scholarly journals Geoquímica do gabro coronítico de Amparo, RJ

2002 ◽  
Vol 25 ◽  
pp. 44-67
Author(s):  
Isabel Pereira Ludka ◽  
Cristina Maria Wiedemann

The aim of this paper is to present geochemical data and some petrological aspects of the Amparo gabbroic (hyperite) body, located approximately 30 km east of the town, Nova Friburgo, Rio de Janeiro State. Ten samples of these basic rocks were analysed for major, minor and trace elements, and three of these for REE. The data obtained reflect the limited mineralogical range. The contents of the major elements indicate a sub-alkalic tholeiitic magma, as shown by modal analysis, which classified these rocks as an olivine gabbro. Geochemical analysis of the minor, trace and rare-earth elements shows abnormal incompatible enrichment, such as the high LREE, Ba and Sr contents. Similar results for other basic and ultrabasic intrusions are common in this portion of the Ribeira Mobile Belt.

2001 ◽  
Vol 73 (1) ◽  
pp. 99-119 ◽  
Author(s):  
SILVIA R. MEDEIROS ◽  
CRISTINA M. WIEDEMANN-LEONARDOS ◽  
SIMON VRIEND

At the end of the geotectonic cycle that shaped the northern segment of the Ribeira Mobile Belt (Upper Proterozoic to Paleozoic age), a late to post-collisional set of plutonic complexes, consisting of a wide range of lithotypes, intruded all metamorphic units. The Várzea Alegre Intrusive Complex is a post-collisional complex. The younger intrusion consists of an inversely zoned multistage structure envolved by a large early emplaced ring of megaporphyritic charnoenderbitic rocks. The combination of field, petrographic and geochemical data reveals the presence of at least two different series of igneous rocks. The first originated from the partial melting of the mantle. This was previously enriched in incompatible elements, low and intermediate REE and some HFS-elements. A second enrichment in LREE and incompatible elements in this series was due to the mingling with a crustal granitic magma. This mingling process changed the composition of the original tholeiitic magma towards a medium-K calc-alkalic magma to produce a suite of basic to intermediate rock types. The granitic magma from the second high-K, calc-alkalic suite originated from the partial melting of the continental crust, but with strong influence of mantle-derived melts.


Author(s):  
J. K. Nanda ◽  
U. C. Pati

While congratulating the authors for the wealth of geochemical data on a very important Precambrian lithological assemblage of India, known commonly as khondalites, which constitute a major part of the Eastern Ghats mobile belt bordering the eastern fringes of the Indian Peninsula, we have a few comments to offer on the hypothesis propounded by the authors (Dash et al. 1987).


1984 ◽  
Vol 48 (348) ◽  
pp. 351-363 ◽  
Author(s):  
I. G. Meighan ◽  
D. Gibson ◽  
D. N. Hood

Abstract Geochemical data (including REE determinations) are presented for all five Mourne Mountains granites and three Northern Ireland rhyolites. These confirm (1) the extremely fractionated nature of some of the rocks (Sr and Ba < 10 ppm, Rb > 400 ppm, Eu/Eu* < 0.1, and K/Rb < 100), and (2) a major revision to the outcrops of the E. Mourne granites G1 and G2 in which much of the former is reclassified as G2. Combined petrographic and geochemical studies have also indicated that magmatic pulses were involved in the emplacement of Mourne intrusions G2 (Revised)-G5 inclusive. The N. Ireland Tertiary acid rocks exhibit general geochemical similarities to their analogues elsewhere in the British Tertiary Igneous Province (in which Sr is generally < 100 ppm and CeN/YbN generally < 8 with Eu/Eu* often < 0.6), but as a suite the Mourne granites are enriched in Rb and some other LIL elements relative to their N. Arran counterparts. The more fractionated acid magmas of NE Ireland are believed to have evolved from primitive granitic parent liquids by crystal fractionation at depth which involved major and accessory phases (including zircon and allanite). In the Mourne (and County Antrim) areas the primitive acid compositions lie at the ends of basaltic (tholeiitic) differentiation series, and in the Mourne central complex there is a complete geochemical sequence from basic rocks through intermediate members to primitive and ultimately highly evolved, subalkaline, granitic intrusions. It is concluded that the data are consistent with the Mourne granites and Northern Ireland rhyolites being essentially basaltic differentiates, although Sr isotope evidence indicates some (probably minor) crustal involvement.


1977 ◽  
Vol 14 (3) ◽  
pp. 444-455 ◽  
Author(s):  
Eric C. Syme ◽  
Richard W. Forester

The Aphebian Boundary intrusions are a group of lensoid, ultramafic to felsic rocks which occur in a N–NW trending zone 10 km long by 4 km wide centred on the town of Flin Flon. The intrusions were emplaced into Amisk metavolcanic rocks and Missi metasedimentary rocks. Field relationships, petrography, and chemical characteristics of the Boundary intrusions indicate that they are composed of three compositionally distinct, sequentially emplaced groups. From oldest to youngest, these are (1) a mafic augite- and biotite-bearing mela-dioritic group, (2) a felsic group ranging from leucodiorite to granodiorite, and (3) an olivine-bearing (wehrlite to olivine gabbro) group. The mafic group crystallized at relatively high [Formula: see text] and [Formula: see text], such that successive differentiates have increasing MgO/FeO ratios. Molar ratio diagrams clearly indicate that fractionation of augite, minor magnetite, and possibly subordinate olivine can account for the observed chemical variation of approximately 80% of this group, whereas the olivine-bearing group could only have formed by crystal fractionation of subequal amounts of olivine and clinopyroxene, and minor magnetite. The felsic group is chemically similar to the post-Missi granodioritic plutons and cannot represent SiO2-rich residual liquids produced solely by fractionation of augite and olivine from a basaltic magma.


1984 ◽  
Vol 43 ◽  
Author(s):  
D. J. Hassett ◽  
G. J. McCarthy ◽  
K. R. Henke ◽  
E. D. Korynta

AbstractLignite gasification ash from the Morgantown Energy Technology Center (METC) gasifier was subiected to two short-term leaching treatments. The cnncentrations of regulated elements in the EPA EP procedure leachate from the bulk METC ash did not exceed the “EP Trigger Limits.” A modification of this procedure that uses a basic synthetic groundwater instead of the acid EP extractant was also performed on the bulk ash and its eleven size fractions. Water equilibria modeling was used to explain the concentrations of major elements in solution. Corcentrations of minor and trace elements in solution after leaching with synthetic groundwater were also below “EP Trigger Limits.”


1994 ◽  
Vol 58 (392) ◽  
pp. 375-386 ◽  
Author(s):  
A. Mogessie ◽  
D. Rammlmair

AbstractBased on petrographic, mineralogical and geochemical data, two groups of rodingites have been documented from the polymetamorphic Vumba Schist Belt of Botswana. Group I rodingites contain relict chromite grains with zoned uvarovite-grossular + clinopyroxene + epidote/zoisite ± quartz, whereas group II rodingites contain no chromite and uvarovite. Although the presence of chromite with Cr/(Cr + Al + Fe3+) ratio > 90, similar to chromites found in komatiites, suggests a possible komatiitic origin of group I rodingites, the major and trace element chemical data of most analysed basic rocks from this belt indicate that the protoliths of both groups of rodingites are related to basalt/gabbro of komatiitic affinity. The rodingites formed during the M3 phase of metamorphism.


2001 ◽  
Vol 138 (2) ◽  
pp. 101-115 ◽  
Author(s):  
YONGFENG ZHU ◽  
SHIHUA SUN ◽  
LIBING GU ◽  
YOSHIHIDE OGASAWARA ◽  
NENG JIANG ◽  
...  

Lower Permian volcanism was the first magmatic activity to occur after the collision events in the Mongolian orogenic zone, east China. The Permian volcanic rocks are therefore a key to understanding the dynamics of the unified continental lithosphere. The volcanic rocks consist of basic and intermediate rocks. The intermediate rocks with high initial 87Sr/86Sr ratios (0.7051 to 0.7052) and low εNd values (−0.73 to −3.57) generally overlie the basic rocks in the field. The basic rocks have relatively low initial 87Sr/86Sr ratios (0.7034 to 0.7051) and high εNd values (2.72 to −0.10). Two parallel Rb–Sr isochrons give almost the same age, about 270 Ma. One consists of the basic rocks giving an initial isochron 87Sr/86Sr ratio of 0.7035. The other consists of the intermediate rocks and one sample of basalt, which give an initial isochron 87Sr/86Sr value of 0.7051. The strong correlations between SiO2 and other major elements suggest that fractional crystallization played an important role in the magmatic processes. However, fractional crystallization cannot explain the geochemistry of most incompatible trace elements and Sr–Nd isotope characteristics. The positive correlation between Th/Nb and (La/Sm)N ratios demonstrates the direct relation between the enrichment of the light rare earth elements and the contamination of continental sediments. The high contents of large ion lithosphere elements (LILE) in the Permian volcanic rocks may suggest an additional ‘crust + fluid’ component, especially in the intermediate rocks, which are highly enriched in Ba (> 400 ppm) relative to the basic rocks (> 200 ppm). We propose that the subduction slab dropped into depleted mantle and released fluid, which induced the mantle metasomatism and LILE enrichment. The metasomatized mantle partially melted and formed the ‘primary’ magma. This primary magma assimilated with the Proterozoic biotite–quartz schist during its rise, and finally formed the Permian volcanic rocks. Magma assimilated with the Proterozoic biotite–quartz schist in small amounts could have produced the basic rocks, while assimilation of larger amounts of magma (because of longer assimilation time) would generate intermediate rocks.


2004 ◽  
Vol 36 (1) ◽  
pp. 300
Author(s):  
Α. Χατζηαποστόλου ◽  
Σ. Καλαϊτζίδης ◽  
Σ. Παπαζησίμου ◽  
Κ. Χρηστάνης ◽  
Δ. Βάγιας

The aim of this study is to estimate the environmental impacts in case of exploitation the Pellanalignites for power generation. The object of the study is to predict the element mobility during lignite combustion using mineralogical and geochemical data from bulk-lignite samples and their ashes of two cores from this area. The mineralogical determinations on the ashes revealed that quartz, K-feldspars and illitemicas are the major mineral phases contained in the lignite. The identification of anhydrite in ashes implies the presence of gypsum, althought neoformation of anhydrite from organic associated with Ca+2 and SO42 can not be excluded. These minerals correspond to primary phases. Oxides and hydroxides occur subordinately and probably represent minerals that do not correspond to primary phases. The results of the elemental analysis show that the major elements (>1000 ppm) are AI, Fe, Ca, Mg and Κ in the bulk samples of both cores. Minor elements (100-1000 ppm) are Na, Mn and Ba, while the concentrations of Be, Bi, Cd, Ce, Co, Cs, Cu, Eu, Ga, Hf, La, Li, Lu, Mo, Nb, Nd, Pb, Rb, Sb, Se, Sm, Sn, Sr, Tb, Te, Th, TI, U, Y, Yb and Zr do not exceed 100 ppm. The concentrations of many elements like As, Ba, Cr, Ni, V and Zn have a wide range among the bulk samples. In order to assess the geochemical affiliation of the studied elements, R-type factor analysis was applied on the element contents of bulk lignite and ash. The elements Ca, S, V, As, Μη, Mo, Na, Sb, Hf, Zr and U provide both organic and inorganic affiliations, while Se and Nb provide organic affiliations. To approach the mobility of each trace element, the relative enrichment factor (RE) was calculated. The most depleted trace elements according to RE mean (<0.5) are Hf and Sb, while the elements Se and Ba are moderately depleted (0.7>RE mean>0.5).


2001 ◽  
Vol 34 (3) ◽  
pp. 1255
Author(s):  
S. PANILAS ◽  
G. HATZIYANNIS

Multivariate statistical analysis was used on existing geochemical data of the Drama lignite deposit, eastern Macedonia, Greece. Factor analysis with varimax rotation technique was applied to study the distribution of major, trace and rare earth elements in the lignite and 850°C lignitic ash, to find a small set of factors that could explain most of the geochemical variability. The study showed that major elements AI, Na, Κ, contained in the lignite samples, presented high correlation with most of the trace and rare earth elements. In 850°C lignitic ashes major and trace elements present different redistribution. Only Al remained correlated with the trace elements Co, Cr, Rb, Ta, Th, Ti, Sc and rare earths related with inorganic matter in the lignite beds. Trace elements Fe, Mo, U, V, W, and Lu were associated with organic matter of lignite and had also been affected by the depositional environment.


2021 ◽  
Vol 24 (1) ◽  
pp. 1879-1888
Author(s):  
Tuan Anh Nguyen ◽  
Doan Thi Thuy ◽  
Ngo Tran Thien Quy ◽  
Lan Ching Yin

Introduction: Extrusive volcanic rocks, such as dacite, andesite, basalto-andesite, basalt… of Chau Thoi and Nui Gio hills in Bien Hoa and Binh Phuoc provinces, southern Viet Nam, characterize volcanic island arc rocks. These rock suites formed as the convergent tectonic between the Indochina and Sibumasu geological blocks. Methods: Geochemical data of rock samples collected on the field were examined and analyzed by the Academia Sinica I E S (Institute of Earth Science, Taiwan and processed with a GCD kit (Geochemical Data Toolkit) to ascertain their characteristics and geotectonic setting. Result: Geochemical data both in major elements and trace elements of the Chau Thoi – Nui Gioshow a specific characteristic of a volcanic island arc environment. Discussion: Chau Thoi and Nui Gio rocks are suitable to correlate to the Permian Thailand Loei Phetchabun volcanic belt. However, at the current time, Chau Thoi and Nui Gio rocks have been classified as Deo Bao Loc formation - late Jurassic to early Cretaceous in ages - belong Truong Son magmatic belt. This magmatic belt resulted from the Yanshanian orogeny by the subduction of the Paleo-Pacific oceanic plate beneath the Eurasia (Indochina) continental plate. More studies needed to be performed, specially geochronological data to support the study. Conclusion: Chau Thoi and Nui Gio rock suites characterize volcanic island arc rocks, products of a convergence tectonic between Indochina and Sibumasu blocks. They are remnants of the Thailand Loei Phetchabun volcanic belt, the first time reported in Vietnam.


Sign in / Sign up

Export Citation Format

Share Document