scholarly journals Effectiveness of demulsifiers for the destruction of highly mineralized water-oil emulsions of the Srednebotuobinsky oil and gas condensate field

2020 ◽  
Vol 217 ◽  
pp. 04001
Author(s):  
Maria Ivanova ◽  
Kirill Tomskii

One of the most serious problems of field oil treatment at the Srednebotuobinsky oil and gas condensate field is an abnormally high content of chloride salts, reaching 350 thousand mg / dm3. The high content of chloride salts significantly complicates the preparation of oil and requires other approaches both in production and in the preparation of extracted raw materials. In this paper, the influence of the drilling fluid used in the Srednebotuobinsky oil and gas condensate field together with the most popular demulsifiers and the effect of acidity on the oil dehydration process are considered. To determine the compatibility of the drilling fluid with the formation water of the field, tests were conducted at various concentrations of the drilling fluid at temperatures. Based on the results of the data obtained, the optimal concentration of Flo-Pro NT drilling fluid from M-I Drilling Fluids Co and ANCO-2000 from ANCOR Drilling Fluids was determined at reservoir temperatures and oil treatment temperatures. Under the conditions selected above, the dynamics of desalination and dehydration of oil from the Srednebotuobinsky field were determined at various dosages of demulsifiers DMO 25126 and Dissolvan 13853 and at various acidities of the medium.

2015 ◽  
pp. 103-108
Author(s):  
R. E. Shesterikova ◽  
E. A. Shesterikova ◽  
M. V. Popov

It is known that development of gas, gas-condensate and oil deposits is related with production of associated mineralized water. For creation of highly profitable processes of production and processing of hydrocarbons the methods of utilization of secondary sources of raw materials and energy become very important. The volumes of produced associated water at the petroleum complex facilities are so great, that it permits to consider them as a source of raw materials for processing with further receiving various commodity products, for example, process liquids, drilling fluids, iodine, bromine and their compounds.


2014 ◽  
Vol 625 ◽  
pp. 526-529 ◽  
Author(s):  
Lim Symm Nee ◽  
Badrul Mohamed Jan ◽  
Brahim Si Ali ◽  
Ishenny Mohd Noor

It is an open secret that currently oil and gas industry is focusing on increasing hydrocarbon production through underbalanced drilling (UBD) and finding ways to ensure the drilling process is less harmful to the environment. Water-based biopolymer drilling fluids are preferred compared to oil based drilling fluids owing to the fact that it causes less pollution to the environment. This paper investigates the effects of varying concentrations of environmentally safe raw materials, namely glass bubbles, clay, xanthan gum and starch concentrations on the density of the formulated biopolymer drilling fluid to ensure that it is suitable for UBD. As material concentrations were varied, the density for each sample was measured at ambient temperature and pressure. Results showed that the final fluid densities are within acceptable values for UBD (6.78 to 6.86 lb/gal). It is concluded that the formulated water-based biopolymer drilling fluid is suitable to be used in UBD operation.


2019 ◽  
Vol 17 (1) ◽  
pp. 1435-1441
Author(s):  
Yonggui Liu ◽  
Yang Zhang ◽  
Jing Yan ◽  
Tao Song ◽  
Yongjun Xu

AbstractTraditional water-in-oil drilling fluids are limited by their shear thinning behavior. In this article, we propose the synthesis of a thermal resistant quaternary ammonium salt gemini surfactant DQGE-I. This surfactant was synthesized using monomers such as N,N-dimethyl-1,3-propanediamine, organic acids and epichlorohydrin, as well as blocking groups such as N-vinylpyrrolidone (NVP). The prepared surfactant exhibited various advantages over traditional surfactants, including excellent thermal stability, good emulsifying and wetting capability. The use of these surfactants was shown to improve the compactness of emulsifier molecules at the oil/water interface, as well as the overall emulsificaiton effect. Laboratory studies revealed that water-in-oil emulsions prepared using DQGE-I showed high emulsion breaking voltage, low liquid precipitation and small and uniformly distributed emulsion drops. Highly thixotropic water-in-oil drilling fluids based on DQGE-I showed low viscosity, high shear rate and thermal tolerance up to 260oC. Additionally, the proposed fluid was applied in 16 wells (including WS1-H2, GS3 and XS1-H8) in the Daqing Oilfield. Testing showed that DQGE-1 exhibited excellent rheological behavior and wall-building capability. The emulsion breaking voltage exceeded 1500 V, and the yield point/ plastic viscosity ratio exceeded 0.4. The use of this surfactant can help to solve problems such as high formation temperature and poor well wall stability.


Author(s):  
E.A. Flik ◽  
◽  
Y.E. Kolodyazhnaya

The article assesses the environmental safety of drilling fluids that are currently widely used in the oil and gas industry. It shows active development of water-based drilling fluid systems using xanthan biopolymer.


Author(s):  
Bunyami Shafie ◽  
Lee Huei Hong ◽  
Phene Neoh Pei Nee ◽  
Fatin Hana Naning ◽  
Tze Jin Wong ◽  
...  

Drilling mud is a dense, viscous fluid mixture used in oil and gas drilling operations to bring rock cuttings to the earth's surface from the boreholes as well as to lubricate and cool the drill bit. Water-based mud is commonly used due to its relatively inexpensive and easy to dispose of. However, several components and additives in the muds become increasingly cautious and restricted. Starch was introduced as a safe and biodegradable additive into the water-based drilling fluid, in line with an environmental health concern. In this study, the suitability of four local rice flours and their heat moistures derivatives to be incorporated in the formulation of water-based drilling fluid was investigated. They were selected due to their natural amylose contents (waxy, low, intermediate, and high). They were also heat moisture treated to increase their amylose contents. Results showed that the addition of the rice flours into water-based mud significantly reduced the density, viscosity, and filtrate volume. However, the gel strength of the mud was increased. The rice flours, either native or heat moisture treated, could serve as additives to provide a variety of low cost and environmentally friendly drilling fluids to be incorporated and fitted into different drilling activity.


2019 ◽  
Vol 141 (10) ◽  
Author(s):  
Mohamed Mahmoud

The well clean-up process involves the removal of impermeable filter cake from the formation face. This process is essential to allow the formation fluids to flow from the reservoir to the wellbore. Different types of drilling fluids such as oil- and water-based drilling fluids are used to drill oil and gas wells. These drilling fluids are weighted with different weighting materials such as bentonite, calcium carbonate, and barite. The filter cake that forms on the formation face consists mainly of the drilling fluid weighting materials (around 90%), and the rest is other additives such as polymers or oil in the case of oil-base drilling fluids. The process of filter cake removal is very complicated because it involves more than one stage due to the compatibility issues of the fluids used to remove the filter cake. Different formulations were used to remove different types of filter cake, but the problem with these methods is the removal efficiency or the compatibility. In this paper, a new method was developed to remove different types of filter cakes and to clean-up oil and gas wells after drilling operations. Thermochemical fluids that consist of two inert salts when mixed together will generate very high pressure and high temperature in addition to hot water and hot nitrogen. These fluids are sodium nitrate and ammonium chloride. The filter cake was formed using barite and calcite water- and oil-based drilling fluids at high pressure and high temperature. The removal process started by injecting 500 ml of the two salts and left for different time periods from 6 to 24 h. The results of this study showed that the newly developed method of thermochemical removed the filter cake after 6 h with a removal efficiency of 89 wt% for the barite filter cake in the water-based drilling fluid. The mechanisms of removal using the combined solution of thermochemical fluid and ethylenediamine tetra-acetic acid (EDTA) chelating agent were explained by the generation of a strong pressure pulse that disturbed the filter cake and the generation of the high temperature that enhanced the barite dissolution and polymer degradation. This solution for filter cake removal works for reservoir temperatures greater than 100 °C.


2020 ◽  
Vol 7 (2) ◽  
pp. 191230
Author(s):  
Yuhuan Bu ◽  
Rui Ma ◽  
Jiapei Du ◽  
Shenglai Guo ◽  
Huajie Liu ◽  
...  

This research work designed a novel mud-cake solidification method to improve the zonal isolation of oil and gas wells. The calculation methodology of mud-cake compressive strength was proposed. The optimal formula of activator and solid precursors, the proper activating time and the best activator concentration were determined by the compressive strength test. The effects of solid precursors on the properties of drilling fluid were evaluated. Test results show that the respective percentage of bentonite, metakaolin, slag and activator is 1 : 1 : 0.3 : 0.8, as well as the optimum ratio of Na 2 SiO 3 /NaOH is 40 : 1. The optimum concentration of activator is 0.21 and the activating time should be more than 10 min. The solid precursors did not show any bad influence on the rheological property of drilling fluids. Even though the compressive strength decreased when the solid precursors blended with barite, the strength values can still achieve 8 MPa. The reaction of metakaolin and activator formed cross-link structure in the mud-cake matrix, which enhanced the connection of the loose bentonite particles, lead to the significant enhancement of shear bonding strength and hydraulic bonding strength. This mud-cake solidification method provides a new approach to improve the quality of zonal isolation.


2011 ◽  
Vol 134 (1) ◽  
Author(s):  
J. Abdo ◽  
M. Danish Haneef

The idea of pushing the limits of drilling oil and gas wells by improving drilling fluids for undemanding and cost efficient drilling operations by extracting advantage from the wonders of nanotechnology forms the basis of the work presented here. Foremost, in order to highlight the significance of reducing the size distribution of particles, new clay ATR which has a chain like structure and offers enormous surface area and increased reactivity was tested in different sizes that were chemically and mechanically milled. Bentonite which is a commonly used drilling fluid additive was also tested in different particle size distribution (PSD) and rheological properties were tested. Significant reduction in viscosity with small sized particles was recorded. The tested material called ATR throughout this paper is shown to offer better functionality than bentonite without the requirement of other expensive additives. Experiments were performed with different size distributions and compositions and drastic changes in rheological properties are observed. A detailed investigation of the shear thinning behavior was also carried out with ATR samples in order to confirm its functionality for eliminating the problem of mechanical and differential pipe sticking, while retaining suitable viscosity and density for avoidance of problems like lost circulation, poor hole cleaning and inappropriate operating hydrostatic pressures.


2017 ◽  
Vol 899 ◽  
pp. 469-473 ◽  
Author(s):  
Irineu Petri Jr. ◽  
Jéssika Marina dos Santos ◽  
Arley Silva Rossi ◽  
Marina Seixas Pereira ◽  
Claudio Roberto Duarte ◽  
...  

Drill cuttings generated by oil and gas drilling process are incorporated into the drilling fluid to ensure an efficient drilling and solids removal. The drilling rigs have a separation system accountable for separating drill cuttings and drilling fluids. Microwave drying is a new technology of separation that has been studied as an alternative to the currently drill cuttings dryer used. The results obtained in preliminary studies showed that this microwave drying is sensitive to different oxides presents into the rock. Thus, this study aimed to describe the microwave heating kinetics of some rocks in order to verify the interaction of oxides with electromagnetic waves. For this, the oxide contents of the rocks were determined by X-ray Fluorescence and different rocks were heated in a microwave heating unit. The results showed that the relationship between the temperature and heating time is exponential and depends on the rock oxide contents. It was found that the iron oxides may be unstable at microwave and rocks with high levels of magnesium oxides and sulfates tend to be good absorbers of microwave. Rocks containing high levels of calcium, silicon, titanium, barium and chloride (NaCl) are not good absorbers of microwave. It was also noted that faster solid heating, lesser the efficiency of microwave drying.


Author(s):  
Massara Salam ◽  
Nada S. Al-Zubaidi ◽  
Asawer A. Al-Wasiti

In the process of drilling directional, extended-reach, and horizontal wells, the frictional forces between the drill string and the wellbore or casing can cause severe problems including excessive torque which is one of the most important problems during drilling oil and gas well. Drilling fluid plays an important role by reducing these frictional forces. In this research, an enhancement of lubricating properties of drilling fluids was fundamentally examined by adding Lignite NPs into the water-based drilling fluid. Lubricity, Rheology and filtration properties of water-based drilling fluid were measured at room temperature using OFITE EP and Lubricity Tester, OFITE Model 900 Viscometer, and OFITE Low-Pressure Filter Press, respectively. Lignite NPs were added at different concentrations (0.05 %, 0.1 %, 0.2 %, 0.5 %, and 1 %) by weight into water-based drilling fluid. Lignite NPs showed good reduction in COF of water-based drilling fluid. The enhancement was increased with increasing Lignite NPs concentrations; 23.68%, 35.52%, and 45.3 % reduction in COF were obtained by adding 0.2%, 0.5%, and 1% by weight Lignite NPs concentration, respectively.


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