scholarly journals rac-(2aS,2a1 R,3aR,3a1 S,5aS,6aR)-2a-Allyl-2,4-dichloro-2a,2a1,3a1,5a,6,6a-hexahydro-3aH-3-oxadicyclopenta[cd,gh]pentalen-3a-ol

IUCrData ◽  
2021 ◽  
Vol 6 (12) ◽  
Author(s):  
Sambasivarao Kotha ◽  
Saima Ansari ◽  
Naveen Kumar Gupta

The title racemic triquinane, C14H14Cl2O2, is composed of four five-membered rings, one of which is a tetrahydrofuran ring to which an allyl group on one side and a hydroxyl group on the other side are attached. The core of the triquinane unit has a cis–syn–cis configuration. In the crystal, the molecules are linked by pairwise O—H...O hydrogen bonds, generating inversion dimers featuring R 2 2(8) loops.

2014 ◽  
Vol 1030-1032 ◽  
pp. 121-124
Author(s):  
Song Li ◽  
Lei Fang

Molecular conformation and binding modeling were built by Hyperchem 8.0 computational chemistry package and the optimum molecular conformation was obtained by molecular mechanics optimizer. It was found that there were two types of binding sites for norfloxacin on the molecular imprinted particles (MIPs).One was the hydrogen bonds between oxygen atom of MIPs with the carbonyl group of norfloxacin and the other one was the hydrogen bonds between oxygen atom of MIPs with the hydroxyl group of norfloxacin. Moreover, the energies change of the molecules were1.69 x106 J/mol,1.80x106 J/mol and 5.37x106 J/mol and 2.54 x106 J/mol during the binding process of the norfloxacin (NOR), ciprofloxacin (CIP), bisphenol A (BPA) and tonalide (TON) onto the MIPs, respectively. The result indicated that the MIPs had a good selectivity for NOR and CIP than BPA and TON.


2003 ◽  
pp. 15-26
Author(s):  
P. Wynarczyk
Keyword(s):  
The Core ◽  

Two aspects of Schumpeter' legacy are analyzed in the article. On the one hand, he can be viewed as the custodian of the neoclassical harvest supplementing to its stock of inherited knowledge. On the other hand, the innovative character of his works is emphasized that allows to consider him a proponent of hetherodoxy. It is stressed that Schumpeter's revolutionary challenge can lead to radical changes in modern economics.


Derrida Today ◽  
2010 ◽  
Vol 3 (1) ◽  
pp. 21-36
Author(s):  
Grant Farred

‘The Final “Thank You”’ uses the work of Jacques Derrida and Friedrich Nietzsche to think the occasion of the 1995 rugby World Cup, hosted by the newly democratic South Africa. This paper deploys Nietzsche's Zarathustra to critique how a figure such as Nelson Mandela is understood as a ‘Superman’ or an ‘Overhuman’ in the moment of political transition. The philosophical focus of the paper, however, turns on the ‘thank yous’ exchanged by the white South African rugby captain, François Pienaar, and the black president at the event of the Springbok victory. It is the value, and the proximity and negation, of the ‘thank yous’ – the relation of one to the other – that constitutes the core of the article. 1


2019 ◽  
Vol 1 (1) ◽  
pp. 138
Author(s):  
Saif Nasrat Tawfiq Al - Haramazi

The theoretical curriculum in all disciplines is a basic requirement that nourishes the minds of the intellectual and cognitive recipients in the various scientific and cognitive stages. This is the framework that distinguishes the academic understanding of the anarchic, which is one of the most important and important keys in thinking and success in that jurisdiction or field, , Because it is unreasonable and logical to get into the core of any subject without searching and searching for its intellectual and historical bases to find out the reasons and reasons that surrounded this idea which was later recognized as an important contribution to the field of human sciences. Applied Sciences and other from the other side.


Imbizo ◽  
2017 ◽  
Vol 7 (1) ◽  
pp. 40-54
Author(s):  
Oyeh O. Otu

This article examines how female conditioning and sexual repression affect the woman’s sense of self, womanhood, identity and her place in society. It argues that the woman’s body is at the core of the many sites of gender struggles/ politics. Accordingly, the woman’s body must be decolonised for her to attain true emancipation. On the one hand, this study identifies the grave consequences of sexual repression, how it robs women of their freedom to choose whom to love or marry, the freedom to seek legal redress against sexual abuse and terror, and how it hinders their quest for self-determination. On the other hand, it underscores the need to give women sexual freedom that must be respected and enforced by law for the overall good of society.


Author(s):  
Rakshith . ◽  
Shivakumar . ◽  
Sreeharsha . ◽  
Divyasree .

The core principles in Ayurveda give prime importance to Agni, Prakriti, Ahara (food) and Vihara (lifestyle) in maintaining health. Present era people are scheduled to one or the other works due to which they are following unrightful food and habits which lead the manifestation of one of the common disorder which troubles person a lot - Amlapitta. By excess “Hurry, Worry and Curry” GIT disorders are the most common, not only affecting physical health but also psychological and social health. Amlapitta is one of that and it is a burning problem of the whole World. Amalpitta is composed of word Amla and Pitta. Amlapitta is a very common disease caused by Vidagdha Pitta with features like Amlodgara, Tiktodgara, Hrit, Kantha Daha etc. Pathya recommended in Amlapitta are Yava, Godhuma, Purana Shali, Mudga Yusha, Lajasaktu etc. Apathya recommended in Amlapitta are Navanna, Avidugdha, Masha, Kulattha, Dadhi and etc. So this present review article throws light on Pathya (conducive) and Apathya (non conducive) in Amlapitta.


2021 ◽  
Vol 13 (15) ◽  
pp. 8333
Author(s):  
Mirella Soyer ◽  
Koen Dittrich

In this study we investigate how consumers in The Netherlands can be persuaded to adopt sustainable practices when purchasing, using and disposing of clothes. This study investigates the attitude-behavior gap for the sustainable choices for purchase, use and disposing of clothes. For each consumption phase we ran a two-step multiple regression. The findings showed that the importance of the factors vary in the three consumption phases. For purchasing and disposal decisions, the core motivator social motivation predicts sustainable practices best, while it has no role in the usage phase. The factor ability appeared to have a significant role in the disposal phase, but not in the other phases. Finally, the trigger appears to lower the consumers’ ability in the purchasing phase, while it enhances the core motivator social evaluation in the disposal phase.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Umar Farooque ◽  
Rakesh Ranjan

AbstractIn order to select the heterogeneous multicore fiber (MCF) configuration with ultra-low crosstalk and low peak bending radius, comparative crosstalk analysis have been done for the three possible core configurations, namely, Configuration 1 - different refractive index (R.I.) and different radius, Configuration 2 - different R.I., and Configuration 3 - different radius. Using the coupled mode equation and the simplified expressions of mode coupling coefficient (MCC) for different configurations of heterogeneous cores, the crosstalk performance of all the heterogeneous MCF configurations along with the homogeneous MCF have been investigated analytically with respect to core pitch (D) and fiber bending radius (${R}_{b}$). Further, these expressions of MCC have been extended to obtain the simplified expressions of MCC for the estimation of crosstalk levels in respective trench-assisted (TA) heterogeneous MCF configurations. It is observed from the analysis that in Configuration 1, crosstalk level is lowest and the rate of decrease in the crosstalk with respect to the core pitch is highest compared to the other configurations of heterogeneous MCF. The values of crosstalk obtained analytically have been validated by comparing it with the values obtained from finite element method (FEM) based numerical simulation results. Further, we have investigated the impact of a fixed percent change (5%) in the core parameters (radius and/or R.I.) of one of the core of a homogeneous MCF, to realize the different heterogeneous MCF configurations, on the variations in crosstalk levels, difference in the mode effective refractive index of the core 1 and core 2 ($\Delta {n}_{eff}={n}_{eff1}-{n}_{eff2}$), and the peak bending radius (${R}_{pk}$). For the same percent variations (5%) in the core parameters (radius and/or R.I.) of different configurations of cores (Config. 1-Config. 3), Config. 1 MCF has highest variation in $\Delta {n}_{eff}$ value compared to other configurations of MCF. Further, this highest variation in $\Delta {n}_{eff}$ value of Config. 1 MCF results in smallest peak bending radius. The smaller value of peak bending radius allows MCF to bend into smaller radius. Therefore, Configuration 1 is the potential choice for the design of MCF with smaller peak bending radius and ultra-low crosstalk level compared to the other configurations of SI-heterogeneous MCF.


Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 552
Author(s):  
Dominika Kozicka ◽  
Paulina Zieleźny ◽  
Karol Erfurt ◽  
Jakub Adamek

Herein we describe the development and optimization of a two-step procedure for the synthesis of N-protected 1-aminomethylphosphonium salts from imides, amides, carbamates, or lactams. Our “step-by-step” methodology involves the transformation of amide-type substrates to the corresponding hydroxymethyl derivatives, followed by the substitution of the hydroxyl group with a phosphonium moiety. The first step of the described synthesis was conducted based on well-known protocols for hydroxymethylation with formaldehyde or paraformaldehyde. In turn, the second (substitution) stage required optimization studies. In general, reactions of amide, carbamate, and lactam derivatives occurred at a temperature of 70 °C in a relatively short time (1 h). On the other hand, N-hydroxymethylimides reacted with triarylphosphonium salts at a much higher temperature (135 °C) and over longer reaction times (as much as 30 h). However, the proposed strategy is very efficient, especially when NaBr is used as a catalyst. Moreover, a simple work-up procedure involving only crystallization afforded good to excellent yields (up to 99%).


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Riikka Nissi ◽  
Melisa Stevanovic

Abstract The article examines how the aspects of the social world are enacted in a theater play. The data come from a videotaped performance of a professional theater, portraying a story about a workplace organization going through a personnel training program. The aim of the study is to show how the core theme of the play – the teaming up of the personnel – is constructed in the live performance through a range of interactional means. By focusing on four core episodes of the play, the study on the one hand points out to the multiple changes taking place both within and between the different episodes of the play. On the other hand, the episodes of collective action involving the semiotic resources of singing and dancing are shown to represent the ideals of teamwork in distinct ways. The study contributes to the understanding of socially and politically oriented theater as a distinct, pre-rehearsed social setting and the means and practices that it deploys when enacting the aspects of the contemporary societal issues.


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