Understanding the Crystalline Region Damage Mechanism of XLPE in Water Tree Propagation by Erosion Method

2021 ◽  
Vol 28 (6) ◽  
pp. 2074-2082
Author(s):  
Kangle Li ◽  
Kai Zhou ◽  
Hongliang Zhang ◽  
Hai Jin ◽  
Xiaonan Li
Author(s):  
P.E. Champness ◽  
R.W. Devenish

It has long been recognised that silicates can suffer extensive beam damage in electron-beam instruments. The predominant damage mechanism is radiolysis. For instance, damage in quartz, SiO2, results in loss of structural order without mass loss whereas feldspars (framework silicates containing Ca, Na, K) suffer loss of structural order with accompanying mass loss. In the latter case, the alkali ions, particularly Na, are found to migrate away from the area of the beam. The aim of the present study was to investigate the loss of various elements from the common silicate structures during electron irradiation at 100 kV over a range of current densities of 104 - 109 A m−2. (The current density is defined in terms of 50% of total current in the FWHM probe). The silicates so far ivestigated are:- olivine [(Mg, Fe)SiO4], a structure that has isolated Si-O tetrahedra, garnet [(Mg, Ca, Fe)3Al2Si3AO12 another silicate with isolated tetrahedra, pyroxene [-Ca(Mg, Fe)Si2O6 a single-chain silicate; mica [margarite, -Ca2Al4Si4Al4O2O(OH)4], a sheet silicate, and plagioclase feldspar [-NaCaAl3Si5O16]. Ion- thinned samples of each mineral were examined in a VG Microscopes UHV HB501 field- emission STEM. The beam current used was typically - 0.5 nA and the current density was varied by defocussing the electron probe. Energy-dispersive X-ray spectra were collected every 10 seconds for a total of 200 seconds using a Link Systems windowless detector. The thickness of the samples in the area of analysis was normally 50-150 nm.


2015 ◽  
Vol 135 (7) ◽  
pp. 424-430 ◽  
Author(s):  
MyongHwan Kim ◽  
Yoshinobu Murakami ◽  
Masayuki Nagao ◽  
Naohiro Hozumi ◽  
Takashi Kurihara ◽  
...  
Keyword(s):  

2016 ◽  
Vol 136 (3) ◽  
pp. 333-343
Author(s):  
Takashi Kurihara ◽  
Eiji Tsutsui ◽  
Eiji Nakanishi ◽  
Kiyoshi Maki ◽  
Kenichi Murakawa ◽  
...  
Keyword(s):  

2014 ◽  
Vol 501-504 ◽  
pp. 1096-1103
Author(s):  
Hong Xiao Wu ◽  
Hao Zhe Xing ◽  
Zhi Fang Yan

The blast impact dynamic experiment of reinforced concrete rectangular plate with simply supported boundary conditions was performed using explosion pressure simulator. With 3-D FEM software LS-DYNA, the separate solid models of concrete and steel were established and 3-D FEM dynamic analysis of the experiment process was carried out. Compared calculation results to experiment results synthetically, the damage mechanism and failure characteristics of reinforced concrete plate under explosion impact loading condition were got and it is also verified that the H-J-C model can approximately simulate the concrete properties well under explosion impact loading condition.


Author(s):  
Yian Wang ◽  
Guoshan Xie ◽  
Zheng Zhang ◽  
Xiaolong Qian ◽  
Yufeng Zhou ◽  
...  

Temper embrittlement is a common damage mechanism of pressure vessels in the chemical and petrochemical industry serviced in high temperature, which results in the reduction of roughness due to metallurgical change in some low alloy steels. Pressure vessels that are temper embrittled may be susceptible to brittle fracture under certain operating conditions which cause high stress by thermal gradients, e.g., during start-up and shutdown. 2.25Cr1-Mo steel is widely used to make hydrogenation reactor due to its superior combination of high mechanical strength, good weldability, excellent high temperature hydrogen attack (HTHA) and oxidation-resistance. However, 2.25Cr-1Mo steel is particularly susceptible to temper embrittlement. In this paper, the effect of carbide on temper embrittlement of 2.25Cr-1Mo steel was investigated. Mechanical properties and the ductile-brittle transition temperature (DBTT) of 2.25Cr-1Mo steel were measured by tensile test and impact test. The tests were performed at two positions (base metal and weld metal) and three states (original, step cooling treated and in-service for a hundred thousand hours). The content and distribution of carbides were analyzed by scanning electron microscope (SEM). The content of Cr and Mo elements in carbide was measured by energy dispersive X-ray analysis (EDS). The results showed that the embrittlement could increase the strength and reduce the plasticity. Higher carbide contents appear to be responsible for the higher DBTT. The in-service 2.25Cr-1Mo steel showed the highest DBTT and carbide content, followed by step cooling treated 2.25Cr-1Mo steel, while the as-received 2.25Cr-1Mo steel has the minimum DBTT and carbide content. At the same time, the Cr and Mo contents in carbide increased with the increasing of DBTT. It is well known that the specimen analyzed by SEM is very small in size, sampling SEM specimen is convenient and nondestructive to pressure vessel. Therefore, the relationship between DBTT and the content of carbide offers a feasible nondestructive method for quantitative measuring the temper embrittlement of 2.25Cr-1Mo steel pressure vessel.


2021 ◽  
Vol 259 ◽  
pp. 113463
Author(s):  
Binbin Liao ◽  
Zhongwei Zhang ◽  
Liping Sun ◽  
Jianwu Zhou ◽  
Panding Wang ◽  
...  

Vacuum ◽  
2021 ◽  
pp. 110350
Author(s):  
Hulin Wu ◽  
Ping Gong ◽  
Suying Hu ◽  
Lin Xiang ◽  
Enlei Wang ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1398
Author(s):  
Yong-Qi Zhang ◽  
Xuan Wang ◽  
Ping-Lan Yu ◽  
Wei-Feng Sun

Trimethylolpropane triacrylate (TMPTA) as a photoactive crosslinker is grafted onto hydrophobic nanosilica surface through click chemical reactions of mercapto double bonds to prepare the functionalized nanoparticles (TMPTA-s-SiO2), which are used to develop TMPTA-s-SiO2/XLPE nanocomposites with improvements in mechanical strength and electrical resistance. The expedited aging experiments of water-tree growth are performed with a water-knife electrode and analyzed in consistence with the mechanical performances evaluated by means of dynamic thermo-mechanical analysis (DMA) and tensile stress–strain characteristics. Due to the dense cross-linking network of polyethylene molecular chains formed on the TMPTA-modified surfaces of SiO2 nanofillers, TMPTA-s-SiO2 nanofillers are chemically introduced into XLPE matrix to acquire higher crosslinking degree and connection strength in the amorphous regions between polyethylene lamellae, accounting for the higher water-tree resistance and ameliorated mechanical performances, compared with pure XLPE and neat-SiO2/XLPE nanocomposite. Hydrophilic TMPTA molecules grafted on the nano-SiO2 surface can inhibit the condensation of water molecules into water micro-beads at insulation defects, thus attenuating the damage of water micro-beads to polyethylene configurations under alternating electric fields and thus restricting water-tree growth in amorphous regions. The intensified interfaces between TMPTA-s-SiO2 nanofillers and XLPE matrix limit the segment motions of polyethylene molecular chains and resist the diffusion of water molecules in XLPE amorphous regions, which further contributes to the excellent water-tree resistance of TMPTA-s-SiO2/XLPE nanocomposites.


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