scholarly journals Sythesis of bioavture through hydrodeoxygenation and catalytic cracking from oleic acid using NiMo/Zeolit catalyst

2018 ◽  
Vol 67 ◽  
pp. 02023
Author(s):  
Michelle Flavin Carli ◽  
Bambang Heru Susanto ◽  
Thareq Kemal Habibie
Keyword(s):  
Oleic Acid ◽  
Catalytic Cracking ◽  
Fossil Fuels ◽  
Liquid Product ◽  
Primary Source ◽  
Chemical Characteristic ◽  
Acid Number ◽  
Operating Conditions ◽  
Aviation Fuel ◽  
Catalytic Cracking Reaction

Currently, fossil fuels are still the primary source of fuel. As has been known, fossil fuel especially aviation fuel is limited resources and can increase greenhouse gas emissions. This condition encourages replacement efforts of avture into bioavture fuel. In this research, bioavture is synthesized through hydrodeoxygenation and catalytic cracking from oleic acid as a model compound using NiMo/Zeolite catalyst. Hydrodeoxygenation carried out under operating conditions: at temperature of 375°C, under 15 bar pressure and for 2.5 hours. The chain of hydrocarbons from the result of hydrodeoxygenation has been cracked by catalytic cracking reaction for 1.5 hours. Variation operating condition used are 360, 375, and 390°C. The liquid product is tested its chemical characteristic, ie acid number, FTIR and GC-MS and its physical characteristics, ie density test and viscosity. Bioavtur that synthesized by catalytic cracking have met the specifications of bioavtur, except the acid number with optimum temperature at 375oC. These conditions with NiMo/Zeolite activated led to dominant yield of 36.32%, selectivity of 38.05%, and conversion of 84.30%. Percentage of yield and selectivity of bioavtur are still low caused by performance of catalyst that is still can not optimum. While, high percentage of conversion caused by high temperature used for catalytic cracking.

scholarly journals BIOFUEL PRODUCTION FROM PALM OLEIN BY CATALYTIC CRACKING PROCESS USING ZSM-5 CATALYST

2017 ◽  
Vol 6 (1) ◽  
pp. 50-55 ◽  
Author(s):  
Rondang Tambun ◽  
Oktris Novali Gusti ◽  
Muhammad Anshori Nasution ◽  
Rangga Pramana Saptawaldi
Keyword(s):  
Reaction Time ◽  
Palm Oil ◽  
Catalytic Cracking ◽  
Palm Olein ◽  
Liquid Product ◽  
Operating Conditions ◽  
Biofuel Production ◽  
Energy Reserves ◽  
Fossil Energy ◽  
Cracking Process

The depletion of fossil energy reserves raises the potential in the development of renewable fuels from vegetable oils. Indonesia is the largest palm oil producer in the world, where palm oil can be converted into biofuels such as biogasoline, kerosene and biodiesel. These biofuels are environmentally friendly and free of the content of nitrogen and sulfur through catalytic cracking process. In this research, palm olein is used as feedstock using catalytic cracking process. ZSM-5 is used as a catalyst, which has a surface area of 425 m2/g and Si/Al ratio of 50. Variables varied are the operating temperature of 375 oC - 450 C and reaction time of 60 minutes - 150 minutes. The result shows that the highest yield of liquid product is 84.82%. This yield is obtained at a temperature of 400 C and reaction time of 120 minutes. The yield of the liquid product in the operating conditions consisting of C6-C12 amounted to 19.47 %, C14-C16 amounted to 16.56 % and the C18-C28 amounted to 48.80 %.

scholarly journals SINTESIS METIL ESTER DARI LIMBAH KELAPA SAWIT DENGAN SONOCHEMISTRY DAN CRACKING MENJADI BIOFUEL DENGAN KATALIS CrMo/HZ

Alotrop ◽  
2019 ◽  
Vol 3 (2) ◽  
Author(s):  
Jertadi Putri Dhani ◽  
Agus Sundaryono ◽  
Dewi Handayani
Keyword(s):  
Methyl Ester ◽  
Catalytic Cracking ◽  
Pour Point ◽  
Liquid Waste ◽  
Acid Number ◽  
Ultrasonic Waves ◽  
Gas Oil ◽  
Cracking Reaction ◽  
Heating Oil ◽  
Catalytic Cracking Reaction

This study aims to calculate the percentage methyl ester converted to biofuel through catalytic cracking reaction,analyzes component and determine characteristics using catalyst CrMo/HZ. This research begins with impregnation sample preparation which includes heating oil,degumming,bleaching and determination free fatty acid (FFA). Methyl ester obtained from liquid waste conversion crude palm oil through an esterification and transesterification reaction with H2SO4 and NaOH catalyst with sonochemistry methode is a method that utilizes ultrasonic waves origanating from a device is ultrasonic cleaner for one hour at temperature 60oC. The methyl ester obtained was cracked with a CrMo/HZ catalyst which was carried out for 2 hours at temperatur 380oC. To find out the components of compounds formed in methyl ester, an analysis was performed using GCMS then characteristics of biofuel are determined from the result of catalytic cracking obtained through acid number testing,density,viscosity,pour point and fog point. The result obtained from the conversion of methyl ester to biofuel with Crmo/HZ Catalyst Is 60,17% And For Testing The Physical Characteristics Of Biofuel Namely The Acid Number 1,87 Mg KOH/G, density 0,804 g/cm3, viscosity 1,162 Cst, pour point 0oC and fog point 1,4oC. The result of cracking produce a consituent component of biofuel namely gasoline 33,67%, kerosene 16,26%, gas oil 10,24% beside that, there are still methyl ester as much as21,89%.

PEMBUATAN SURFAKTAN DARI ASAM OLEAT

2019 ◽  
Vol 1 (3) ◽  
pp. 68
Author(s):  
Puguh Setyopratomo ◽  
Edy Purwanto ◽  
H. Yefrico ◽  
H. Yefrico
Keyword(s):  
Oleic Acid ◽  
Optimum Condition ◽  
Reaction Temperature ◽  
Catalyst Concentration ◽  
Acid Number ◽  
Esterification Reaction ◽  
Number Density ◽  
Sample Analysis ◽  
Reaction Conversion ◽  
Glycerol Mono

The synthesis of glycerol mono oleic from oleic acid and glycerol is classified as an esterification reaction. This research is aimed to study the influent of reaction temperature and catalyst concentration on reaction conversion. During the experiment the temperature of reaction mixture was varied as 110 oC, 130 oC, and 150 oC, while the catalyst concentration of 1%, 3 %, and 5% was used. The batch experiment was conducted in a glass reactor equipped with termometer, agitator, and reflux condensor. The oleic acid – glycerol mol ratio of 1 : 2 was used as a mixture feed. To maintain the reaction temperature at certain level, the oil bath was used. After the temperature of reaction mixture was reached the expected value, then H2SO4 catalyst was added to the reactor.  To measure the extent of the reaction, every 30 minutes the sample was drawn out from the reactor vessel. The sample analysis include acid number, density, and viscosity measurement. From this research the optimum condition which is the temperature of reaction of 150 oC and 1% catalyst concentration was obtained. At this optimum condition the convertion reach 86% and the analysis of other physical properties of the product show the acid number of 24.12, the density of 0.922 g/cc, and the viscosity of 118.4 cp.

scholarly journals AN UNSATURATED FATTY ACID FRACTION OF PIG PANCREAS WHICH INHIBITS THE GROWTH OF CHICKEN SARCOMA

1936 ◽  
Vol 64 (3) ◽  
pp. 333-338 ◽  
Author(s):  
O. M. Helmer
Keyword(s):  
Oleic Acid ◽  
Fatty Acid ◽  
Iodine Number ◽  
Aqueous Extract ◽  
Unsaturated Fatty Acid ◽  
Fatty Acid Fraction ◽  
Pancreatic Tissue ◽  
Acid Number ◽  
Acid Fraction ◽  
Commercial Oleic Acid

The inhibiting action of pancreatic tissue was found to be associated with the unsaturated fatty acid fraction. As small an amount of fatty acid as 0.1 mg. inhibited the chicken sarcoma agent contained in 0.2 cc. of a 1:60 aqueous extract of Chicken Tumor I. The unsaturated fatty acid had an acid number and an iodine number similar to those for oleic acid. Commercial oleic acid also was found to inhibit the growth of the chicken sarcoma in comparable quantities.

Effect of Film Cooling on Low Temperature Hot Corrosion in a Coal Fired Gas Turbine

2003 ◽  
Author(s):  
Vaidyanathan Krishnan ◽  
J. S. Kapat ◽  
Y. H. Sohn ◽  
V. H. Desai
Keyword(s):  
Low Temperature ◽  
Corrosion Rate ◽  
Hot Corrosion ◽  
Film Cooling ◽  
Gas Turbines ◽  
Primary Source ◽  
Operating Conditions ◽  
Coal Gas ◽  
A Chain ◽  
Lower Corrosion Rate

In recent times, the use of coal gas in gas turbines has gained a lot of interest, as coal is quite abundant as a primary source of energy. However, use of coal gas produces a few detrimental effects that need closer attention. This paper concentrates on one such effect, namely hot corrosion, where trace amounts of sulfur can cause corrosion (or sulfidation) of hot and exposed surfaces, thereby reducing the life of the material. In low temperature hot corrosion, which is the focus of this paper, transport of SO2 from the hot gas stream is the primary process that leads to a chain of events, ultimately causing hot corrosion. The corrosion rate depends on SO2 mass flux to the wall as well as wall surface temperature, both of which are affected in the presence of any film cooling. An analytical model is developed to describe the associated transport phenomena of both heat and mass in the presence of film cooling The model predicts how corrosion rates may be affected under operating conditions. It is found that although use of film cooling typically leads to lower corrosion rate, there are combinations of operating parameters under which corrosion rate can actually increase in the presence of film cooling.

scholarly journals Formation of Surface Deposits on Steel and Titanium Aviation Fuel Tubes under Real Operating Conditions

ACS Omega ◽  
2019 ◽  
Vol 4 (5) ◽  
pp. 8255-8273 ◽  
Author(s):  
Igor Velkavrh ◽  
Ion Palamarciuc ◽  
Dan Gelu Galuşcă ◽  
Alexander Diem ◽  
Josef Brenner ◽  
...  
Keyword(s):  
Operating Conditions ◽  
Aviation Fuel

Experimental and Analytical Characterization of Alternative Aviation Fuel Sprays Under Realistic Operating Conditions

2018 ◽  
Author(s):  
Andrew Corber ◽  
Nader Rizk ◽  
Wajid Ali Chishty
Keyword(s):  
Experimental Data ◽  
Alternative Fuels ◽  
Laser Sheet ◽  
National Research Council ◽  
Diagnostic System ◽  
Operating Conditions ◽  
Aviation Fuel ◽  
Injection System ◽  
Test Time

The National Jet Fuel Combustion Program (NJFCP) is an initiative, currently being led by the Office of Environment & Energy at the FAA, to streamline the ASTM jet fuels certification process for alternative aviation fuels. In order to accomplish this objective, the program has identified specific applied research tasks in several areas. The National Research Council of Canada (NRC) is contributing to the NJFCP in the areas of sprays and atomization and high altitude engine performance. This paper describes work pertaining to atomization tests using a reference injection system. The work involves characterization of the injection nozzle, comparison of sprays and atomization quality of various conventional and alternative fuels, as well as use of the experimental data to validate spray correlations. The paper also briefly explores the application viability of a new spray diagnostic system that has potential to reduce test time in characterizing sprays. Measurements were made from ambient up to 10 bar pressures in NRC’s High Pressure Spray Facility using optical diagnostics including laser diffraction, phase Doppler anemometry (PDA), LIF/Mie Imaging and laser sheet imaging to assess differences in the atomization characteristics of the test fuels. A total of nine test fluids including six NJFCP fuels and three calibration fluids were used. The experimental data was then used to validate semi-empirical models, developed through years of experience by engine OEMs and modified under NJFCP, for predicting droplet size and distribution. The work offers effective tools for developing advanced fuel injectors, and generating data that can be used to significantly enhance multi-dimensional combustor simulation capabilities.

scholarly journals The Application of Catalytic Processes on the Production of Algae-based Biofuels: A Review

2020 ◽  
Author(s):  
Antonio Zuorro ◽  
Janet B. García-Martínez ◽  
Andrés F. Barajas-Solano
Keyword(s):  
Fossil Fuels ◽  
Operating Conditions ◽  
Thermochemical Conversion ◽  
Chemical Components ◽  
High Carbon ◽  
Microalgal Biomass ◽  
Microalgae Biomass ◽  
End Products ◽  
Recent Developments ◽  
Thermochemical Processes

Over the last decades, microalgal biomass has gained a significant role in the development of different high-end (nutraceuticals, colorants, food supplements, and pharmaceuticals) and low-end products (biodiesel, bioethanol, and biogas) due to rapid growth and high carbon fixing efficiency. Therefore, microalgae are considered a useful and sustainable resource to attain energy security while reducing our current reliance on fossil fuels. From the technologies available for obtaining biofuels using microalgae biomass, thermochemical processes (pyrolysis, HTL, gasification) have proven to be processed with higher viability, because they use all biomass. However, the biocrudes obtained from direct thermochemical conversion have substantial quantities of heteroatoms (oxygen, nitrogen, and sulfur) due to the complexity of the biomass's content of chemical components (lipids, carbohydrates, and proteins). As a solution, catalyst-based processes have emerged as a sustainable solution for the increase in biocrude production. This paper's objective is to present a comprehensive review of recent developments on catalyst mediated conversion of algal biomass. Special attention will be given to operating conditions, strains evaluated, and challenges for the optimal yield of algal-based biofuels through pyrolysis and HTL.

scholarly journals FATTY ACID ESTERIFICATION: EFFECTS OF UNSATURATION AND SYNTHESIS WITH THERMAL HEATING VIA ULTRASON AND MICROWAVES

2018 ◽  
Vol 15 (30) ◽  
pp. 447-462
Author(s):  
M. C. de M. SOUZA ◽  
L. DI SOUZA ◽  
V. P. da S. Caldeira ◽  
A. G. D. SANTOS ◽  
B. ADILSON
Keyword(s):  
Fatty Acids ◽  
Oleic Acid ◽  
Fatty Acid ◽  
Energy Demand ◽  
Fossil Fuels ◽  
Acid Catalysis ◽  
Thermal Heating ◽  
Ultrasonic Methods ◽  
Homogeneous Acid ◽  
Acid Esterification

With the increasing selective energy demand, fossil fuels are becoming scarce and environmentally incorrect, a viable alternative to this problem being the production of biodiesel. However, the esterification and transesterification reactions used are slow, expensive and ecologically incorrect because they produce polluting waste. Thus, it is necessary to develop techniques, reagents and equipment that make them fast, cheap and environmentally friendly. This work evaluated the performance of the thermal heating, microwave and ultrasonic methods in the esterification efficiency of oleic and stearic fatty acids via homogeneous acid catalysis. The efficiency of the reaction was certificated with the variables: time, yield and conversion and the biodiesel characterization were done with TG / DTG, FTIR and NMR. Conversions were determined by TG and 1H NMR and the yield by gravimetry. The results showed conversion with all methods with differences in the analyzed variables. The yields decrease in the microwave order (52%) conduction (33%) ultrasound (30%) for reactions with oleic acid and are practically the same (22, 22 and 20), independently of the stearic acid. Among the methods used, the most efficient is the microwave, because it has a higher yield in the case of oleic acid and reducing the reaction time.

scholarly journals Synthesis of 1,4-Dioxaspiro[4.4] and 1,4-Dioxaspiro[4.5] Novel Compounds from Oleic Acid as Potential Biolubricant

2017 ◽  
Vol 17 (2) ◽  
pp. 301
Author(s):  
Yehezkiel Steven Kurniawan ◽  
Yudha Ramanda ◽  
Kevin Thomas ◽  
Hendra Hendra ◽  
Tutik Dwi Wahyuningsih
Keyword(s):  
Oleic Acid ◽  
Viscous Liquid ◽  
Acid Number ◽  
The Other ◽  
Esterification Reaction ◽  
Base Number ◽  
Sonochemical Method ◽  
Total Acid ◽  
Hydroxylation Reaction ◽  
Total Base

Two 1,4-dioxaspiro novel compounds which derivated from methyl 9,10-dihydroxyoctadecanoate (MDHO) with cyclopentanone and cyclohexanone had been synthesized by a sonochemical method in the presence of montmorillonite KSF catalyst. The MDHO compound had been prepared from 9,10-dihydroxyoctadecanoic acid (DHOA) and methanol. Meanwhile, DHOA was synthesized by hydroxylation of oleic acid with the solution of 1% KMnO4 under basic condition. The structures of the products were confirmed by FTIR, GC-MS, 1H-NMR, and 13C-NMR spectrometers. Hydroxylation reaction of oleic acid gave DHOA as a white solid powder in 46.52% yield (m.p. 131-132 °C). On the other side, esterification reaction via sonochemical method between DHOA and methanol gave MDHO as a white powder in 93.80% yield (m.p. 80-81 °C). The use of cyclopentanone in 45 min sonochemical method gave methyl 8-(3-octyl-1,4-dioxaspiro[4.4]nonan-2-yl)octanoate as a yellow viscous liquid in 50.51% yield. The other compound, methyl 8-(3-octyl-1,4-dioxaspiro[4.5]decan-2-yl)octanoate as yellow viscous liquid had been synthesized by similar method with cyclohexanone via the sonochemical method in 45.12% yield. From physicochemical properties, i.e. density, total acid number, total base number, and iodine value, gave the conclusion that these novel compounds are potential biolubricant candidates to be developed.

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