Mechanical and thermal properties of polyolefin thermoplastic elastomer blends

2019 ◽  
Vol 48 (8) ◽  
pp. 338-346 ◽  
Author(s):  
Leslie A. Maynard ◽  
Barbara L. DeButts ◽  
Justin R. Barone
2014 ◽  
Vol 59 (1) ◽  
pp. 237-239
Author(s):  
A. Kozłowska ◽  
M. Piatek-Hnat

Abstract The results of studies of mechanical and thermal properties of synthesized elastomeric nanocomposites have been presented. An elastomeric multiblock terpoly(ester-b-ether-b-amide)s as polymeric matrix and nanoparticles SiO2 i TiO2 used as fillers. It was shown that the introduction of multiblock thermoplastic elastomer matrix of SiO2 and TiO2 nanoparticles allows to obtain nanocomposite materials with improved mechanical properties compared to the terpolymer before modification. An increase in glass transition temperature, which has a positive effect for the processing of terpolymers.


2020 ◽  
Vol 150 ◽  
pp. 02015
Author(s):  
Nacer Akkouri ◽  
Khadija Baba ◽  
Sana Simou ◽  
Latifa ELfarissi ◽  
Abderrahman Nounah

The use of different types of recycled plastic waste such as recycled polypropylene (PP), recycled low-density polyethylene (LDPE) and recycled polystyrene (PS), as raw materials for bitumen modification is known. However, the mechanical and thermal properties of recycled plastic waste modified bitumen (RPMB) are lower than those of the pure plastic modified bitumen. Therefor this paper aims to study the mechanical and thermal properties improvement of the RPMB with the use of a commercial elastomer styrene-butadiene-styrene (SBS). Initially conventional 35/50 quality bitumen was mixed with different percentages of LDPE, PS and PP, and then doped with commercial SBS. Basic rheological parameters such as penetration, softening point, elastic recovery and penetration index showed the changes caused by each rate of polymer addition to pure bitumen. The tests showed that the penetrability of the modified bitumen decreases and its softening point and elastic recovery increases, resulting in a decrease in the thermal sensitivity of the new bitumen mixture.


2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Manwar Hussain ◽  
Young Hui Ko ◽  
Yong Ho Choa

Thermoplastic elastomer composites and nanocomposites were fabricated via melt processing technique by blending thermoplastic elastomer (TPEE) with poly(butylene terephthalate) (PBT) thermoplastic and also by adding small amount of organo modified nanoclay and/or polytetrafluoroethylene (PTFE). We study the effect of polymer blending on the mechanical and thermal properties of TPEE blends with and without nanoparticle additions. Significant improvement was observed by blending only TPEE and virgin PBT polymers. With a small amount (0.5 wt.%) of nanoclay or PTFE particles added to the TPEE composite, there was further improvement in both the mechanical and thermal properties. To study mechanical properties, flexural strength (FS), flexural modulus (FM), tensile strength (TS), and tensile elongation (TE) were all investigated. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used to analyze the thermal properties, including the heat distortion temperature (HDT), of the composites. Scanning electron microscopy (SEM) was used to observe the polymer fracture surface morphology. The dispersion of the clay and PTFE nanoparticles was confirmed by transmission electron microscopy (TEM) analysis. This material is proposed for use as a baffle plate in the automotive industry, where both high HDT and high modulus are essential.


2021 ◽  
pp. 073168442110517
Author(s):  
Ali Fazli ◽  
Denis Rodrigue

In this work, recycled high density polyethylene (rHDPE) was compounded with regenerated tire rubber (RR) (35–80 wt.%) and reinforced with recycled tire textile fiber (RTF) (20 wt.%) as a first step. The materials were compounded by melt extrusion, injection molded, and characterized in terms of morphological, mechanical, physical, and thermal properties. Although, replacement of the rubber phase with RTF compensated for tensile/flexural moduli losses of rHDPE/RR/RTF blends because of the more rigid nature of fibers increasing the composites stiffness, the impact strength substantially decreased. So, a new approach is proposed for impact modification by adding a blend of maleic anhydride grafted polyethylene (MAPE)/RR (70/30) into a fiber-reinforced rubberized composite. As in this case, a more homogeneous distribution of the fillers was observed due to better compatibility between MAPE, rHDPE, and RR. The tensile properties were improved as the elongation at break increased up to 173% because of better interfacial adhesion. Impact modification of the resulting thermoplastic elastomer (TPE) composites based on rHDPE/(RR/MAPE)/RTF was successfully performed (improved toughness by 60%) via encapsulation of the rubber phase by MAPE forming a thick/soft interphase decreasing interfacial stress concentration slowing down fracture. Finally, the thermal stability of rubberized fiber-reinforced TPE also revealed the positive effect of MAPE addition on molecular entanglements and strong bonding yielding lower weight loss, while the microstructure and crystallinity degree did not significantly change up to 60 wt.% RR/MAPE (70/30).


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