting existing locomotive diesel engines, as well as on original manufactured engines. Given the lower polluting potential of natural gas heavy engines, when compared to diesel counterparts, LNG locomotives can be used to comply with increasingly restrictive Particulate Matter (PM) and Nitrogen Oxides (NOx) emission standards with less technological complexity (engine design and aftertreatment hardware) and their intrinsic lower associated costs. Prior to commercial operation of LNG locomotives, there are some technical, operational and economic hurdles that need to be addressed, i.e. : i) locomotive engine and fuel tender car technological maturity and reliability improvement; ii) regulation improvement, basically focused on operational safety and interchange operations; iii) current and long term diesel - gas price differential, a decisive driver, and, finally, iv) LNG infrastructure requirements (fueling facilities, locomotives and tender car specifications). This work involved an extensive research into already published works to present an overview of LNG use in freight rail industry into a technical, operational and economical perspective, followed by a critical evaluation of its potential into some relevant freight rail markets, such as United States, Brazil and Australia, as well as some European non electrified rail freight lines.


Methane ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 24-37
Author(s):  
Muhammad Alfiza Farhan ◽  
Yuichi Sugai ◽  
Nuhindro Priagung Widodo ◽  
Syafrizal Syafrizal

The leakage of methane from the subsurface on the coalfield or natural gas field invariably becomes an important issue nowadays. In notable addition, materials such as activated carbon, zeolites, and Porapak have been successfully identified as adsorbents. Those adsorbents could adsorb methane at atmospheric pressure and room temperature. Therefore, in this scholarly study, a new method using adsorbents to detect points of methane leakage that can cover a wide-scale area was developed. In the beginning, the most capable adsorbent should be determined by quantifying adsorbed methane amount. Furthermore, checking the possibility of adsorption in the column diffusion and desorption method of adsorbents is equally necessary. The most capable adsorbent was activated carbon (AC), which can adsorb 1.187 × 10−3 mg-CH4/g-AC. Hereinafter, activated carbon successfully can adsorb methane through column diffusion, which simulates the situation of on-site measurement. The specific amount of adsorbed methane when the initial concentrations of CH4 in a bag were 200 ppm, 100 ppm, and 50 ppm was found to be 0.818 × 10−3 mg-CH4/g-AC, 0.397 × 10−3 mg-CH4/g-AC, 0.161 × 10−3 mg-CH4/g-AC, respectively. Desorption of activated carbon analysis shows that methane concentration increases during an hour in the temperature bath under 80 °C. In conclusion, soil methane leakage points can be detected using activated carbon by identifying the observed methane concentration increase.


1986 ◽  
Author(s):  
V.A. Kuuskraa ◽  
D.E. Wicks
Keyword(s):  

2018 ◽  
Vol 43 ◽  
pp. 01001 ◽  
Author(s):  
Siew-Pei Lee ◽  
N. Mellon ◽  
Azmi M. Shariff ◽  
Jean-Marc Leveque

Development of covalent organic polymer (COP) is a potential new class of adsorbent for CO2 separation from natural gas mainly due to their good hydrothermal stability, chemical tuning flexibility and low cost. CO2 and methane adsorption on COP-1 was studied under atmospheric condition (101.3 kPa, 298 K). COP-1 was synthesized via catalyst-free polycondensation of cyanuric chloride and piperazine. The properties of COP-1 were characterized using several analytical methods such as Fourier Transform Infra-Red (FTIR), N2 adsorption and desorption measurement and Field Transmission Electron Microscopy in coupled of Energy Dispersive X-ray Spectroscopy (FESEM-EDS). Reversible CO2 adsorption isotherm on COP-1 reflects low heat of adsorption which is beneficial to energy minimization in adsorbent regeneration process. Furthermore, moderate specific surface area COP-1 (88.5 m2/g) shows about nine times CO2 uptake higher than methane. The highly selective adsorption performance provides a promising insight in application of COP adsorbent for CO2 removal in natural gas field.


1996 ◽  
Vol 454 ◽  
Author(s):  
Z. C. Kang ◽  
Z. L. Wang

ABSTRACTA mixed-valent oxide-catalytic carbonization (MVOCC) process is described for synthesizing monodispersed carbon spheres (or tubes) in macroscopic quantities at low cost. The technique uses natural gas and reusable catalysts and produces no environmental waste or pollution. The product is controlled to be either all of spheres (∼ 210 nm) or all of tubes with high purity (> 95 %). In spherical form, the product is solid and comprised of layered graphitic flakes containing paired pentagonal-heptagonal carbon-rings. In spiral tube form, the product is composed of twisted graphitic helix layers containing spherical nodes. A growth mechanism has been proposed, in which the pairing of pentagonal and heptagonal carbon-rings plays an important role. It is concluded that a change in fraction and nucleation rates of pentagonal, hexagonal and heptagonal carbon-rings results in the growth of different geometrical shapes. The success of using mixed-valence metal oxides as catalysts has opened a new field in catalysis research and applications.


Subject Energy diversification efforts. Significance The El Nino weather phenomenon has laid bare the vulnerabilities of South America's dependence on hydropower. Gas has been the primary back-up, and liquefied natural gas (LNG) import capacity a strategic necessity (one which the northern part of the continent lacks). However, a recovery in Argentine gas production could eventually change the region's current gas balance, while the growth of renewables offers a new, indigenous, low-cost energy source. Impacts Investment in LNG import capacity and gas storage will continue. However, facilities face the threat of low utilisation as renewables capacity and domestic gas production increases. As one of the cheapest forms of electricity generation with a large amount of unexploited resource, hydropower will expand. States will gradually look towards other forms of system flexibility and grid resilience.


Author(s):  
Harry Miller ◽  
Anders T. Johnson ◽  
Markus Ahrens ◽  
T. Kenton Flanery

A team forms to address the challenge of low cost, low maintenance gas compression that can be quickly ramped up to meet peak demands. The Natural Gas Industry recognizes the importance of efficient, flexible compression equipment for the transmission of gas. In the early 1900s the Gas Industry met its compression objectives with many small reciprocating compressor units. As competition increased, Gas Companies began employing more cost effective larger units 3.7 MW (5,000 bhp) and eventually gas turbines 11+ MW (15,000+ bhp) became the prime mover of choice. While gas fired engine driven compressors are convenient for gas companies; they are becoming increasingly difficult to install. Environmental restrictions have tightened making permitting difficult. The larger gas turbine units seemed a solution because they were the low capital cost prime mover and clean burning. However, gas turbines have not yet achieved the high degree of flexibility and fuel efficiency gas transporters hoped. Flexibility has become an increasingly important issue because of the new “Peaking Power Plants” that are coming online. Gas companies are trying to solve the problem of low cost, low maintenance compression that can be quickly ramped up to meet peak demands. The idea of using electric motors to drive compressors to minimize the environmental, regulatory, and maintenance issues is not new. The idea of installing an electrically powered, highly flexible, efficient, low maintenance compressor unit directly into the pipeline feeding the load, possibly underground where it won’t be seen or heard, is a new and viable way for the gas and electric industries to do business together. This paper examines the application of totally enclosed, variable speed electric motor driven gas compressors to applications requiring completely automated, low maintenance, quick response gas pressure boosters. In this paper we will describe how a natural gas transporter, compressor manufacturer, motor manufacturer, and power company have teamed up to design the world’s first gas compressor that can be installed directly in the pipeline. We will discuss methodologies for installing the proposed compressor, the environmental benefits — no emissions, a small footprint, minimal noise — and the benefit of being able to install compression exactly where it is needed to meet the peaking requirements of today’s new loads.


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