scholarly journals Comparison of mechanical properties of geopolymers from different raw materials with the addition of waste glass

2021 ◽  
pp. 252-261

The combustion of fossil fuels results in creating a lot of solid wastes such as fly ash and slag. However, these environmentally unfriendly materials can be used as a raw material for alkali activation – geopolymerization. Although these wastes have been successfully used in industrial production for several decades, its use does not achieve the level of its potential. Today, to achieve a sustainable construction industry, alternative cement has been extensively investigated. Geopolymer (GP) is a kind of material that is obtained from the alkaline activator, and it can be produced from industrial wastes or by-products. The aim of this work was to describe the improvement of mechanical properties of alkali-activated binders – geopolymers made of fly ash and blast furnace slag. The effect of the addition of waste glass in three different values feed into fly ash or GGBFS, and its impact on mechanical properties (compressive and flexural strengths) of geopolymers was examined. The highest value of compressive strength was achieved with 20% waste glass addition to a fly ash sample on 90th day 58,9 MPa. The waste glass was added in the form of broken and crushed glass particles.

2015 ◽  
Vol 1124 ◽  
pp. 177-182
Author(s):  
Vit Cerný

Combustion of coal creates a high amount of by-products in heat power plants. The largest share occupies fly ash as solid mineral residuals. Global pressure grows currently for the use of energy by-products. Utilization as a raw material for production of artificial sintered aggregate is one of the ways to make optimal use of even low-quality fly ash. Environmental and economic reasons lead currently to trying to upgrade the technology, which will fully use of the principle of self-sintering process based on content of combustible substances.The amount of combustible substances is today increasing by coal as a primary and finite resource. There is also best way for utilization of industrial wastes that contain a suitable share of combustible substances for ensure the smooth running of sintering.The paper deals with laboratory verification of selected industrial wastes as a correction component in the sintered aggregate production technology. As an alternative raw materials were selected coal tailings, sludge from paper industry, sludge from waste water treatment plant and fly ash from municipal waste incineration plant. The aim of the study was to investigate the effect of corrective components to the quality of the resulting sintered aggregates.


Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 197
Author(s):  
Jozef Vlček ◽  
Michaela Topinková ◽  
Miroslava Klárová ◽  
Petra Maierová ◽  
Hana Ovčačíková ◽  
...  

Metakaolin (MK) prepared by the calcination of kaolin at 550 °C and fly ash (FA) from the combustion of black coal in a granulating boiler were used to prepare unfired ceramic bonding systems via the alkali activation process. A long-term stability of the mechanical properties of the prepared samples similar to the unfired ceramic systems was observed. The optimal metakaolin and fly ash ratio, the type of the activator (NaOH or water glass) and its concentration were evaluated after the hydration in: a) laboratory conditions; b) hydration box; and c) under the hydrothermal activation. Raw materials and the samples prepared by alkali activation process were characterized by XRD, XRF, TG/DTA, and FTIR methods. The mechanical properties of the prepared samples were tested using a compressive strength test after 2, 28 and 56 days of hydration. The compressive strengths of 16 and 24 MPa after 28 days of hydration were reached for FA samples activated with water glass. The alkali activation of MK was successful in the NaOH solution of the molar concentration above 5 M. The compressive strength values of metakaolin, activated hydrothermally and hydrated at laboratory conditions, reached 11.2 and 5.5 MPa, respectively, for 5 M activator of NaOH.


2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Hong-xia Zhai ◽  
Yu-zhao Tang ◽  
Shu-hang Chen ◽  
Hui-hua Chen ◽  
Bao-quan Cheng ◽  
...  

This paper focused on the optimization of the C40 fly ash concrete pavement, which was considered as a measure to accelerate the consumption of industrial solid wastes such as fly ash, committing to the goal of zero waste. By comparing with three groups of ordinary mix proportion, the performances (e.g., mechanical properties, durability, and brittle property) of the optimized mix proportion were evaluated via multiple mechanical and physical tests. Their air voids’ structure was characterized by the BJH method (a method to calculate pore size described by Barrett, Joyner, and Halenda), and the results were combined with the road performances of concrete to analyze the formation mechanism of high durability of optimized fly ash pavement concrete. As for the experimental results for the optimized, its 28 d compressive strength peaked at 50.8 MPa together with corresponding 28 d flexural strength at 8.2 MPa, which indicated a favorable mechanical performance for wide application in pavement construction. Except for the mechanical properties, the better durability indicators obtained after optimization also provided a more compact pore structure for the optimized. The raw materials and construction technology of the two kinds of pavements were compared. Promoting the use of optimized fly ash pavement concrete can break the situation of the asphalt pavement monopolizing heavy-haul highway and greatly reduce the industrial wastes which can be used as raw materials in the production of cement, such as blast furnace slag and fly ash. It was proved that the optimized fly ash concrete pavement can be used to replace the asphalt pavement under the premise of achieving the same working performances.


2013 ◽  
Vol 591 ◽  
pp. 130-133 ◽  
Author(s):  
Rong Zhao ◽  
Feng Lan Han

In this study, reference the method of preparing cement sand to produce geopolymer, using Electrolytic Manganese Residue(EMR), fly ash, magnesium slag (with boric acid), sodium silicate, sand, calcined kaolin as the main raw materials, focus on the study of using electrolytic manganese residue to produce Geopolymeric cement. Finally, through a series of comparison, we find out the best recipe of Geopolymer preparation, and the best ratio of each raw material is 80% EMR, 10% magnesium slag, 10% fly ash. In this way, the Geopolymer has the best mechanical properties.


2019 ◽  
Vol 22 ◽  
pp. 26-30
Author(s):  
Radek Hermann ◽  
Rostislav Drochytka ◽  
Jiří Kolísko ◽  
Pavel Reiterman

This paper addresses optimization of mix-design and granulometric curves of aggregate of chemically resistant cementitious sprayed mix. The target of the paper is to improve properties of currently developed mix-design, which has no chemical resistance, and to utilize the secondary raw materials. The mix was optimized by additions improving chemical resistance and binder substituted by secondary raw materials. The binder was substituted by finely ground waste glass and high-temperature fly ash. Filler was substituted with slag from deposit yard and waste sand with soluble glass from steel manufacture. Main observed properties for design of optimized mix were workability time, consistence and physical-mechanical properties. Optimized mix-design successfully replaced all fine parts of filler and up to 30% of binder while the physical-mechanical properties were preserved or even enhanced. Optimized mix-designs show the same consistencies and workability times.


2021 ◽  
Vol 5 (6) ◽  
pp. 151
Author(s):  
Mustapha El Kanzaoui ◽  
Chouaib Ennawaoui ◽  
Saleh Eladaoui ◽  
Abdelowahed Hajjaji ◽  
Abdellah Guenbour ◽  
...  

Given the amount of industrial waste produced and collected in the world today, a recycling and recovery process is needed. The study carried out on this subject focuses on the valorization of one of these industrial wastes, namely the fly ash produced by an ultra-supercritical coal power plant. This paper describes the use and recovery of fly ash as a high percentage reinforcement for the development of a new high-performance composite material for use in various fields. The raw material, fly ash, comes from the staged combustion of coal, which occurs in the furnace of an ultra-supercritical boiler of a coal-fired power plant. Mechanical compression, thermal conductivity, and erosion tests are used to study the mechanical, thermal, and erosion behavior of this new composite material. The mineralogical and textural analyses of samples were characterized using Scanning Electron Microscopy (SEM). SEM confirmed the formation of a new composite by a polymerization reaction. The results obtained are very remarkable, with a high Young’s modulus and a criterion of insulation, which approves the presence of a potential to be exploited in the different fields of materials. In conclusion, the composite material presented in this study has great potential for building material and could represent interesting candidates for the smart city.


2016 ◽  
Vol 881 ◽  
pp. 383-386 ◽  
Author(s):  
Raimundo J.S. Paranhos ◽  
Wilson Acchar ◽  
Vamberto Monteiro Silva

This study evaluated the potential use of Sugarcane Bagasse Ashes (SBA) as a flux, replacing phyllite for the production of enamelled porcelain tile. The raw materials of the standard mass components and the SBA residue were characterized by testing by XRF, XRD, AG, DTA and TGA. Test samples were fabricated, assembled in lots of 3 units and sintered at temperatures of 1150 ° C to 1210 ° C. The results of the physical properties, mechanical properties and SEM of the sintered samples, showed that the formulation, G4 - in which applied 10% of SBA replacing phyllite, sintering temperature 1210 ° C showed better performance as the previously mentioned properties due to the formation of mullite crystals, meeting the prerequisites of standards for enamelled porcelain tile, while reducing the environmental impact and the cost of production.


2021 ◽  

Concrete is the most versatile, durable and reliable material and is the most used building material. It requires large amounts of Portland cement which has environmental problems associated with its production. Hence, an alternative concrete – geopolymer concrete is needed. The general aim of this book is to make significant contributions in understanding and deciphering the mechanisms of the realization of the alkali-activated fly ash-based geopolymer concrete and, at the same time, to present the main characteristics of the materials, components, as well as the influence that they have on the performance of the mechanical properties of the concrete. The book deals with in-depth research of the potential recovery of fly ash and using it as a raw material for the development of new construction materials, offering sustainable solutions to the construction industry.


2021 ◽  
Vol 898 ◽  
pp. 27-33
Author(s):  
Petr Figala ◽  
Rostislav Drochytka ◽  
Vit Černý ◽  
Radek Hermann ◽  
Jiří Kolísko

This paper deals with the study of chemical resistance of new cement-based grout for invert grouting. The aim of this work is to verify new mixtures with specific admixtures. The study monitors resistance to external sulphate attack. Specimens were placed into sulphate solution 29.8 g∙l-1 (44 g∙l-1 Na2SO4) according to DIN19753 standard. Based on the results gained, new mixtures will be designed and optimized by addition of suitable secondary raw materials (fly ash, waste foundry sand, waste glass, waste filers).


2014 ◽  
Vol 602-603 ◽  
pp. 640-643
Author(s):  
Yu Fei Chen ◽  
Yan Gai Liu ◽  
Xiao Wen Wu ◽  
Zhao Hui Huang ◽  
Ming Hao Fang

Mica glass-ceramics can be applied in all kinds of electrical equipment, locomotive internal circuits in high-speed rail, ordinary electric locomotive and subway locomotive. In this study, mica glass-ceramics were prepared by sintering process using flake mica and waste glass as the main raw material with low cost. Different mica glass-ceramic samples were fabricated by changing the formula of raw materials, molding process and sintering temperature. X-ray diffraction, scanning electron microscopy, three-point bending test, and balanced-bridge technique were applied to investigate the phase, microstructure, mechanical and electrical resistivities of the samples, respectively. The results show that the optimum sintering temperature is 900 to 1000 °C holding for two hours, the desirable ratio is 70 wt% of mica powder while 30 wt% of glass powder. In that condition the sample could be less porosity, high flexural strength (63.3 MPa) and eligible electrical resistivity (0.4×1013 Ω·cm).


Sign in / Sign up

Export Citation Format

Share Document