scholarly journals Interrelation of microstructure and thermodynamic parameters in TiNi alloy during multiple martensitic transformations

2019 ◽  
Vol 298 ◽  
pp. 00002
Author(s):  
Anna Churakova

The effect of multiple martensitic transformations on the microstructure and thermodynamic parameters of the alloy of the TiNi system was investigated. It was shown that in the Ti50Ni50 alloy, with an increase in the number of thermal cycles with rapid heating and cooling up to n = 100, a consistent increase in the dislocation density occurs, and a decrease in the width of martensitic plates is observed. And also, that in TCs with fast heating and cooling of the Ti50Ni50 alloy in a coarse-grained state, a change in the trend in the temperatures of martensitic transformations is observed — with an increase in the number of thermal cycles to n = 50, they decrease, and at n> 50 the temperatures increase.

2019 ◽  
Vol 298 ◽  
pp. 00019 ◽  
Author(s):  
Anna Churakova ◽  
Anna Yudahina ◽  
Elina Kayumova ◽  
Nikita Tolstov

Influence of thermomechanical treatment (deformation, thermal cycling treatment in the temperature range of martensitic transformations B2-B19’) on the TiNi alloys’ mechanical behaviour and fracture was studied. Different states were considered, they are initial coarse-grained (CG), ultrafine-grained (UFG) after ECAP (with a grain size of 200 nm), the state after ECAP and cold upsetting by 30% - UFG state with high dislocation density. It was shown that thermal cycling causes some increase in dislocation density, strength and microhardness in all the states. Thermal cycling of UFG alloys allows forming the states with non-equilibrium grain boundaries, with additional dislocations of “phase hardening”. The nature of the fracture was analysed in the TiNi alloy in various states.


2021 ◽  
Vol 2124 (1) ◽  
pp. 012026
Author(s):  
E M Kayumova ◽  
A A Churakova ◽  
O R Latypov

Abstract This article studies the corrosion behavior of the TiNi alloy in the coarse-grained and ultrafine-grained states. The study of the influence of the initial microstructure on the corrosion behavior of the TiNi alloy was carried out by the gravimetric method in the NaCl and H2SO4 solution for a month. Studies was shown that as a result of the action of a corrosive medium from a sample in a coarse-grained state, it undergoes greater destruction, pitting corrosion was observed, at the same time, in an ultrafine-grained sample only traces of corrosion products are observed on the surface of the samples. Investigations with an inverted light microscope in a dark field made it possible to observe corrosion products and determine their volume fraction. Evaluation of the corrosion rate showed that in the coarse-grained state it is 126 times higher than the corrosion rate in the ultrafine-grained state. Analysis of X-ray phase analysis showed that in the coarse-grained state after corrosion tests, a significant proportion of the TiNiH1.4 phase is observed, while in the ultrafine-grained state all phases correspond only to the TiNi phases. The TiNi alloy contains an Ti2Ni phase enriched Ti both in the coarse-grained state and in the ultrafine-grained state. Moreover, in a coarse-grained state, its share is 2 times higher.


2022 ◽  
Author(s):  
A. Churakova

Abstract. In this work was investigate the corrosion behavior of the TiNi alloy in a coarse-grained state in inorganic field with different concentration and holding time. An increase in the concentration of the solution leads to a significant acceleration of corrosion processes in the Ti49.1Ni50.9 alloy with a high Ni content, including until the samples are completely dissolved. It was revealed that solutions of 1 M sulfuric and hydrochloric acids after a month's exposure did not change in color and no precipitations were found, while solutions of 5 M hydrochloric and sulfuric acids acquired a violet and then green color, which is due to the predominant release of titanium ions (+4) and nickel (+2).


2020 ◽  
Author(s):  
Chi-Toan Nguyen ◽  
Alistair Garner ◽  
Javier Romero ◽  
Antoine Ambard ◽  
Michael Preuss ◽  
...  

Author(s):  
Nicolas Scepi ◽  
Mitchell C Begelman ◽  
Jason Dexter

Abstract Dwarf novæ (DNe) and low mass X-ray binaries (LMXBs) are compact binaries showing variability on time scales from years to less than seconds. Here, we focus on explaining part of the rapid fluctuations in DNe, following the framework of recent studies on the monthly eruptions of DNe that use a hybrid disk composed of an outer standard disk and an inner magnetized disk. We show that the ionization instability, that is responsible for the monthly eruptions of DNe, is also able to operate in the inner magnetized disk. Given the low density and the fast accretion time scale of the inner magnetized disk, the ionization instability generates small, rapid heating and cooling fronts propagating back and forth in the inner disk. This leads to quasi-periodic oscillations (QPOs) with a period of the order of 1000 s. A strong prediction of our model is that these QPOs can only develop in quiescence or at the beginning/end of an outburst. We propose that these rapid fluctuations might explain a subclass of already observed QPOs in DNe as well as a, still to observe, subclass of QPOs in LMXBs. We also extrapolate to the possibility that the radiation pressure instability might be related to Type B QPOs in LMXBs.


Author(s):  
A. Paulsen ◽  
H. Dumlu ◽  
D. Piorunek ◽  
D. Langenkämper ◽  
J. Frenzel ◽  
...  

AbstractTi75Ta25 high-temperature shape memory alloys exhibit a number of features which make it difficult to use them as spring actuators. These include the high melting point of Ta (close to 3000 °C), the affinity of Ti to oxygen which leads to the formation of brittle α-case layers and the tendency to precipitate the ω-phase, which suppresses the martensitic transformation. The present work represents a case study which shows how one can overcome these issues and manufacture high quality Ti75Ta25 tensile spring actuators. The work focusses on processing (arc melting, arc welding, wire drawing, surface treatments and actuator spring geometry setting) and on cyclic actuator testing. It is shown how one can minimize the detrimental effect of ω-phase formation and ensure stable high-temperature actuation by fast heating and cooling and by intermediate rejuvenation anneals. The results are discussed on the basis of fundamental Ti–Ta metallurgy and in the light of Ni–Ti spring actuator performance.


1970 ◽  
Vol 12 (2) ◽  
pp. 156-159 ◽  
Author(s):  
V. P. Kurbatov ◽  
V. I. Murav'ev

2014 ◽  
Vol 2014 (1) ◽  
pp. 000100-000106
Author(s):  
Tom Colosimo ◽  
Horst Clauberg ◽  
Evan Galipeau ◽  
Matthew B. Wasserman ◽  
Michael Schmidt-Lange ◽  
...  

Advancements in electronic packaging performance and cost have historically been driven by higher integration primarily provided by fab shrinks that has followed the well-known Moore's law. However, due to the tremendous and continuously increasing cost of building new fabs, the performance/cost improvements achieved via node shrinks are negated. This leaves packaging innovation as the vehicle to achieve future cost-performance improvements. This has initiated a More-than-Moore idea that has led to vigorous R&D in packaging. Advanced packages which employ ultra-fine pitch flip chip technology for chip-to-substrate, chip-to-chip, or chip-to-interposer for the first level interconnect have been developed as an answer to obtaining higher performance. However, the costs are too high as compared to traditional wire bonding. The status today is that the fundamental technical hurdles of manufacturing the new advanced packages have been solved, but cost reduction and yield improvements have to be addressed for large-scale adoption into high volume manufacturing. In traditional flip chip assembly silicon chips are tacked onto a substrate and then the solder joints are melted and mass reflowed in an oven. This mass reflow technique is troublesome as the pitch of the solder bumps become finer. This is due to the large differences in the thermal expansion coefficient of the die and the substrate, which creates stress at the solder joints and warpage of the package when the die and substrate are heated and cooled together. To mitigate and resolve this issue, thermo-compression bonders have been developed which locally reflow the solder without subjecting the entire substrate to the heating and cooling cycle. This requires that the bondhead undergo heating past the melting point of solder and then cooling down to a low enough temperature to pick the next die from the wafer that is mounted to tape. Machines in the market today can accomplish this temperature cycle in 7 to 15 seconds. This is substantially slower than the standard flip chip process which leads to high cost and is delaying the introduction of these new packages. This paper shows a flip chip bonder with a new heating and cooling concept that will radically improve the productivity of thermo-compression bonding. Data and productivity cycles from this new bond head with heating rates of over 200°C/sec and cooling of faster than 100°C/sec are revealed. Experimental results are shown of exceptional temperature accuracy across the die of 5°C throughout the cycle and better than 3°C at the final heating stage. The high speed thermo-compression bonds are analyzed and the efficacy of the new concept is proven. Excellent temperature uniformity while heating rapidly is an absolute necessity for enabling good solder joints in a fast process. Without good temperature uniformity, additional dwell times need to be incorporated to allow heat to flow to all of the joints, negating any benefits from rapid heating. Whereas the current state-of-that-art is often to program temperature in steps, this bonder can be commanded and accurately follows more complex temperature profiles with great accuracy. Examples of how this profiling can be used to enhance the uniformity and integrity of the joints with non-conductive pastes, film, and without underfill along with the associated productivity improvements will be shown. Tests that show portability across platforms that will lead to set up time and yield improvements and are identified and quantified. Additionally new ideas for materials and equipment development to further enhance productivity and yield are explored.


2004 ◽  
Vol 120 ◽  
pp. 405-412
Author(s):  
J. Ahlström ◽  
B. Karlsson ◽  
S. Niederhauser

A model on laser cladding of medium carbon steel, used in railway wheels and rails, is developed and implemented. When the laser beam is scanned over the surface during the cladding operation, phase transformations occur in the topmost layer of the substrate material due to rapid heating and cooling. The hardened regions may later be annealed, either during subsequent passes of the laser beam or by for example induction heating. The current model is a first step towards judging the resulting microstructure and hardness in the heat affected zone under the clad.


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