scholarly journals Stabilization of the Dispersed System of Halloysite Nanotubes for Silicate Constructional Material

2021 ◽  
Vol 346 ◽  
pp. 02026
Author(s):  
Natalia Lukuttsova ◽  
Sergey Golovin ◽  
Natalia Zolotukhina ◽  
Olga Sycheva

The stabilization of the dispersed system of halloysite nanotubes (HN) obtained by ultrasonic treatment (UST) in the aqueous medium of the stabilizers of sodium polynaphthalene methylene sulfonate stabilizers (S-3) and a synthetic compound based on polycarboxylate ether (MG) is considered. The morphology of halloysite is studied. Various mechanisms of aggregate stability connected with the spatial obstacles to aggregation due to the action of electrostatic, adsorption-solvate, and structural-mechanical stabilization factors are established. Three variants of introducing S-3 and MG stabilizers into the dispersed system of halloysite nanotubes are considered. It has been found that the most preferred method is the one with the stabilizer added in two steps. In this variant halloysite nanotubes are of minimum size and with maximum specific surface area. The maximum ζ-potential values of 52.9 mV and 43.8 mV are obtained for the dispersed system stabilized with S-3.

Geosciences ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 28
Author(s):  
Gaetano Festa ◽  
Guido Maria Adinolfi ◽  
Alessandro Caruso ◽  
Simona Colombelli ◽  
Grazia De Landro ◽  
...  

Seismic sequences are a powerful tool to locally infer geometrical and mechanical properties of faults and fault systems. In this study, we provided detailed location and characterization of events of the 3–7 July 2020 Irpinia sequence (southern Italy) that occurred at the northern tip of the main segment that ruptured during the 1980 Irpinia earthquake. Using an autocorrelation technique, we detected more than 340 events within the sequence, with local magnitude ranging between −0.5 and 3.0. We thus provided double difference locations, source parameter estimation, and focal mechanisms determination for the largest quality events. We found that the sequence ruptured an asperity with a size of about 800 m, along a fault structure having a strike compatible with the one of the main segments of the 1980 Irpinia earthquake, and a dip of 50–55° at depth of 10.5–12 km and 60–65° at shallower depths (7.5–9 km). Low stress drop release (average of 0.64 MPa) indicates a fluid-driven initiation mechanism of the sequence. We also evaluated the performance of the earthquake early warning systems running in real-time during the sequence, retrieving a minimum size for the blind zone in the area of about 15 km.


NANO ◽  
2015 ◽  
Vol 10 (01) ◽  
pp. 1550005 ◽  
Author(s):  
Yaling Xie ◽  
Aidong Tang ◽  
Huaming Yang

Nanoporous materials Al -MCM-41 with varying Si / Al molar ratios have been successfully synthesized from natural clay mineral halloysite nanotubes (HNTs). Hydrothermal treatment of acid-pretreated HNTs and NaOH solution resulted in the one-step synthesis of final nanoporous products by using surfactant. The effects of Si / Al molar ratios (7.7, 61.0 and 176.5) on the surface area, porosity and degree of structural order of Al -MCM-41 materials have been investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), N 2 adsorption–desorption measurements and Fourier transform infrared (FTIR) spectra techniques. The results indicated that Si / Al molar ratio had important effect on the characteristics of nanoporous materials, and Al -MCM-41 with an intermediate Si / Al molar ratio of 61.0 exhibited excellent characteristics with high degree of order, high surface area (S BET ) of 1033 m2/g and pore volume of 0.92 mL/g.


Author(s):  
Fernando López Ramón

<p align="justify">Partiendo de la notable fragmentación del mapa municipal español en el contexto europeo, se ofrecen elementos estadísticos, históricos y comparados que podrían proporcionar los siguientes criterios de reforma: 1) las diferencias existentes entre los mapas municipales de las Comunidades Autónomas justifican políticas no coincidentes; 2) el tamaño importa, de manera que, distanciándose tanto de posturas inmovilistas como de opciones por la movilidad constante en la organización territorial, cabría establecer un tamaño mínimo de los municipios en la legislación básica del Estado sin perjuicio del diseño de tamaños óptimos por las Comunidades Autónomas; 3) la cooperación intermunicipal como alternativa a las fusiones de municipios requiere esfuerzos sostenidos en el tiempo, y presenta notas de complejidad y de confusión de responsabilidades, según se advierte en el caso de Francia; 4) las fusiones municipales determinadas por fines de equilibrio territorial pueden ser más útiles que las establecidas por razones de eficiencia económica, tal y como ponen de relieve las experiencias europeas de Suecia, Dinamarca, Bélgica y Grecia; y 5) las comarcas como vía alternativa de solución del inframunicipalismo presentan limitaciones, aunque no habría de descartarse el empleo de mapas comarcales para constituir nuevos mapas municipales.</p> <p align="justify"><b>Starting from the remarkable fragmentation of the Spanish municipal map within the European context, the work presents statistical, historical and comparative information that provide the following criteria for a reform: 1) the differences between regions justify different local policies; 2) size matters are important, so, far away from extremist positions (ie immobilism, on the one hand, and constant reshape of municipalities, on the other), a minimum size for municipalities shall be determined by the basic State law, without prejudice to the design of optimal sizes by the Autonomous Regions in their respective territories; 3) intermunicipal cooperation as an alternative to mergers between municipalities requires sustained efforts over time, and is subject to complexity and confusion of responsibilities, as the French experience shows; 4) municipal mergers motivated by objectives of territorial balance may be more useful than those originated by reasons of economic efficiency, as is highlighted in the experience of Sweden, Denmark, Belgium and Greece; and 5)) counties (“comarcas”) as an alternative way of dealing with the problem of infra-size of municipalities have their limitations, although the use of county maps to establish new municipal maps should not be discarded.</p>


2003 ◽  
Vol 13 (1) ◽  
pp. 47-53 ◽  
Author(s):  
Radu Matei ◽  
Liviu Goraç

In this paper we investigate the linear filtering capabilities of the standard cellular neural network in the general case of non-symmetric templates. We approached here systematically the CNNs with minimum-size templates (1x3), analyzing in detail their filtering capabilities in the one-dimensional case. Starting from a general form of the spatial transfer function, we emphasize some useful filtering functions that can be obtained. For each filter type, we derive the relations which give the template parameter values, in order to design a given CNN filter with specified characteristics-like central frequency, bandwidth, selectivity etc. Filters with symmetric templates are treated as a particular case. For each type of filtering the characteristics are shown and simulation results are presented as well. Some of these results are then extended to 2-D CNNs and several simulations of useful filtering tasks are presented on real images.


Author(s):  
Y. Chi ◽  
R. Du

Heat pipes have been applied popularly in microelectronic cooling, in which grooved heat pipes are the one of main types. Most of commercial grooved heat pipes with OD 6mm have 55 grooves and the groove width is larger than 200μm, which causes the biggest drawback of grooved heat pipes having no fine anti-gravity performance. In this paper, a fabrication method of inner micro-grooved pipes is investigated. First, a die with micro-tooth was fabricated by micro wire electrical discharge machining (WEDM). Utilizing micro wire with diameter in 30μm, it can machine micro slot with minimum size of 45μm wide, the surface roughness (Ra) is smaller than 0.1μm. Then, the die forms the micro grooves on the inner wall of pipes by high-speed spinning process. Last, the grooved pipes were draw to reduce the pipe diameter further, and then smaller grooves can be formed. The experiment results show that the width of obtained grooves is less than 100μm and the depth is about 250μm. The depth-to-width ratio increases significantly. The capillary force improves by double times, so the anti-gravity performance is better.


OENO One ◽  
2021 ◽  
Vol 55 (1) ◽  
pp. 295-312
Author(s):  
Javier Abad ◽  
Iranzu Hermoso de Mendoza ◽  
Diana Marín ◽  
Luis Orcaray ◽  
Luis Gonzaga Santesteban

This work seeks to synthesise the knowledge on the use of cover crops in vineyards in the last 20 years, emphasising on the one hand, soil characteristics such as nutrition, organic carbon, structure or erosion and, on the other hand, environmental factors such as soil and biodiversity in vineyards, and gas emissions.A systematic review was made using Scopus-index journals for the past 20 years (1999 - 2018). The selection was independently done by two researchers, selecting a total of 272 published papers related to cover crops in the vineyard. Each article was categorised according to its theme and metadata were created, considering all relevant information from an agro-ecological point of view.The use of cover crops has a positive effect on the vineyard by increasing soil organic carbon (SOC), improving water infiltration and aggregate stability, and reducing erosion and greenhouse gases emission to the atmosphere. Furthermore, there is an increase in biodiversity, both in soil and the vineyard. Finally, cover crops do not constitute as a rule a major competition for nutrients to the vines except for nitrogen when grass covers are used. Contrarily, legume cover crops generally increase N in the soil, although its availability for plants is not immediate.This review constitutes an objective tool to help growers when considering the use of cover crops in vineyards that, based in a systematic review, provides relevant information depending on the characteristics of the growing condition of the vineyard.


2019 ◽  
Vol 1 ◽  
pp. 1-2
Author(s):  
Enrique J. Arriaga-Varela ◽  
Toru Takahashi

<p><strong>Abstract.</strong> The process of manually georeferencing or aligning historic or illustrated maps with contemporary maps can be a difficult and time consuming task (Fleet et al., 2012). It is generally accepted that the level of understanding necessary to correctly georeference a single image can be rather daunting (Bajcsy and Alumbaugh, 2003). This is especially challenging in an open environment where there is no previous information to help approximating the real coordinates.</p><p>Over the last couple of decades there have been advances in the automatic georeferencing of map images, aerial photographs or raster maps (Chen et al., 2004), (Desai et al., 2005), (Kim et al., 2010), (Cléry et al., 2014). However, there has been little discussion dealing with heterogeneous maps. For instance, some algorithms apply fixed image processing techniques to find features within the map images, and then try to match these patterns of features to a database of geographical information (Chen et al., 2004). The drawback with this approach is that the image processing operations used in a particular style may not work for a map created using a different style. Other techniques only work for a specific kind of map, like street maps (Desai et al., 2005) or aerial photographs (Kim et al., 2010). Furthermore, the artistic vision of the creator or the theme of the map can also result in these features being represented in different ways (Fiori, 2005). For instance, some styles or themes may highlight some roads or completely ignore others. Finally, historic but inaccurate cartography or contemporary illustrated maps can suffer from distortion or unusual perspective (Cajthaml, 2011).</p><p>In this paper, we present a novel algorithm to automatically help start the georeferencing of historic and illustrated maps based on the text found in the map image. To accomplish this, we leverage the power of modern OCR (Optical Character Recognition) and geocoding services on the cloud. The proposed algorithm is able to calculate the area covered by the map, and where north is located in the image, with a precision greater than 80%. This information obtained represents a great help to inexpert users performing the alignment and georeference of maps for the first time. We also propose an optional machine learning module to speed up the process in dynamic environments in which the time required to obtain a result is an important factor. Figure 1 shows some examples of heterogeneous maps processed with the proposed algorithm.</p><p>The proposed algorithm contains five modules as shown in Figure 2. The first module applies an OCR process to extract the text contained within the input image. The results pass through a processing step to filter the text using heuristics to remove incorrect and ambiguous entries. The next module (optional) is a bidirectional LSTM (Long shortterm memory) recurrent neural network (Graves and Schmidhuber, 2005) that takes text and orders it according to likelihood of useful geocoding result return. The third module takes the text (ordered or not) and searches for each line in a geocoding service. The output is a list of locations, each one with its real world latitude and longitude and its coordinates within the image. The fourth module calculates a matrix of distances between locations. Each distance contains the real life geodesic distance (Karney, 2013) in meters, the Euclidean distance between each piece of text in pixels, the calculated meters per pixel (MPP), and the rotation. We define rotation as the difference in angle between real life location and the text in the image. Using the MPP and rotation as dimensions, the module finds clusters of corresponding locations. Lastly, the largest cluster is selected as the best. The fifth and final module uses the best cluster of locations and calculates the georeference information. This output information contains the northeast and southwest corners of the map, a list of mapping points, as well as the angle of north in the image (counter-clockwise, where 0 degrees is pointing up).</p><p>The proposed algorithm has approximately twelve hyper-parameters that can be tuned. We found that one of the most important is the minimum size of the cluster used to calculate the georeference information. In other words, the minimum number of corresponding locations the algorithm needs to converge.</p><p>In Table 1 we show the results of executing the algorithm against a set of 359 illustrated maps obtained from Stroly’s database (Vermeulen et al., 2011). The maps were manually georeferenced, and this information is used as ground truth. The georeference information returned by the algorithm is considered correct when two conditions are met. First, the width of the calculated area is between 50% and 200% of the width of the real area. Second, there is an intersection between both areas. Figure 3 shows the visualization of some results, executing the algorithm against several kinds of maps. The map area delimited in blue is the ground truth, while the one in orange is the one calculated by the presented algorithm. The markers in blue are the locations that are part of the cluster used to calculate the information.</p><p>In conclusion, we offer a novel solution to start and in some cases to complete the georeferencing process for heterogeneous historic and illustrated maps based on the text contained within them. The algorithm does not need vector information or geographical databases, nor image preprocessing. We have proven that even with a small cluster of locations the precision of this method is greater than 80%. The precision increases when the hyper-parameter is set to need larger clusters to converge (98.86% for a minimum of six locations). In future iterations we aim to improve the algorithm to increase the precision for smaller clusters and to improve the recall in general.</p>


2019 ◽  
Vol 945 ◽  
pp. 287-292 ◽  
Author(s):  
N.P. Lukutsova ◽  
I.A. Kulesh ◽  
S.N. Golovin ◽  
S.A. Andrushin

The stabilizer nature effect on the aggregative stability of the modifying concrete additives based on halloysite nanotubes in the aquatic environment is shown. The chemical composition and morphology of halloysite nanotubes and their additives, obtained by ultrasonic dispersion in the aquatic environment of the surfactant, are studied. The influence on the processes of charge stabilization on the outer and inner surface of halloysite nanotubes is determined. The dependence of nanotube sizes and specific surface area on the stabilizer type, the time of ultrasonic dispersion, and additive storage is revealed. The stabilization mechanisms of aqueous dispersions of modifying additives based on halloysite nanotubes with anion-and cation-active substances are considered. It is established that the polynaphthalenesulfonate-based modifier S-3 has got the maximum efficiency as a stabilizer of aqueous dispersions of modifying concrete additives with halloysite nanotubes.


Author(s):  
Silvana Espinosa G. ◽  
María Fernanda Delgado Hernández ◽  
Bernardo Orobio Riofrío ◽  
Luz Marina Mejía Ladino ◽  
Diego L. Gil Agudelo

The objective of this investigation was to evaluate the status of piangua (Anadara tuberculosa, Sowerby) populations in two areas of the province of Nariño (Pacific coast of Colombia), and to assess the effect on natural communities of conservation strategies such as closed periods, rotation on extracting areas, and enforcement of the 5 cm minimum size declared by INPA (resolution 539, 2000). Permanent plots were set up and all piangua were collected using the traditional manual techniques. Morphometric measurements of gathered organisms were recorded. Subsequent samplings were performed at different times depending on the conservation strategy evaluated. A total of 10441 individuals of A. tuberculosa were collected, 61 % corresponding to Bazán and 39 % to Nerete. All conservation strategies assessed showed positive effects on the conservation and sustainable use of the resource, being closed periods of two months the one with better results (p= 0.027 for Bazán and p= 8.57E-06 for Nerete; Tukey: p< 0.05); in Bazán, this strategy was the only one showing positive results, while in Nerete the three strategies showed to be effective.


2003 ◽  
Vol 2 (2) ◽  
pp. 43
Author(s):  
B. SETIAWATY

Representation which generates the observed process of a hidden Markov model is not unique. The simplest one, that is, the one with minimum size is called a true parameter. This article is aimed to present characteristics of this parameter.


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