scholarly journals The soft X-ray Neupert effect as a proxy for solar energetic particle injection

2020 ◽  
Vol 10 ◽  
pp. 64
Author(s):  
Ruhann Steyn ◽  
Du Toit Strauss ◽  
Frederic Effenberger ◽  
Daniel Pacheco
Keyword(s):  
Thermal Emission ◽  
Transport Model ◽  
Solar Energetic Particle ◽  
Particle Injection ◽  
New Approach ◽  
X Ray ◽  
Neupert Effect ◽  
Long Duration ◽  
Cast Model

The acceleration and injection of solar energetic particles (SEPs) near the Sun is one of the major unsolved problems in contemporary SEP transport modeling efforts. Here, we establish a new approach to the injection problem by utilizing a correlation between the soft X-ray thermal emission in solar flares, and their hard X-ray counterpart, the so-called Neupert effect, which is indicative of the presence of non-thermal particles. We show that the resulting injection function, in the initial phase of the flare, is similar to those inferred from inverting the transport problem based on in-situ observations. For few cases, we find early injections with no in-situ correspondence, that can be caused by particles accelerated before there is a magnetic connection between the source and the spacecraft. The method has limitations for long-duration injections, since it is not applicable to the decay phase of the flare where particle trapping might play a role. For a sample of SEP events in 1980, observed with the Helios-1 and IMP8 spacecraft, we show the results of a 2D SEP transport model based on this approach. We discuss that, with this method, a physics-based, real-time operational SEP now-cast model for the heliosphere is feasible.

In situ back-side illumination fluorescence XAFS (BI-FXAFS) studies on platinum nanoparticles deposited on a HOPG surface as a model fuel cell: a new approach to the Pt-HOPG electrode/electrolyte interface

2014 ◽  
Vol 16 (27) ◽  
pp. 13748-13754 ◽  
Author(s):  
Hiromitsu Uehara ◽  
Yohei Uemura ◽  
Takafumi Ogawa ◽  
Kentaro Kono ◽  
Ryoichi Ueno ◽  
...  
Keyword(s):  
Fine Structure ◽  
Fuel Cell ◽  
Back Side ◽  
New Approach ◽  
X Ray ◽  
Model Fuel ◽  
Fluorescence Xafs ◽  
X Ray Absorption ◽  
Side Illumination

We measured the in situ polarization-dependent X-ray absorption fine structure of PtNPs deposited on a flat HOPG substrate.

scholarly journals Early neutron star evolution in high-mass X-ray binaries

2020 ◽  
Vol 494 (1) ◽  
pp. 44-49 ◽  
Author(s):  
Wynn C G Ho ◽  
M J P Wijngaarden ◽  
Nils Andersson ◽  
Thomas M Tauris ◽  
F Haberl
Keyword(s):  
Magnetic Field ◽  
Neutron Star ◽  
Thermal Emission ◽  
Equilibrium Phase ◽  
High Mass ◽  
X Ray ◽  
Spin Period ◽  
Long Duration ◽  
X Ray Binaries ◽  
The Magnetic Field

ABSTRACT The application of standard accretion theory to observations of X-ray binaries provides valuable insights into neutron star (NS) properties, such as their spin period and magnetic field. However, most studies concentrate on relatively old systems, where the NS is in its late propeller, accretor, or nearly spin equilibrium phase. Here, we use an analytic model from standard accretion theory to illustrate the evolution of high-mass X-ray binaries (HMXBs) early in their life. We show that a young NS is unlikely to be an accretor because of the long duration of ejector and propeller phases. We apply the model to the recently discovered ∼4000 yr old HMXB XMMU J051342.6−672412 and find that the system’s NS, with a tentative spin period of 4.4 s, cannot be in the accretor phase and has a magnetic field B > a few × 1013 G, which is comparable to the magnetic field of many older HMXBs and is much higher than the spin equilibrium inferred value of a few × 1011 G. The observed X-ray luminosity could be the result of thermal emission from a young cooling magnetic NS or a small amount of accretion that can occur in the propeller phase.

scholarly journals Green Synthesis of Luminescent Gold-Zinc Oxide Nanocomposites: Cell Imaging and Visible Light–Induced Dye Degradation

2021 ◽  
Vol 9 ◽  
Author(s):  
Kanika Bharti ◽  
Shahbaz Ahmad Lone ◽  
Ankita Singh ◽  
Sandip Nathani ◽  
Partha Roy ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Visible Light ◽  
Green Synthesis ◽  
Photoelectron Spectroscopy ◽  
Sodium Citrate ◽  
Dye Degradation ◽  
X Ray ◽  
Long Duration ◽  
Solvent Free Conditions

Green synthesis of gold-zinc oxide (Au-ZnO) nanocomposite was successfully attempted under organic solvent–free conditions at room temperature. Prolonged stirring of the reaction mixture introduced crystallinity in the ZnO phase of Au-ZnO nanocomposites. Luminescence properties were observed in these crystalline Au-ZnO nanocomposites due to in situ embedding of gold nanoparticles (AuNP) of 5–6 nm diameter on the surface. This efficient strategy involved the reduction of Au(III) by Zn(0) powder in aqueous medium, where sodium citrate (NaCt) was the stabilizing agent. Reaction time and variation of reagent concentrations were investigated to control the Au:Zn ratio within the nanocomposites. The reaction with the least amount of NaCt for a long duration resulted in Au-ZnO/Zn(OH)2 nanocomposite. X-ray photoelectron spectroscopy (XPS) confirmed the formation of Zn(OH)2 and ZnO in the same nanocomposite. These nanocomposites were reconnoitered as bioimaging materials in human cells and applied for visible light–induced photodegradation of rhodamine-B dye.

scholarly journals Intracellular bound chlorophyll residues identify 1 Gyr-old fossils as eukaryotic algae

2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Marie Catherine Sforna ◽  
Corentin C. Loron ◽  
Catherine F. Demoulin ◽  
Camille François ◽  
Yohan Cornet ◽  
...  
Keyword(s):  
Metamorphic Rocks ◽  
Low Grade ◽  
Direct Identification ◽  
New Approach ◽  
X Ray ◽  
Eukaryotic Algae ◽  
Fundamental Step ◽  
In Situ Detection ◽  
Chlorophyll Derivatives

AbstractThe acquisition of photosynthesis is a fundamental step in the evolution of eukaryotes. However, few phototrophic organisms are unambiguously recognized in the Precambrian record. The in situ detection of metabolic byproducts in individual microfossils is the key for the direct identification of their metabolisms. Here, we report a new integrative methodology using synchrotron-based X-ray fluorescence and absorption. We evidence bound nickel-geoporphyrins moieties in low-grade metamorphic rocks, preserved in situ within cells of a ~1 Gyr-old multicellular eukaryote, Arctacellularia tetragonala. We identify these moieties as chlorophyll derivatives, indicating that A. tetragonala was a phototrophic eukaryote, one of the first unambiguous algae. This new approach, applicable to overmature rocks, creates a strong new proxy to understand the evolution of phototrophy and diversification of early ecosystems.

New approach in the monitoring and characterization of titanium nitride thin films

1999 ◽  
Vol 14 (2) ◽  
pp. 436-441 ◽  
Author(s):  
S. Logothetidis ◽  
E. I. Meletis ◽  
G. Kourouklis
Keyword(s):  
Thin Films ◽  
Photoelectron Spectroscopy ◽  
Electron Spectroscopy ◽  
Auger Electron ◽  
Ex Situ ◽  
New Approach ◽  
X Ray ◽  
Plasma Energy

In situ and ex situ spectroscopic ellipsometry (SE), Raman spectroscopy (RS), x-ray photoelectron spectroscopy (XPS), and Auger electron spectroscopy (AES) have been used to study the stoichiometry and characterize TiNx thin films deposited by magnetron sputtering at various stoichiometries. In situ SE can provide parameters, such as the plasma energy, that can be utilized for monitoring of the film stoichiometry. Besides plasma energy, optical phonon position in RS was also found to be a sensitive probe of TiNx stoichiometry as detected by RS, XPS, and ex situ SE. Under these conditions, AES faces difficulties for reliable film characterization, and the complementary use of other techniques is required for determining the exact film stoichiometry.

scholarly journals In situ high-energy X-ray diffraction of precipitation and dissolution reactions during heating of Al alloys

2021 ◽  
Author(s):  
Hannes Fröck ◽  
Christian Rowolt ◽  
Benjamin Milkereit ◽  
Michael Reich ◽  
Wolfgang Kowalski ◽  
...  
Keyword(s):  
High Energy ◽  
Al Alloys ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Zero Crossing ◽  
New Approach ◽  
X Ray ◽  
Common Technique ◽  
Equilibrium Phases

AbstractDuring heating of Al alloys, typically a sequence of precipitation and dissolution reactions occurs and the single (partly opposing) reactions superimpose. Differential scanning calorimetry (DSC) is one common technique to analyse the kinetic development of precipitation and dissolution in Al alloys, but the superposition of the exothermic precipitation and endothermic dissolution reactions complicates the DSC signal interpretation, as DSC measures the sum of any heat effect. Synchrotron high-energy X-ray diffraction (HEXRD) allows the kinetic development of phase transformations to be obtained and can support the separation of superimposed DSC signals. HEXRD results from this work offer a new approach to separate part of the superimposed reactions and their kinetic development for the equilibrium phases β-Mg2Si in EN AW-6082 and η-Mg(Zn,Cu,Al)2 in EN AW-7150. Comparing DSC and HEXRD results confirms serious overlap issues. Common DSC evaluation methods alone, using zero crossing between endothermic and exothermic heat flow or peak positions can be misleading regarding individual reaction start and finish temperatures as well as regarding reaction intensities, which can be unambiguously determined by in situ HEXRD.

scholarly journals New approach to evaluate satellite derived XCO<sub>2</sub> over oceans by integrating ship and aircraft observations

2020 ◽  
Author(s):  
Astrid Müller ◽  
Hiroshi Tanimoto ◽  
Takafumi Sugita ◽  
Toshinobu Machida ◽  
Shin-ichiro Nakaoka ◽  
...  
Keyword(s):  
Carbon Cycle ◽  
Atmospheric Chemistry ◽  
Transport Model ◽  
Satellite Observations ◽  
Reference Dataset ◽  
Model Calculations ◽  
New Approach ◽  
Mixing Ratios ◽  
In Situ Data

Abstract. Satellite observations provide spatially-resolved global estimates of column-averaged mixing ratios of CO2 (XCO2) over the Earth's surface. The accuracy of these datasets can be validated against reliable standards in some areas, but other areas remain inaccessible. To date, limited reference data over oceans hinders successful uncertainty quantification or bias correction efforts, and precludes reliable conclusions about changes in the carbon cycle in some regions. Here, we propose a new approach to analyze and evaluate seasonal, interannual and latitudinal variations of XCO2 over oceans by integrating cargo-ship (SOOP, Ship Of Opportunity) and commercial aircraft (CONTRAIL, Comprehensive Observation Network for Trace gases by Airliner) observations with the aid of state-of-the art atmospheric chemistry-transport model calculations. The consistency of the in situ based column-averaged CO2 dataset (in situ XCO2) with satellite estimates was analyzed over the Western Pacific between 2014 and 2017, and its utility as reference dataset evaluated. Our results demonstrate that the new dataset accurately captures seasonal and interannual variations of CO2. Retrievals of XCO2 over the ocean from GOSAT (Greenhouse gases observing satellite: NIES v02.75, National Institute for Environmental Studies; ACOS v7.3, Atmospheric CO2 Observation from Space) and OCO-2 (Orbiting Carbon Observatory, v9r) observations show a negative bias of about 1 parts per million (ppm) in northern midlatitudes, which was attributed to measurement uncertainties of the satellite observations. The NIES retrieval had higher consistency with in situ XCO2 at midlatitudes as compared to the other retrievals. At low latitudes, it shows many fewer valid data and high scatter, such that ACOS and OCO-2 appear to provide a better representation of the carbon cycle. At different times, the seasonal cycles of all three retrievals show positive phase shifts of one month relative to the in situ data. The study indicates that even if the retrievals complement each other, remaining uncertainties limit the accurate interpretation of spatiotemporal changes in CO2 fluxes. A continuous long-term XCO2 dataset with wide latitudinal coverage based on the new approach has a great potential as a robust reference dataset for XCO2 and can help to better understand changes in the carbon cycle in response to climate change using satellite observations.

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