scholarly journals Optimal Behavior of Spectral Line Analysis Through Fine Identification of Heavy Metal Lines in Crude Oil Using LIPS-Technique

2022 ◽  
Vol 961 (1) ◽  
pp. 012055
Author(s):  
Bilal Ahmed Hbeeb ◽  
Ahmed Ali Akbar ◽  
Abdul Khaliq Fawzi
Keyword(s):  
Heavy Metals ◽  
Crude Oil ◽  
Organic Liquid ◽  
Spectral Lines ◽  
Control Technique ◽  
Evaluation Procedure ◽  
Optimal Behavior ◽  
Fundamental Wavelength ◽  
Spot Number ◽  
Optical Insulator

Abstract Assessment of the quality of minerals, especially heavy ones, in crude oil by identifying spectral lines is very important to determine the quality and specifications of crude oil and the following treatments in production of the lines. In this study heavy metals lines (HMs) found in crude oil extracted from Iraq south field were identified that are unique spectral lines by using the laser-induced plasma spectroscopy (LIPS – mechanism), which were analyzed later by spectrometer based on the principle of finger print. The optimum spectrum (analytical lines) of metals emitted from the crude oil plasma in air were selected and determined. By determining the optimization behavior for evaluation procedure, the important condition was laser spot number (scan area). Comparison was performed between the fundamental wavelength and harmonic generation (HG) used in the laser beam to determine the optimum spectrum and optical insulator to cover the selected sample at atmospheric air pressure and room temperature. The results obtained from the actual raw spectrum were determined to represent the emission lines without the influence of foreign light (no noise) using the optical isolator, and unique new analytical lines were identified when increasing the number of lasers points up to 5 points, and a balanced spectrum was determined with good absorption when using a basic wavelength of 1064 nm. Difficulties were presented due to the characteristics of the crude oil as organic liquid case. The optimum results obtained indicated that the LIPS technique is effective and a control technique to well identify the spectrum lines of the heavy metals (HMs) presented in the crude oil.

scholarly journals Heavy Metal Tolerance Bacillus spp Isolated From Crude Oil Polluted Soil

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Muibat Fashola
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Crude Oil ◽  
Metal Tolerance ◽  
Heavy Metal Tolerance ◽  
Polluted Soil ◽  
Diffusion Method ◽  
Bacillus Species ◽  
Antibiotics Resistance ◽  
Bacillus Spp

Introduction: Indiscriminate dumping of spent oils enriched with heavy metals has led to increase in heavy metals load in the soil. Heavy metals exert toxic effects on biodegradation of organic pollutant in cocontaminated soil and there is need to find suitable strategies for their removal. Aim: The aim of this study was to assess the heavy metals resistance capability of indigenous Bacillus species in hydrocarbon polluted soil to nickel (Ni), Cadmium (Cd), Lead (Pb) and Chromium (Cr). Materials and Methods: Heavy metal tolerant bacteria were isolated from hydrocarbon polluted soil using Luria-Berthani agar supplemented with the respective metals and spread plate techniques. The isolates were putatively identified on the basis of their colonial morphology and biochemical characteristics and their antibiotics susceptibility pattern were evaluated using disc diffusion method. Results: The maximum tolerable concentration (MTC) of the four heavy metals to the selected isolates was 2 mM. Four bacteria isolates able to withstand the MTC were putatively identified as Bacillus subtilis, Bacillus megaterium, Bacillus laterosporus and Bacillus polymyxa. Out of the four Bacillus species, only B. laterosporus did not show multiple tolerance to the tested antibiotics which show that there is correlation between heavy metal tolerance and antibiotics resistance by the isolates. Conclusion: Multiple heavy metal tolerance Bacillus spp. were isolated from crude oil polluted soil. These bacteria could be suitable agents for bioaugmentation of hydrocarbon polluted soil co-contaminated with heavy metals.

Engineering Study of an Oil Gellation Technique to Control Spills from Distressed Tankers

1973 ◽  
Vol 1973 (1) ◽  
pp. 247-253
Author(s):  
Arnold M. Goldstein ◽  
Robert M. Koros ◽  
Barry L. Tarmy
Keyword(s):  
Crude Oil ◽  
Engineering Design ◽  
Environmental Protection Agency ◽  
Large Scale ◽  
Organic Liquid ◽  
Mixing Time ◽  
Gel Strength ◽  
Scale Model ◽  
Experimental Unit ◽  
Design Data

ABSTRACT Crude oil gellation is a potentially attractive technique for minimizing or preventing the loss of oil from a distressed tanker by converting the liquid oil into a rigid solid. The procedure involves the chemical reaction of two organic liquid gelling agents dissolved in the oil to form a gelant compound which entraps the oil. The resulting gel would float as a coherent mass if it were extruded from a ship or escape as a result of tanker break-up. This paper presents the results of a program undertaken to demonstrate in situ gellation on a large scale, and to gather engineering design information for this technique. The work was jointly funded in part by the U.S. Environmental Protection Agency. Engineering design data gathered during this study include the effect of mixing energy, mixing time, gellation time and temperature on gel strength. In addition, rheological properties of the gel were examined to relate gel strength to the maximum fluid static head that may be maintained without flow through a certain hull hole. Details of a gellation test with 500 bbl of South Louisiana crude oil will be discussed. The experimental unit was 7′ × 14′ × 30′ high and represented the region between two transverse frames in a wing compartment of a 21,000 dwt tanker. The design criteria for the mixing equipment required for gellation was validated by tracer mixing studies in both the 500 bbl tank and a one-seventh scale model of the larger unit. This work forms the basis for the further efforts on equipment development, selection and evaluation required before this technique can be used in the field.

scholarly journals Comparative Evaluation of Metals and Heavy Metals in Some Yemeni Crude and Fuel Oil

2020 ◽  
Vol 8 (6) ◽  
Author(s):  
Rokhsana M. Ismail ◽  
Fatima Sahleh Nagi
Keyword(s):  
Heavy Metals ◽  
Crude Oil ◽  
Modern Society ◽  
Oil Fields ◽  
Fuel Oil ◽  
Raw Material ◽  
Crude Oils ◽  
Two Samples ◽  
Fuel Oils ◽  
Oil Blend

Due to high importance of the crude oil to the modern society as a source of energy and as raw material for a wide chemical and petro chemical industries. In this study we made assessment of metals and heavy metals  in some Yemeni crude, and fuel oils namely Mareb crude oil blend, Masila crude oil blend plus two samples from Sounah and Hijah oil fields in Masila basin. Fifteen  metals and heavy metals were determined in above samples, but the most indicated were ( Na, K, Mg, ) and ( V, Co, Ni ) using ICP technique and atomic absorption spectroscopy . The order of concentration of metals in Yemeni crude oils were as shown in figures: Na < K < Co < Mg < V < Ni < Ca< Fe < Cd < Al< Zn < Cr < Cu < Pb < Mn. In Fuel oil: Na < Co < V < Mg < K < Ni < Ca < Fe < Al < Cd < Zn < Cr< Pb < Mn < Cu. Comparing concentrations of metals in studied sample, in general were less than in crude oil and fuel oil in many countries. That mean Yemeni crude and fuel oil are the best in quality. The order of concentration of metals in Yemeni crude oils were as shown in figures: Na < K < Co < Mg < V < Ni < Ca< Fe < Cd < Al< Zn < Cr < Cu < Pb < Mn. In Fuel oil: Na < Co < V < Mg < K < Ni < Ca < Fe < Al < Cd < Zn < Cr< Pb < Mn < Cu. Comparing concentrations of metals in studied sample, in general were less than in crude oil and fuel oil in many countries. That mean Yemeni crude and fuel oil are the best in quality.  

scholarly journals Microbiological Characteristics and Heavy Metal Pollution of Crude Oil Contaminated Water Bodies in Port Harcourt Metropolis, Nigeria

2021 ◽  
pp. 1-11
Author(s):  
Popoola, Taye Precious ◽  
David. N. Ogbonna ◽  
J. O. Williams
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Crude Oil ◽  
Water Samples ◽  
Metal Pollution ◽  
Heavy Metal Pollution ◽  
Heterotrophic Bacteria ◽  
Oil Pollution ◽  
Microbiological Analysis ◽  
Filter Feeder

Crude oil exploration has been beneficial to our economy but detrimental to our environment with the artisanal refineries further compounding the challenge. This research was aimed at investigating the microbiology and heavy metal pollution of three crude oil polluted rivers in Rivers State, Nigeria and effects on living organisms inhabiting that environment. This study was carried out in three locations in South-South Nigeria (Eagle Island, Iwofe and Chokocho rivers). A total of 64 water samples (upstream and downstream points) were collected using appropriate containers and sterile polyethene bags for 6 crab samples for a period of three months. Water and crab samples were analyzed for heavy metals using Atomic Absorption Spectrophotometric method while microbiological analysis involved isolation and enumeration of microbial populations of the water and crab samples as well as characterization and identification of the isolates using standard methods Results showed Total Heterotrophic bacteria (THB) ranged from 6.0 × 106 cfu/ml to 9.0 × 108cfu/ml for the downstream locations and 1.7 × 106cfu/ml to 3.5 × 107cfu/ml for the upstream locations. Total Heterotrophic Fungi (THF) ranged from 2.0 × 104cfu/ml to  1.1 × 105cfu/ml  for downstream locations and 0.1 × 104cfu/ml to  4.0 × 104cfu/ml  for upstream locations, Hydrocarbon Utilizing Bacteria (HUB) ranged from 0.8 × 103cfu/ml to  4.0 × 103cfu/ml in downstream locations and 2.0 × 103cfu/ml to  7.4 × 103cfu/ml in upstream locations, Hydrocarbon Utilizing Fungi (HUF) ranged from 1.0 × 103cfu/ml to  6.0 × 103cfu/ml for downstream locations and 5.0 × 102cfu/ml to  8.0 × 103cfu/ml for upstream locations.   The bacteria identified biochemically included Serratia sp., Enterobacter sp. and Salmonella sp. for the crab samples and Bacillus sp. was dominant in the water samples (Bacillus subtilis, Bacillus cereus, Bacillus carboniphilus). The heavy metals (Fe, Ni, Zn, Cd, Cu, Mn, Cr and Pb) were below the DPR permissible limit but are likely to increase since the activities leading to pollution are still ongoing. The crab as a filter feeder, had higher concentration of heavy metals and microbial population and the location with the highest crude oil pollution (14.5mg/l) had the lowest THB (6.0 × 106cfu/ml) as physicochemical parameters like the amount of Dissolved Oxygen had been altered.

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