Atomistic Origins of Friction
This chapter covers the current state of knowledge about how the shear strength (the force needed to slide one surface over another) originates at the atomic level. For adhesive friction, friction originates from the forces needed to move the atoms on one surface over the atomic structure of the opposing surface; the simplest model for adhesive friction is the cobblestone model. The Frenkel–Kontorova model, the Prandtl–Tomlinson model, and molecular dynamic simulations are typically used to show how the atomic structure of the surfaces leads to static friction. One exciting aspect of these friction models is the prediction of superlubricity or negligible friction for incommensurate sliding surfaces, which is now being realized in experiments. Also discussed is why superlubricity is not observed in real-life situations. As atoms and molecules slide over surfaces, kinetic friction originates from phonon and electronic excitations, which are typically studied using the quartz crystal microbalance (QCM).