scholarly journals The influence of fibre pre-treatment on the mechanical properties of the geopolymer composites

2020 ◽  
Vol 322 ◽  
pp. 01012
Author(s):  
Kinga Korniejenko ◽  
Beata Figiela ◽  
Hana Šimonová ◽  
Barbara Kucharczyková ◽  
Martin Duarte Guigou ◽  
...  

This article aims to analyse the long-term influence of the pre- treatment method on mechanical properties such as the compressive strength of geopolymer composites reinforced with short natural fibres (length of around 5 mm). This paper presents the behaviour of sodium activator-synthesised fly ash geopolymer containing natural fibres at ambient temperatures. Fly ash from the Skawina coal power plant (located in: Skawina, Lesser Poland, Poland) was used as a raw material. The chemical composition of the fly ash was typical for class F. The article evaluated the methods of pre-treatment of the fibres on the mechanical properties of the geopolymer composites. It compares the plain specimens and composites with fibres pre-treated in water and alkali solutions as well as with fibres without any pre-treatment. The fibres were added at the amount of 1% by weight. The investigation was made by visual analysis and the testing of mechanical properties (compressive and flexural strength at ambient temperature) after 6 months. The achieved results do not confirm the positive influence of the fibre pre-treatment on the mechanical properties of the composites.

2020 ◽  
Vol 322 ◽  
pp. 01004
Author(s):  
Kinga Korniejenko ◽  
Dariusz Mierzwiński ◽  
Roland Szabó ◽  
Nóra Papné Halyag ◽  
Petr Louda ◽  
...  

Efflorescence is one of the limitations of the widespread use of geopolymers. This problem is caused by excess unreacted sodium oxide remaining inside materials. Unreacted sodium oxide creates white efflorescence on the surface of the produced material in the form of sodium carbonate heptahydrate Na2CO3∙ 7H2O. It decreases not only the aesthetic value of the final products, but also the mechanical properties of the material. The aim of this article is to analyse the influence of the curing method on the appearance of efflorescence on geopolymer composites reinforced by short basalt, especially on mechanical properties. Class F fly ash from the ‘Skawina’ coal-fired power plant (located in Skawina, Lesser Poland, Poland) was used as raw material for the geopolymerization process. The article compares two methods of curing: typical laboratory conditions (in the air) and samples submerged in water. Three series of fly ash-based geopolymer were cast: basalt fibres were added as 1% and 2% by weight of fly ash and one control series without any fibres. The investigation was performed using visual analysis, including microstructure investigation, and the testing of mechanical properties (compressive strength at ambient temperature) after 28 days.


Author(s):  
Kinga Korniejenko ◽  
Gábor Mucsi ◽  
Nóra Papné Halyag ◽  
Roland Szabó ◽  
Dariusz Mierzwiński ◽  
...  

This article analyses the influence of a short basalt fibre admixture on the mechanical properties of geopolymers, especially compressive strength. This preliminary research is the first step towards the development of a composite for fire resistant applications in civil engineering. This study investigates the behaviour of a fly ash based geopolymer containing basalt fibres. Fly ash from the coal power plant ‘Skawina’ (located in: Skawina, Lesser Poland, Poland) was used as the raw material. The chemical composition of this fly ash is typical for class F. Three series of fly ash based geopolymers were cast. In the first, short basalt fibres were added as 1% by weight of fly ash, in the second short basalt fibres were added as 2% by weight of fly ash and the third functioned as a control series without any fibres. Each series of samples were tested on compressive strength after 28, 14 and 7 days, and specimen density was determined. Additionally, microstructural analysis was carried out after 28 days. The results show that the addition of basalt fibres can improve the mechanical properties of geopolymer composites. Keywords: geopolymer, basalt fibre, composites, fire resistance


Materials ◽  
2019 ◽  
Vol 12 (9) ◽  
pp. 1459 ◽  
Author(s):  
Hasan Assaedi ◽  
Thamer Alomayri ◽  
Faiz Shaikh ◽  
It-Meng Low

The durability of natural fibres as reinforcement in geopolymer composites continues to be a matter of concern due to the alkalinity of activators of geopolymer matrices. The alkaline environment is the main reason for natural fibres degradation in cementitious matrices. This paper presents the influence of nano silica (NS) on the durability and mechanical performance of geopolymer composites that are reinforced with flax fabric (FF). The durability investigations were conducted after the storage of samples at ambient temperature for 32 weeks. The study revealed that the addition of nano silica has a positive influence on the physical and mechanical properties of these composites. The presence of NS accelerated the geopolymeric reaction and lowered the alkalinity of the system, thus reducing the degradation of flax fibres.


2021 ◽  

Concrete is the most versatile, durable and reliable material and is the most used building material. It requires large amounts of Portland cement which has environmental problems associated with its production. Hence, an alternative concrete – geopolymer concrete is needed. The general aim of this book is to make significant contributions in understanding and deciphering the mechanisms of the realization of the alkali-activated fly ash-based geopolymer concrete and, at the same time, to present the main characteristics of the materials, components, as well as the influence that they have on the performance of the mechanical properties of the concrete. The book deals with in-depth research of the potential recovery of fly ash and using it as a raw material for the development of new construction materials, offering sustainable solutions to the construction industry.


2015 ◽  
Vol 244 ◽  
pp. 140-145 ◽  
Author(s):  
Matej Špak ◽  
Pavel Raschman

Fly ash is a well utilizable secondary raw material for the production of alkali activated construction materials. It is a significant alumina-silicates source suitable for the chemical reaction resulting in hardened composites. Physical and chemical properties of fly ashes as a co-product of coal burning mainly depend on characteristics of coal, burning temperature and combustion conditions. High variability of the properties of fly ash causes an uncertainty in the properties of alkali activated mortars. Time behaviour of the composition of the fly ash produced in a heating plant located in Košice, Slovakia as well as leaching behaviour of both alumina and silica from particular batches during one-year period was documented. Leaching tests were carried out using the distilled water and alkali solutions with three different concentrations. Both compressive and tensile strengths of alkali activated mortars were measured, and the correlation between the mechanical properties of hardened mortars and the chemical composition of fly ashes as well as their leaching characteristics was investigated.


2013 ◽  
Vol 831 ◽  
pp. 62-66
Author(s):  
Chen Si ◽  
Zhu Ge Yan ◽  
De Ping Xu

This paper presents a discussion of factors affecting the performance of fly ash based geopolymer, and some recent innovations on fly ash based geopolymer. The characteristics of fly ash based geopolymer are discussed in terms of the effects of raw material selection, alkaline activators, and curing procedures. Nowadays, researchers have used geopolymer as a cementitious material to develop innovative geopolymer materials, such as porous, fibre reinforced and foam fly ash based geopolymer concrete, which are greener than the traditional cementitious material. The high-calcium fly ashes could be used to produce porous fly ash based geopolymer composites with satisfactory mechanical properties. The addition of fibres increases greatly the ductility of geopolymer. Foam can be added to the geopolymeric mixture to produce lightweight concrete. However, the manufacturing of fly ash-based geopolymer foam concrete has not been explored too much.


2021 ◽  
pp. 252-261

The combustion of fossil fuels results in creating a lot of solid wastes such as fly ash and slag. However, these environmentally unfriendly materials can be used as a raw material for alkali activation – geopolymerization. Although these wastes have been successfully used in industrial production for several decades, its use does not achieve the level of its potential. Today, to achieve a sustainable construction industry, alternative cement has been extensively investigated. Geopolymer (GP) is a kind of material that is obtained from the alkaline activator, and it can be produced from industrial wastes or by-products. The aim of this work was to describe the improvement of mechanical properties of alkali-activated binders – geopolymers made of fly ash and blast furnace slag. The effect of the addition of waste glass in three different values feed into fly ash or GGBFS, and its impact on mechanical properties (compressive and flexural strengths) of geopolymers was examined. The highest value of compressive strength was achieved with 20% waste glass addition to a fly ash sample on 90th day 58,9 MPa. The waste glass was added in the form of broken and crushed glass particles.


2016 ◽  
Vol 1812 ◽  
pp. 89-94
Author(s):  
Claudia M. Lopez-Badillo ◽  
Jorge López-Cuevas ◽  
Carlos A. Gutiérrez-Chavarría ◽  
José L. Rodríguez-Galicia ◽  
Elia M. Múzquiz-Ramos

ABSTRACTBaAl2Si2O8 and SrAl2Si2O8 were synthesized by solid-state reaction of stoichiometric mixtures of either BaCO3 or SrCO3 with coal fly ash and Al2O3. The mixtures were mechanically activated in an attrition mill for up to 12 h and then reaction-sintered at 900-1300 °C, aiming to promote the formation of BaAl2Si2O8 and SrAl2Si2O8 as well as the conversion from their hexagonal (Hexacelsian) into their monoclinic (Celsian) forms, which is associated with improved mechanical properties in the sintered materials. Especially in the case of SrAl2Si2O8, the formation of Celsian was favored at relatively low sintering temperatures by increasing milling time. Although only the SrAl2Si2O8 composition was fully converted into Celsian, the Hexacelsian to Celsian conversions obtained for the mechanically-activated BaAl2Si2O8 composition were significantly higher than those previously reported in the literature for this compound. This could be attributed to the use of coal fly ash as raw material, which contains mineralizers that promote the mentioned conversion.


2014 ◽  
Vol 600 ◽  
pp. 452-459 ◽  
Author(s):  
Mariana Gatani ◽  
Victoria Granero ◽  
Juan Carlos Medina ◽  
Juliano Fiorelli ◽  
Josefina Lerda ◽  
...  

New materials are being developed for architectural and design purposes. The recycling of waste is presented as an opportunity for new applications based on increased industrial waste and raw material shortages. Seeking an alternative to wooden panels, regional waste without sustainable disposal is being used as inputs in the production of lignocellulosic panels. We present the results of two experiments. The first one consists in the development of peanut husks ground-treated and untreated panels made in order to determine the influence of different particle sizes, shapes and their combinations, aiming to the physical and mechanical characterization of compact panels properties. In the second experiment, compact panels with whole peanut husks were made with polyurethane resin using castor oil painting. The object of this study was to analyze the influence of this new resin, without formaldehyde emissions, in the resulting panels physical and mechanical properties. It was concluded that the smaller particles had a positive influence in the panels physical-mechanical properties, and that the property characterization of panels made with castor oil resin was satisfactory for use in interior furniture. Peanut husks panels show good prospects for their integration in the field of design and architecture.


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