Jet fuel range hydrocarbons production by co-pyrolysis of low density polyethylene and wheat straw over activated carbon catalyst

Author(s):  
Erguang Huo ◽  
Chao Liu ◽  
Liyong Xin ◽  
Yayun Zhang ◽  
Yunfeng Zhao ◽  
...  

High-efficiency and low-cost catalyst matters a great deal to convert solid wastes into high valued chemicals and biofuels. In this study, catalytic co-pyrolysis of wheat straw and low density polyethylene...

2020 ◽  
Vol 4 (7) ◽  
pp. 3687-3700
Author(s):  
Dengle Duan ◽  
Yayun Zhang ◽  
Hanwu Lei ◽  
Moriko Qian ◽  
Elmar Villota ◽  
...  

The catalytic co-pyrolysis of Douglas fir and low-density polyethylene with commercial activated carbon catalysts was investigated for the first time.


Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2436
Author(s):  
Abubakar Sadiq Mohammed ◽  
Martina Meincken

Low-cost wood–plastic composites (WPCs) were developed from invasive trees and recycled low-density polyethylene. The aim was to produce affordable building materials for low-cost social housing in South Africa. Both raw materials are regarded as waste materials, and the subsequent product development adds value to the resources, while simultaneously reducing the waste stream. The production costs were minimised by utilising the entire biomass of Acacia saligna salvaged from clearing operations without any prior processing, and low-grade recycled low-density polyethylene to make WPCs without any additives. Different biomass/plastic ratios, particle sizes, and press settings were evaluated to determine the optimum processing parameters to obtain WPCs with adequate properties. The water absorption, dimensional stability, modulus of rupture, modulus of elasticity, tensile strength, and tensile moduli were improved at longer press times and higher temperatures for all blending ratios. This has been attributed to the crystallisation of the lignocellulose and thermally induced cross-linking in the polyethylene. An increased biomass ratio and particle size were positively correlated with water absorption and thickness swelling and inversely related with MOR, tensile strength, and density due to an incomplete encapsulation of the biomass by the plastic matrix. This study demonstrates the feasibility of utilising low-grade recycled polyethylene and the whole-tree biomass of A. saligna, without the need for pre-processing and the addition of expensive modifiers, to produce WPCs with properties that satisfy the minimum requirements for interior cladding or ceiling material.


2017 ◽  
Author(s):  
Darunee Aussawasathien ◽  
Kotchaporn Jariyakun ◽  
Thongchai Pomrawan ◽  
Kittipong Hrimchum ◽  
Rungsima Yeetsorn ◽  
...  

2015 ◽  
Vol 768 ◽  
pp. 392-401
Author(s):  
Guo Qiang Zhou ◽  
Wei Kun Yao ◽  
Yu Jue Wang ◽  
Yu Feng ◽  
Yan Qing Yu ◽  
...  

This study investigated catalytic fast pyrolysis (CFP) of beech wood, low-density polyethylene (LDPE), and their mixture (mass ratio of 1) with a conventional microporous ZSM-5 and mesoporous bifunctional Zn/ZSM-5meso zeolite prepared by desilication of the conventional ZSM-5 with NaOH solution and then impregnation with Zn.The generation of mesopores by desilication improved the diffusion property of the zeolite, which decreased the formation of undesired polyaromatic hydrocarbons from secondary polymerization reactions of monoaromatics in CFP. In addition, the impregnation of Zn increased the dehydrogenation activity of the zeolites, and thus enhanced the conversion of low-value alkanes to valuable olefins. As a result, Zn/ZSM-5meso produced higher yields (56.0 C%) of valuable petrochemicals (monoaromatic hydrocarbons and olefins) and lower yields of undesired polyaromatics (1.70 C%) and alkanes (10.2 C%) in co-feed CFP of the beech wood and LDPE mixture than ZSM-5 (48.2 C%, 4.18 C%, and 18.7 C% for petrochemicals, polyaromatics, and alkanes, respectively).ZSM-5 desilication and impregnation with Zn thus have a beneficial effect on improve the product distribution in CFP of biomass and plastic mixtures. In addition, the results suggest that CFP may provide a promising technology for producing renewable petrochemicals from municipal and agricultural solid wastes, which usually contain high contents of biomass and waste plastics.


Catalysts ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 66 ◽  
Author(s):  
Jeerati Ob-eye ◽  
Piyasan Praserthdam ◽  
Bunjerd Jongsomjit

Recently, the interest in ethanol production from renewable natural sources in Thailand has been receiving much attention as an alternative form of energy. The low-cost accessibility of ethanol has been seen as an interesting topic, leading to the extensive study of the formation of distinct chemicals, such as ethylene, diethyl ether, acetaldehyde, and ethyl acetate, starting from ethanol as a raw material. In this paper, ethanol dehydrogenation to acetaldehyde in a one-step reaction was investigated by using commercial activated carbon with four different metal-doped catalysts. The reaction was conducted in a packed-bed micro-tubular reactor under a temperature range of 250–400 °C. The best results were found by using the copper doped on an activated carbon catalyst. Under this specified condition, ethanol conversion of 65.3% with acetaldehyde selectivity of 96.3% at 350 °C was achieved. This was probably due to the optimal acidity of copper doped on the activated carbon catalyst, as proven by the temperature-programmed desorption of ammonia (NH3-TPD). In addition, the other three catalyst samples (activated carbon, ceria, and cobalt doped on activated carbon) also favored high selectivity to acetaldehyde (>90%). In contrast, the nickel-doped catalyst was found to be suitable for ethylene production at an operating temperature of 350 °C.


2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Xiaotao Zhang ◽  
Yinan Hao ◽  
Ximing Wang ◽  
Zhangjing Chen ◽  
Chun Li

This paper presents low-cost and recyclable activated carbon (XLAC) derived from Xanthoceras sorbifolia Bunge hull for high-efficiency adsorption of Cd(II) and Hg(II) ions in industrial wastewater. XLAC was prepared through H3PO4 activation and was characterized using N2 adsorption-desorption, scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDX), and Fourier transform infrared (FTIR) spectroscopy. In single-metal-system adsorption experiments, the maximum adsorption capacities for Cd(II) and Hg(II) obtained under different experimental conditions were 388.7 and 235.6 mg·g−1, respectively. All adsorption equilibrium data fit perfectly with the Langmuir isotherm model. In a binary metal system, competitive studies demonstrated that the presence of Cd(II) significantly decreased the adsorption of Hg(II), but the adsorption of Cd(II) showed a little change in the presence of Hg(II). In addition, XLAC can be regenerated with a 0.01 mol·L−1 HNO3 solution and reused at least four times. The FTIR spectra revealed that a chemical interaction occurs between functional groups containing lone electron pairs in XLAC and metal ions. Overall, these results suggest that XLAC may be suitable as an adsorbent for heavy metal removal from wastewater streams.


2019 ◽  
Vol 35 (1) ◽  
pp. 200-206
Author(s):  
Mashael Alshabanat

This work aims to develop green linear low-density polyethylene (LLDPE) composites that are commercially viable due to the low cost of the date palm leaflet filler, which is a local renewable resource. The filler was naturally treated with gum arabic solution. FT-IR, XRD, and SEM techniques were used to characterize the samples. The thermal and mechanical properties were measured by TGA, DSC, and tensile testing. The results showed noticeable changes in the properties of the composites compared to those of the original LLDPE sample. TGA revealed that the composite started thermally. The composites started thermally degrading before the original polymer, owing to the degradation of the natural components in the filler. The findings from DSC suggested that the crystallinity was affected. The tensile testing results indicated that the composites were appropriate for applications requiring low tensile strength at break and high Young’s modulus. A comparison of these results with earlier ones exhibited that the basic additives in the polymer may have an effect on the filler performance.


2019 ◽  
Vol 88 ◽  
pp. 1-9 ◽  
Author(s):  
Dengle Duan ◽  
Yayun Zhang ◽  
Hanwu Lei ◽  
Elmar Villota ◽  
Roger Ruan

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