scholarly journals Precise fabrication of porous polymer frameworks using rigid polyisocyanides as building blocks: from structural regulation to efficient iodine capture

2022 ◽  
Author(s):  
Xun-Hui Xu ◽  
Yan-Xiang Li ◽  
Li Zhou ◽  
Na Liu ◽  
Zong-Quan Wu
Keyword(s):  
Pore Size ◽  
High Efficiency ◽  
High Capacity ◽  
Building Blocks ◽  
Porous Polymer ◽  
Structural Regulation ◽  
Very High

Macroporous polymer frameworks with a tunable pore size were readily prepared using 4-arm rod-like polymers as building blocks. They showed excellent iodine capture performance with very high efficiency (1 minute) and high capacity (574%).

Resorcinarene Cavitand Polymers for the Remediation of Halomethanes and 1,4-Dioxane

2019 ◽  
Author(s):  
Luke Skala ◽  
Anna Yang ◽  
Max Justin Klemes ◽  
Leilei Xiao ◽  
William Dichtel
Keyword(s):  
Drinking Water ◽  
Activated Carbon ◽  
High Capacity ◽  
The United States ◽  
Water Sources ◽  
Disinfection Byproducts ◽  
Porous Polymer ◽  
Organic Micropollutants ◽  
Executive Summary ◽  
Regulatory Limits

<p>Executive summary: Porous resorcinarene-containing polymers are used to remove halomethane disinfection byproducts and 1,4-dioxane from water.<br></p><p><br></p><p>Disinfection byproducts such as trihalomethanes are some of the most common micropollutants found in drinking water. Trihalomethanes are formed upon chlorination of natural organic matter (NOM) found in many drinking water sources. Municipalities that produce drinking water from surface water sources struggle to remain below regulatory limits for CHCl<sub>3</sub> and other trihalomethanes (80 mg L<sup>–1</sup> in the United States). Inspired by molecular CHCl<sub>3</sub>⊂cavitand host-guest complexes, we designed a porous polymer comprised of resorcinarene receptors. These materials show higher affinity for halomethanes than a specialty activated carbon used for trihalomethane removal. The cavitand polymers show similar removal kinetics as activated carbon and have high capacity (49 mg g<sup>–1</sup> of CHCl<sub>3</sub>). Furthermore, these materials maintain their performance in real drinking water and can be thermally regenerated under mild conditions. Cavitand polymers also outperform activated carbon in their adsorption of 1,4-dioxane, which is difficult to remove and contaminates many public water sources. These materials show promise for removing toxic organic micropollutants and further demonstrate the value of using supramolecular chemistry to design novel absorbents for water purification.<br></p>

Electrochemical Oxidative Esterification of Thiophenols: Efficient Access to Sulfinic Esters

2020 ◽  
Vol 17 (7) ◽  
pp. 540-547
Author(s):  
Chun-Hui Yang ◽  
Cheng Wu ◽  
Jun-Ming Zhang ◽  
Xiang-Zhang Tao ◽  
Jun Xu ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Efficient Method ◽  
High Efficiency ◽  
Building Blocks ◽  
Constant Current ◽  
Good Efficiency ◽  
Oxidative Esterification ◽  
Efficient Access ◽  
New Applications ◽  
Sulfinic Esters

Background: The sulfinic esters are important and useful building blocks in organic synthesis. Objective: The aim of this study was to develop a simple and efficient method for the synthesis of sulfinic esters. Materials and Methods: Constant current electrolysis from thiols and alcohols was selected as the method for the synthesis of sulfinic esters. Results and Discussion: A novel electrochemical method for the synthesis of sulfinic esters from thiophenols and alcohols has been developed. Up to 27 examples of sulfinic esters have been synthesized using the current methods. This protocol shows good functional group tolerance as well as high efficiency. In addition, this protocol can be easily scaled up with good efficiency. Notably, heterocycle-containing substrates, including pyridine, thiophene, and benzothiazole, gave the desired products in good yields. A plausible reaction mechanism is proposed. Conclusion: This research not only provides a green and efficient method for the synthesis of sulfinic esters but also shows new applications of electrochemistry in organic synthesis. It is considered that this green and efficient synthetic protocol used to prepare sulfinic esters will have good applications in the future.

scholarly journals Near quantitative synthesis of urea macrocycles enabled by bulky N-substituent

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yingfeng Yang ◽  
Hanze Ying ◽  
Zhixia Li ◽  
Jiang Wang ◽  
Yingying Chen ◽  
...  
Keyword(s):  
High Efficiency ◽  
Molecular Structures ◽  
High Yield ◽  
Kinetic Control ◽  
High Concentration ◽  
Weak Association ◽  
Quantitative Synthesis ◽  
Thermodynamic Stabilization ◽  
Discrete Structures ◽  
Very High

AbstractMacrocycles are unique molecular structures extensively used in the design of catalysts, therapeutics and supramolecular assemblies. Among all reactions reported to date, systems that can produce macrocycles in high yield under high reaction concentrations are rare. Here we report the use of dynamic hindered urea bond (HUB) for the construction of urea macrocycles with very high efficiency. Mixing of equal molar diisocyanate and hindered diamine leads to formation of macrocycles with discrete structures in nearly quantitative yields under high concentration of reactants. The bulky N-tert-butyl plays key roles to facilitate the formation of macrocycles, providing not only the kinetic control due to the formation of the cyclization-promoting cis C = O/tert-butyl conformation, but also possibly the thermodynamic stabilization of macrocycles with weak association interactions. The bulky N-tert-butyl can be readily removed by acid to eliminate the dynamicity of HUB and stabilize the macrocycle structures.

Design and Analysis of a High Pitch to Chord Ratio Cascade Representative of Ducted Propfans

1991 ◽  
Author(s):  
A. Weber ◽  
W. Steinert ◽  
H. Starken
Keyword(s):  
Boundary Layer ◽  
Mach Number ◽  
High Efficiency ◽  
Pressure Ratio ◽  
Flow Analysis ◽  
High Pitch ◽  
Integral Boundary ◽  
Pressure Loss Coefficient ◽  
Distribution Boundary ◽  
Very High

Efforts to reduce the specific fuel consumption of a modern aero engine focus in particular on increasing the by-pass ratio beyond the current level of around 5. One concept is the counterrotating shrouded propfan operating at low overall pressure ratio and having only very few fan blades of extremely high pitch/chord ratios. The relative inlet Mach numbers cover a range from 0.7 at the hub to 1.1 at the tip section of the first rotor. A propfan cascade was designed by taking into account two characteristic features of a propfan blade-blade section: • a very high pitch/chord ratio of s/c = 2.25 • an inlet Mach number of M1 = 0.90 which leads to transonic flow conditions inside the blade passage In the design process a profile generator and a quasi-3D Euler solver were used iteratively to optimize the profile Mach number distribution. Boundary layer behavior was checked with an integral boundary layer code. The cascade design was verified experimentally in the transonic cascade wind tunnel of DLR at Cologne. The extensive experimental results confirm the design goal of roughly 5 degree flow turning. A total pressure loss coefficient of less than 1.5% was measured at design conditions. This validates the very high efficiency level the propfan concept is calling for. A 2D Navier-Stokes flow analysis code yields good results in comparison to the experimental ones.

High Efficiency Combined Aggregate – Submerged Combustion Melter–Electric Furnace for Vitrification of High-Level Radioactive Wastes

2004 ◽  
Author(s):  
L. S. Pioro ◽  
I. L. Pioro
Keyword(s):  
Electric Furnace ◽  
High Efficiency ◽  
High Capacity ◽  
Main Idea ◽  
Melting Process ◽  
Radioactive Wastes ◽  
Single Stage ◽  
Interface Surface ◽  
High Level ◽  
Submerged Combustion

It is well known that high-level radioactive wastes (HLRAW) are usually vitrified inside electric furnaces. Disadvantages of electric furnaces are their low melting capacity and restrictions on charge preparation. Therefore, a new concept for a high efficiency combined aggregate – submerged combustion melter (SCM)–electric furnace was developed for vitrification of HLRAW. The main idea of this concept is to use the SCM as the primary high-capacity melting unit with direct melt drainage into an electric furnace. The SCM employs a single-stage method for vitrification of HLRAW. The method includes concentration (evaporation), calcination, and vitrification of HLRAW in a single-stage process inside a melting chamber of the SCM. Specific to the melting process is the use of a gas-air or gas-oxygen-air mixture with direct combustion inside a melt. Located inside the melt are high-temperature zones with increased reactivity of the gas phase, the existence of a developed interface surface, and intensive mixing, leading to intensification of the charge melting and vitrification process. The electric furnace clarifies molten glass, thus preparing the high-quality melt for subsequent melt pouring into containers for final storage.

scholarly journals Instantaneous Electromagnetic Torque Components in Synchronous Motors Fed by Load-Commutated Inverters

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3223
Author(s):  
Gabriel Ekemb ◽  
Fouad Slaoui-Hasnaoui ◽  
Joseph Song-Manguelle ◽  
P. M. Lingom ◽  
Issouf Fofana
Keyword(s):  
High Efficiency ◽  
Air Gap ◽  
International Standards ◽  
Synchronous Motors ◽  
Gas Compression ◽  
Variable Frequency Drives ◽  
Torsional Analysis ◽  
Analytical Expressions ◽  
Very High ◽  
Excitation Circuit

This paper proposes time-domain analytical expressions of the instantaneous pulsating torque components in a synchronous machine air gap when supplied by a load-commutated-inverter (LCI) system. The LCI technology is one of the most used variable frequency drives when very high power and low speed are required in applications such as pipeline recompression and decompression, as well as liquefied natural gas compression. In such applications, synchronous motors are used because of their high efficiency resulting from a separated supply of the current to their rotor through the excitation circuit. These applications usually have long and flexible shafts, which are very sensitive to torsional vibration excitation when their natural frequencies interact with any external torque applied to the shaft. A torsional analysis is required by international standards to assess the survivability of the shaft through the overall speed range of the motor. Therefore, the magnitude and frequencies of the motor air-gap torque are needed for such evaluation. The proposed developments are supported by numerical simulations of LCI systems in a large range of operation range. From the simulation results, torque harmonic families are derived and expressed in a parametric form, which confirm the accuracy of the proposed relationships.

scholarly journals Achieving Atomic Dispersion of Highly Loaded Transition Metals in Small‐Pore Zeolite SSZ‐13: High‐Capacity and High‐Efficiency Low‐Temperature CO and Passive NO x Adsorbers

2018 ◽  
Vol 57 (51) ◽  
pp. 16672-16677 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Nicholas R. Jaegers ◽  
Libor Kovarik ◽  
Jonathan C. Hanson ◽  
Franklin (Feng) Tao ◽  
...  
Keyword(s):  
Low Temperature ◽  
Transition Metals ◽  
High Efficiency ◽  
High Capacity ◽  
Small Pore ◽  
Highly Loaded
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