Test Results of Low NOx Catalytic Combustors for Gas Turbines

1994 ◽  
Vol 116 (3) ◽  
pp. 511-516 ◽  
Author(s):  
Y. Ozawa ◽  
J. Hirano ◽  
M. Sato ◽  
M. Saiga ◽  
S. Watanabe

Catalytic combustion is an ultralow NOx combustion method, so it is expected that this method will be applied to a gas turbine combustor. However, it is difficult to develop a catalytic combustor because catalytic reliability at high temperature is still insufficient. To overcome this difficulty, we designed a catalytic combustor in which premixed combustion was combined. By this device, it is possible to obtain combustion gas at a combustion temperature of 1300°C while keeping the catalytic temperature below 1000°C. After performing preliminary tests using LPG, we designed two types of combustor for natural gas with a capacity equivalent to one combustor used in a 20 MW class multican-type gas turbine. Combustion tests were conducted at atmospheric pressure using natural gas. As a result, it was confirmed that a combustor in which catalytic combustor segments were arranged alternately with premixing nozzles could achieve low NOx and high combustion efficiency in the range from 1000°C to 1300°C of the combustor exit gas temperature.

Author(s):  
Y. Ozawa ◽  
J. Hirano ◽  
M. Sato ◽  
M. Saiga ◽  
S. Watanabe

Catalytic combustion is an ultra low NOx combustion method, so it is expected that this method will be applied to gas turbine combustor. However, it is difficult to develop catalytic combustor because catalytic reliability at high temperature is still insufficient. To overcome this difficulty, we designed a catalytic combustor in which premixed combustion was combined. By this device, it is possible to obtain combustion gas at a combustion temperature of 1300°C while keeping the catalytic temperature below 1000°C. After performing preliminary tests using LPG, we designed two types of combustors for natural gas with a capacity equivalent to 1 combustor used in a 20MW–class multi–can type gas turbine. Combustion tests were conducted at atmospheric pressure using natural gas. As a result, it was confirmed that a combustor in which catalytic combustor segments were arranged alternately with premixing nozzles could achieve low NOx and high combustion efficiency in the range from 1000°C to 1300°C of the combustor exit gas temperature.


Author(s):  
Mircea Fetescu

The High Efficiency-Coal and Gas (HE-C&G) is a hybrid power plant concept integrating Conventional Steam Power Plants (CSPP) and gas turbine / combined cycle plants. The gas turbine exhaust gas energy is recovered in the HRSG providing partial condensate and feedwater preheating and generating steam corresponding to the main boiler live steam conditions (second steam source for the ST). The concept, exhibiting very high design flexibility, integrates the high performance Sequential Combustion gas turbines GT24/GT26 technology into a wide range of existing or new CSPP. Although HE-C&G refers to coal as the most abundant fossil fuel resource, oil or natural gas fired steam plants could be also designed or converted following the same principle. The HE-C&G provides very high marginal efficiencies on natural gas, up to and above 60%, very high operating and dispatching flexibility and on-line optimization of fuel and O&M costs at low capital investment. This paper emphasizes the operating flexibility and resulting benefits, recommending the HE-C&G as one of the most profitable options for generating power especially for conversion of existing CSPP with gas turbines.


Author(s):  
Arun Basu ◽  
Mike Gradassi ◽  
Ron Sills ◽  
Theo Fleisch ◽  
Raj Puri

A new, ultra-clean fuel for gas turbines — a blend consisting primarily of dimethyl ether (DME) with lesser amounts of methanol and water — has been identified by BP. This fuel, containing no metals, sulfur or aromatics, burns like natural gas and it can be handled like LPG. The turbine-grade DME fuel can be manufactured from natural gas, coal and other hydrocarbon or biomass feedstocks. High-purity DME, manufactured from methanol, is currently used as an aerosol propellant due to its environmentally benign characteristics. Fuel-grade DME is used commercially as a LPG-substitute in China. BP initiated key programs to test various fuel mixtures containing DME in General Electric test combustors with equivalent electricity production of nearly 16 MW. Later, BP collaborated with EPDC (Electric Power Development Corporation, Japan) to conduct additional follow-up tests. These tests show that DME is an excellent gas turbine fuel with emissions properties comparable to natural gas. BP is currently working with the Indian Oil Corporation (IOCL), the Gas Authority of India Limited (GAIL) and the Indian Institute of Petroleum to evaluate the potential of DME as a multi-purpose fuel for India. In June 2000, the India Ministry of Power issued a notification permitting the use of DME as a fuel for power generation subject to its meeting all the environmental and pollution regulations. This paper presents key gas turbine combustor test results and discusses how DME can be used as a fuel in gas turbines.


1998 ◽  
Vol 120 (3) ◽  
pp. 509-513 ◽  
Author(s):  
T. Fujii ◽  
Y. Ozawa ◽  
S. Kikumoto ◽  
M. Sato ◽  
Y. Yuasa ◽  
...  

Recently, the use of gas turbine systems, such as combined cycle and cogeneration systems, has gradually increased in the world. But even when a clean fuel such as LNG (liquefied natural gas) is used, thermal NOx is generated in the high temperature gas turbine combustion process. The NOx emission from gas turbines is controlled through selective catalytic reduction processes (SCR) in the Japanese electric industry. If catalytic combustion could be applied to the combustor of the gas turbine, it is expected to lower NOx emission more economically. Under such high temperature and high pressure conditions, as in the gas turbine, however, the durability of the catalyst is still insufficient. So it prevents the realization of a high temperature catalytic combustor. To overcome this difficulty, a catalytic combustor combined with premixed combustion for a 1300°C class gas turbine was developed. In this method, catalyst temperature is kept below 1000°C, and a lean premixed gas is injected into the catalytic combustion gas. As a result, the load on the catalyst is reduced and it is possible to prevent the catalyst deactivation. After a preliminary atmospheric test, the design of the combustort was modified and a high pressure combustion test was conducted. As a result, it was confirmed that NOx emission was below 10 ppm (at 16 percent O2) at a combustor outlet gas temperature of 1300°C and that the combustion efficiency was almost 100 percent. This paper presents the design features and test results of the combustor.


Author(s):  
T. Fujii ◽  
Y. Ozawa ◽  
S. Kikumoto ◽  
M. Sato ◽  
Y. Yuasa ◽  
...  

Recently, use of gas turbine systems such as combined cycle and cogeneration systems has gradually increased in the world. But even when a clean fuel such as LNG (liquefied natural gas) is used, thermal NOx is generated in the high temperature gas turbine combustion process. The NOx emission from gas turbines is controlled through selective catalytic reduction processes (SCR) in the Japanese electric industry. If catalytic combustion could be applied to the combustor of the gas turbine, it is expected to lower NOx emission more economically. Under such high temperature and high pressure conditions as in the gas turbine, however, the durability of the catalyst is still insufficient. So it prevents the realization of a high temperature catalytic combustor. To overcome this difficulty, a catalytic combustor combined with premixed combustion for a 1300°C class gas turbine was developed. In this method, catalyst temperature is kept below 1000°C and a lean premixed gas is injected into the catalytic combustion gas. As a result, the load on the catalyst is reduced and it is possible to prevent the catalyst deactivation. After a preliminary atmospheric test, the design of the combustor was modified and a high pressure combustion test was conducted. As a result, it was confirmed that NOx emission was below 10ppm (at 16% O2) at a combustor outlet gas temperature of 1300°C and that the combustion efficiency was almost 100%. This paper presents the design features and test results of the combustor.


Author(s):  
Colin F. McDonald

The combustion gas turbine, operating in both simple and combined cycle modes, is rapidly becoming the preferred prime-mover for electrical power generation for both new plants, and in the repowering of old power stations. In replacing Rankine cycle plants the combustion gas turbine could become dominant in the power generation field early in the next century. Fired currently with natural gas, and later with gasified coal these gas turbines will operate for many decades with no concern about resource depletion. This paper addresses an extension of high efficiency gas turbine technology but uses a combustion and emission-free heat source, namely a high temperature gas cooled nuclear reactor. The motivation for this evolution is essentially twofold, 1) to introduce an environmentally benign plant that does not emit greenhouse gases, and 2) provide electrical power to nations that have no indigenous natural gas or coal supplies. This paper presents a confidence-building approach that eliminates risk towards the goal of making the nuclear gas turbine a reality in the 21st century.


Author(s):  
Hafiz M Hassan ◽  
Adeel Javed ◽  
Asif H Khoja ◽  
Majid Ali ◽  
Muhammad B Sajid

A clear understanding of the flow characteristics in the older generation of industrial gas turbines operating with silo combustors is important for potential upgrades. Non-uniformities in the form of circumferential and radial variations in internal flow properties can have a significant impact on the gas turbine stage performance and durability. This paper presents a comprehensive study of the underlying internal flow features involved in the advent of non-uniformities from twin-silo combustors and their propagation through a single axial turbine stage of the Siemens v94.2 industrial gas turbine. Results indicate the formation of strong vortical structures alongside large temperature, pressure, velocity, and flow angle deviations that are mostly located in the top and bottom sections of the turbine stage caused by the excessive flow turning in the upstream tandem silo combustors. A favorable validation of the simulated exhaust gas temperature (EGT) profile is also achieved via comparison with the measured data. A drop in isentropic efficiency and power output equivalent to 2.28% points and 2.1 MW, respectively is observed at baseload compared to an ideal straight hot gas path reference case. Furthermore, the analysis of internal flow topography identifies the underperforming turbine blading due to the upstream non-uniformities. The findings not only have implications for the turbine aerothermodynamic design, but also the combustor layout from a repowering perspective.


Author(s):  
Elliot Sullivan-Lewis ◽  
Vincent McDonell

Lean-premixed gas turbines are now common devices for low emissions stationary power generation. By creating a homogeneous mixture of fuel and air upstream of the combustion chamber, temperature variations are reduced within the combustor, which reduces emissions of nitrogen oxides. However, by premixing fuel and air, a potentially flammable mixture is established in a part of the engine not designed to contain a flame. If the flame propagates upstream from the combustor (flashback), significant engine damage can result. While significant effort has been put into developing flashback resistant combustors, these combustors are only capable of preventing flashback during steady operation of the engine. Transient events (e.g., auto-ignition within the premixer and pressure spikes during ignition) can trigger flashback that cannot be prevented with even the best combustor design. In these cases, preventing engine damage requires designing premixers that will not allow a flame to be sustained. Experimental studies were conducted to determine under what conditions premixed flames of hydrogen and natural gas can be anchored in a simulated gas turbine premixer. Tests have been conducted at pressures up to 9 atm, temperatures up to 750 K, and freestream velocities between 20 and 100 m/s. Flames were anchored in the wakes of features typical of premixer passageways, including cylinders, steps, and airfoils. The results of this study have been used to develop an engineering tool that predicts under what conditions a flame will anchor, and can be used for development of flame anchoring resistant gas turbine premixers.


2021 ◽  
Vol 143 (3) ◽  
Author(s):  
Serena Romano ◽  
Roberto Meloni ◽  
Giovanni Riccio ◽  
Pier Carlo Nassini ◽  
Antonio Andreini

Abstract This paper addresses the impact of natural gas composition on both the operability and emissions of lean premixed gas turbine combustion system. This is an issue of growing interest due to the challenge for gas turbine manufacturers in developing fuel-flexible combustors capable of operating with variable fuel gases while producing very low emissions at the same time. Natural gas contains primarily methane (CH4) but also notable quantities of higher order hydrocarbons such as ethane (C2H6) can also be present. A deep understanding of natural gas combustion is important to obtain the highest combustion efficiency with minimal environmental impact. For this purpose, Large Eddy Simulations of an annular combustor sector equipped with a partially premixed burner are carried out for two different natural gas compositions with and without including the effect of flame strain rate and heat loss resulting in a more adequate description of flame shape, thermal field, and extinction phenomena. Promising results, in terms of NOx, compared against available experimental data, are obtained including these effects on the flame brush modeling, enhancing the fuel-dependency under nonadiabatic condition.


Author(s):  
Daniel E. Caguiat

The Naval Surface Warfare Center, Carderock Division (NSWCCD) Gas Turbine Emerging Technologies Code 9334 was tasked by NSWCCD Shipboard Energy Office Code 859 to research and evaluate fouling resistant compressor coatings for Rolls Royce Allison 501-K Series gas turbines. The objective of these tests was to investigate the feasibility of reducing the rate of compressor fouling degradation and associated rate of specific fuel consumption (SFC) increase through the application of anti-fouling coatings. Code 9334 conducted a market investigation and selected coatings that best fit the test objective. The coatings selected were Sermalon for compressor stages 1 and 2 and Sermaflow S4000 for the remaining 12 compressor stages. Both coatings are manufactured by Sermatech International, are intended to substantially decrease blade surface roughness, have inert top layers, and contain an anti-corrosive aluminum-ceramic base coat. Sermalon contains a Polytetrafluoroethylene (PTFE) topcoat, a substance similar to Teflon, for added fouling resistance. Tests were conducted at the Philadelphia Land Based Engineering Site (LBES). Testing was first performed on the existing LBES 501-K17 gas turbine, which had a non-coated compressor. The compressor was then replaced by a coated compressor and the test was repeated. The test plan consisted of injecting a known amount of salt solution into the gas turbine inlet while gathering compressor performance degradation and fuel economy data for 0, 500, 1000, and 1250 KW generator load levels. This method facilitated a direct comparison of compressor degradation trends for the coated and non-coated compressors operating with the same turbine section, thereby reducing the number of variables involved. The collected data for turbine inlet, temperature, compressor efficiency, and fuel consumption were plotted as a percentage of the baseline conditions for each compressor. The results of each plot show a decrease in the rates of compressor degradation and SFC increase for the coated compressor compared to the non-coated compressor. Overall test results show that it is feasible to utilize anti-fouling compressor coatings to reduce the rate of specific fuel consumption increase associated with compressor performance degradation.


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