New techniques for the characterization of defect levels in semi-insulating materials

Author(s):  
C. Longeaud ◽  
J.P. Kleider ◽  
P. Kaminski ◽  
R. Kozlowski ◽  
M. Pawlowski ◽  
...  
Author(s):  
M.A. Parker ◽  
K.E. Johnson ◽  
C. Hwang ◽  
A. Bermea

We have reported the dependence of the magnetic and recording properties of CoPtCr recording media on the thickness of the Cr underlayer. It was inferred from XRD data that grain-to-grain epitaxy of the Cr with the CoPtCr was responsible for the interaction observed between these layers. However, no cross-sectional TEM (XTEM) work was performed to confirm this inference. In this paper, we report the application of new techniques for preparing XTEM specimens from actual magnetic recording disks, and for layer-by-layer micro-diffraction with an electron probe elongated parallel to the surface of the deposited structure which elucidate the effect of the crystallographic structure of the Cr on that of the CoPtCr.XTEM specimens were prepared from magnetic recording disks by modifying a technique used to prepare semiconductor specimens. After 3mm disks were prepared per the standard XTEM procedure, these disks were then lapped using a tripod polishing device. A grid with a single 1mmx2mm hole was then glued with M-bond 610 to the polished side of the disk.


Author(s):  
Dirk Doyle ◽  
Lawrence Benedict ◽  
Fritz Christian Awitan

Abstract Novel techniques to expose substrate-level defects are presented in this paper. New techniques such as inter-layer dielectric (ILD) thinning, high keV imaging, and XeF2 poly etch overflow are introduced. We describe these techniques as applied to two different defects types at FEOL. In the first case, by using ILD thinning and high keV imaging, coupled with focused ion beam (FIB) cross section and scanning transmission electron microscopy (STEM,) we were able to judge where to sample for TEM from a top down perspective while simultaneously providing the top down images giving both perspectives on the same sample. In the second case we show retention of the poly Si short after removal of CoSi2 formation on poly. Removal of the CoSi2 exposes the poly Si such that we can utilize XeF2 to remove poly without damaging gate oxide to reveal pinhole defects in the gate oxide. Overall, using these techniques have led to 1) increased chances of successfully finding the defects, 2) better characterization of the defects by having a planar view perspective and 3) reduced time in localizing defects compared to performing cross section alone.


2012 ◽  
Vol 65 (8) ◽  
pp. 1435-1440 ◽  
Author(s):  
Thiago L. Marques ◽  
Vanessa N. Alves ◽  
Luciana M. Coelho ◽  
Nívia M. M. Coelho

Metal contaminants are generally removed from effluents by chemical and physical processes which are often associated with disadvantages such as the use of toxic reagents, generation of toxic waste and high costs. Hence, new techniques have been developed, among them the study of natural adsorbents, for instance, the use of Moringa oleifera seeds. The potential of M. oleifera seeds for nickel removal in aqueous systems was investigated. The seeds utilized were obtained from plants grown in Uberlândia/Brazil. After being dried and pulverized, the seeds were treated with 0.1 mol/L NaOH. Fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analyses were used for the characterization of the material. Using the optimized methodology (50 mL of 4.0 mg/L Ni(II), pH range of 4.0–6.0, agitation time of 5 min and adsorption mass of 2.0 g) more than 90% of Ni(II) could be removed from water samples. The sorption data were fitted satisfactorily by the Langmuir adsorption model. Evaluation applying the Langmuir equation gave the monolayer sorption capacity as 29.6 mg/g. The results indicate that this material could be employed in the extraction of nickel, considering its ease of use, low cost and environmental viability, which make it highly attractive for application in developing countries.


Author(s):  
Shin'ichi Yamamura ◽  
Tadamasa Kimura ◽  
Shigemi Yugo ◽  
Riichiro Saito ◽  
Michio Murata ◽  
...  

Author(s):  
Bernadette Bensaude Vincent ◽  
Antonio García Belmar

The most striking feature of the diffusion of Mendeleev’s system in France is that his great achievement prompted no real debates, no controversy among French academic chemists. It is not that his work was totally ignored. Rather, it was integrated as a non-event in the daily work focused on the discovery and characterization of chemical elements thanks to new techniques (spectroscopy, crystallization, and so on). In science journals Mendeleev’s system attracted attention only insofar as it could lead to the discovery of new chemical elements. After briefly mentioning when and how Mendeleev’s ideas were presented in French primary, secondary, and higher education chemistry textbooks and mentioned in official programs, we will try to understand the reasons for preferring alternative criteria for classification in chemistry textbooks. In addition to the explicit arguments advanced by those who mentioned Mendeleev’s proposals, we will attempt to interpret the silence that most textbook authors kept. In a third section, we will symmetrically focus on the small group of chemists who promoted Mendeleev’s periodic classification and try to disentangle their motivations and modes of appropriation. We will then conclude that, far from being a form of resistance to Mendeleev’s specific system, the overall skepticism expressed in French chemistry textbooks was the expression of an enduring statu quo resulting from a long debate over the best chemical classification in educational milieus. In September 1879 the Department of Haute-Marne organized at the Hôtel de la Préfecture de Chaumont an exposition scolaire aimed at exhibiting the innovative activities developed by teachers and students of local primary school institutions. It was intended to contribute to the reform of primary education following the trauma caused by the defeat in the war against Prussia. As one of its organizers claimed, “it is primary instruction, and its patriotic direction, which made the strength of our enemies. It should make ours.” It was in this context of educational reform and post-war tensions that we found the first reference to didactic use of Mendeleev’s periodic system in France.


1972 ◽  
Vol 18 (6) ◽  
pp. 534-538
Author(s):  
Mario Werner ◽  
Albert L Jones

Abstract To improve the characterization of electrophoretic lipoprotein subfractions, we developed two new techniques for analyzing lipoproteins after electrophoresis on thin agarose layers. Overlay with antisera exactly localizes specific apoproteins without any distortion caused by antigen diffusion; electron microscopy of eluted fractions determines the varying particle-size distribution. Applied together, these methods can detect individual differences between hyperlipemic samples that are not immediately apparent in the electrophoretic pattern, and should provide valuable new insight into the classification of hyperlipoproteinemias.


2018 ◽  
Vol 9 (2) ◽  
pp. 163-168 ◽  
Author(s):  
Á. Lakatos ◽  
I. Deák ◽  
U. Berardi

The development of high performance insulating materials incorporating nanotechnologies has enabled considerable decrease in the effective thermal conductivity. Besides the use of conventional insulating materials, such as mineral fibers, the adoption of new nano-technological materials such as aerogel, vacuum insulation panels, graphite expanded polystyrene, is growing. In order to reduce the thermal conductivity of polystyrene insulation materials, during the manufacturing, nano/micro-sized graphite particles are added to the melt of the polystyrene grains. The mixing of graphite flakes into the polystyrene mould further reduces the lambda value, since graphite parts significantly reflect the radiant part of the thermal energy. In this study, laboratory tests carried out on graphite insulation materials are presented. Firstly, thermal conductivity results are described, and then sorption kinetic curves at high moisture content levels are shown. The moisture up-taking behaviour of the materials was investigated with a climatic chamber where the relative humidity was 90% at 293 K temperature. Finally, calorific values of the samples are presented after combusting in a bomb calorimeter.


1978 ◽  
Vol 79 (1) ◽  
pp. 217-234 ◽  
Author(s):  
P J Oates ◽  
O Touster

To investigate the properties of phagolysosome (PL) fusion in Acanthamoeba homogenates, it was necessary to develop reliable methods for measuring in vitro PL fusion. The need to distinguish PL fusion from PL adhesion was met by the development of a quantitative electron microscope assay. Initial characterization of the fusion reaction by this method was followed by the development of a more rapid light microscope assay. Results obtained by the two methods were found to be in close agreement. By use of these new techniques, the in vitro PL fusion reaction was demonstrated to occur in a quantitatively reproducible manner. Under the present conditions employed, PL breakdown was not detected at any time during the in vitro incubation, while PL fusion was observed to proceed linearly for approximately 10 min, at which time the reaction ceased. Incubation of mixtures of two distinct PL types resulted in increases in hybrid PL types that were paralleled by decreases in nonhybrid PL types. The relative changes in PL concentrations observed were quantitatively consistent with PL fusion occurring randomly with respect to PL type. PL fusion was strongly inhibited by low concentrations of KF (50% inhibition at 2.7 mM), and by approximately tenfold higher concentrations of KCl, while KCN and 2,4-dinitrophenol (2,4-DNP) had little effect. In addition to further defining the nature of the PL fusion reaction in this system, these results demonstrate that, by use of the techniques described, quantitative study of the biochemical properties of this reaction is now possible.


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