scholarly journals A NOx Correlation Method for Gas Turbine Combustors Based on NOx Formation Assumptions

Author(s):  
Géza Vermes

Based on a simplified description of the combustion process in the primary zone of a can type gas turbine combustor, a generalized NOx versus fuel flow relationship is proposed. Using this relationship and considerations based on chemical kinetics, the effect of combustor inlet pressure, inlet temperature and air residence time on NOx formation is investigated in industrial and automotive type combustion chambers. Data reported in the literature and original test work is cited to substantiate the validity of the assumptions. Based on the findings, a simple method is presented to predict NOx emissions of a gas turbine combustor under conditions which differ substantially from those of the test run. The assumptions may be used to assemble a model for a priori prediction of NOx emissions in a given combustion geometry.

Author(s):  
Mohamed A. Altaher ◽  
Hu Li ◽  
Gordon E. Andrews

Biodiesels have advantages of low carbon footprint, reduced toxic emissions, improved energy supply security and sustainability and therefore attracted attentions in both industrial and aero gas turbines sectors. Industrial gas turbine applications are more practical biodiesels due to low temperature waxing and flow problems at altitude for aero gas turbine applications. This paper investigated the use of biodiesels in a low NOx radial swirler, as used in some industrial low NOx gas turbines. A waste cooking oil derived methyl ester biodiesel (WME) was tested on a radial swirler industrial low NOx gas turbine combustor under atmospheric pressure, 600K air inlet temperature and reference Mach number of 0.017&0.023. The pure WME, its blends with kerosene (B20 and B50) and pure kerosene were tested for gaseous emissions and lean extinction as a function of equivalence ratio for both Mach numbers. Sauter Mean Diameter (SMD) of the fuel spray droplets was calculated. The results showed that the WME and its blends had lower CO, UHC emissions and higher NOx emissions than the kerosene. The weak extinction limits were determined for all fuels and B100 has the lowest value. The higher air velocity (at Mach = 0.023) resulted in smaller SMDs which improved the mixing and atomizing of fuels and thus led to reductions in NOx emissions.


Author(s):  
Di Wang ◽  
Wenjun Kong ◽  
Yuhua Ai ◽  
Baorui Wang

A research program is in development in China in order to realize a demonstrator of combined cooling heating and power system (CCHP) with net electrical output around 100kW by using of a can-type micro gas turbine. In this paper, numerical simulations were completed to investigate the pollutant emissions in a can-type low NOx gas turbine combustor. Based on the analysis of the computational fluid dynamics (CFD) results, a Chemical Reactor Network (CRN) model was set up to simulate the pollutant emissions in the combustor with detailed gas-phase chemical kinetic mechanism of GRI-Mech 3.0. The CRN consists of a number of ideal reactors of the perfectly stirred reactors (PSR) and plug flow reactors (PFR) in series and parallel structures. Two types of CRN models were designed. One is relatively simple, another is more complex. The results show that the complex CRN model corresponds with the actual combustion process better. The trends of nitrogen oxides (NOx) and carbon monoxide (CO) varying with the equivalence ratio were conducted. Effects of the inlet temperature and pressure on NOx and CO emissions were also presented in this paper. At last, the numerical results are compared with the experimental results.


1996 ◽  
Vol 118 (3) ◽  
pp. 534-540 ◽  
Author(s):  
T. Nakata ◽  
M. Sato ◽  
T. Ninomiya ◽  
T. Hasegawa

Developing integrated coal gasification combined-cycle systems ensures cost-effective and environmentally sound options for supplying future power generation needs. The reduction of NOx emissions and increasing the inlet temperature of gas turbines are the most significant issues in gas turbine development in Integrated Coal Gasification Combined Cycle (IGCC) power generation systems. The coal gasified fuel, which is produced in a coal gasifier of an air-blown entrained-flow type has a calorific value as low as 1/10 of natural gas. Furthermore, the fuel gas contains ammonia when a gas cleaning system is a hot type, and ammonia will be converted to nitrogen oxides in the combustion process of a gas turbine. This study is performed in a 1500°C-class gas turbine combustor firing low-Btu coal-gasified fuel in IGCC systems. An advanced rich-lean combustor of 150-MW class gas turbine was designed to hold stable combustion burning low-Btu gas and to reduce fuel NOx emissions from the ammonia in the fuel. The main fuel and the combustion air are supplied into a fuel-rich combustion chamber with strong swirl flow and make fuel-rich flame to decompose ammonia into intermediate reactants such as NHi and HCN. The secondary air is mixed with primary combustion gas dilatorily to suppress the oxidization of ammonia reactants in fuel-lean combustion chamber and to promote a reducing process to nitrogen. By testing under atmospheric pressure conditions, the authors have obtained a very significant result through investigating the effect of combustor exit gas temperature on combustion characteristics. Since we have ascertained the excellent performance of the tested combustor through our extensive investigation, we wish to report on the results.


1976 ◽  
Vol 98 (3) ◽  
pp. 320-326 ◽  
Author(s):  
W. S. Y. Hung

A diffusion limited model has been described previously to simulate accurately the thermal NOx emission processes in various gas turbine combustors for fuels containing negligible amounts of fuel bound nitrogen. The application of this model to simulate accurately the water injection process has also been demonstrated. It is currently proposed that any bound nitrogen in fuel is completely reacted to form nitric oxide during the hydrocarbon combustion process; the ultimate net conversion is determined subsequently based on the Zeldovich mechanisms. With this additional assumption, this model has been generalized to include the use of fuels containing significant amounts of bound nitrogen, such as crude or residual oils. The predicted NOx emissions from these nitrogen containing fuels are in excellent agreement with laboratory and field data including the effect of water injection. Comprehensive understanding of the NOx formation processes has been gained from the current analytical study.


2021 ◽  
Vol 35 (8) ◽  
pp. 6776-6784
Author(s):  
Truc Huu Nguyen ◽  
Jungkyu Park ◽  
Changhun Sin ◽  
Seungchai Jung ◽  
Shaun Kim

Author(s):  
Lei-Yong Jiang ◽  
Yinghua Han ◽  
Prakash Patnaik

To understand the physics of volcanic ash impact on gas turbine hot-components and develop much-needed tools for engine design and fleet management, the behaviors of volcanic ash in a gas turbine combustor and nozzle guide vanes (NGV) have been numerically investigated. High-fidelity numerical models are generated, and volcanic ash sample, physical, and thermal properties are identified. A simple critical particle viscosity—critical wall temperature model is proposed and implemented in all simulations to account for ash particles bouncing off or sticking on metal walls. The results indicate that due to the particle inertia and combustor geometry, the volcanic ash concentration in the NGV cooling passage generally increases with ash size and density, and is less sensitive to inlet velocity. It can reach three times as high as that at the air inlet for the engine conditions and ash properties investigated. More importantly, a large number of the ash particles entering the NGV cooling chamber are trapped in the cooling flow passage for all four turbine inlet temperature conditions. This may reveal another volcanic ash damage mechanism originated from engine cooling flow passage. Finally, some suggestions are recommended for further research and development in this challenging field. To the best of our knowledge, it is the first study on detailed ash behaviors inside practical gas turbine hot-components in the open literature.


Author(s):  
D. A. Sullivan ◽  
P. A. Mas

The effect of inlet temperature, pressure, air flowrate and fuel-to-air ratio on NOx emissions from gas turbine combustors has received considerable attention in recent years. A number of semi-empirical and empirical correlations relating these variables to NOx emissions have appeared in the literature. They differ both in fundamental assumptions and in their predictions. In the present work, these simple NOx correlations are compared to each other and to experimental data. A review of existing experimental data shows that an adequate data base does not exist to evaluate properly the various NOx correlations. Recommendations are proposed to resolve this problem in the future.


Author(s):  
Chi-Rong Liu ◽  
Hsin-Yi Shih

The purpose of this study is to investigate the combustion and emission characteristics of syngas fuels applied in a micro gas turbine, which is originally designed for a natural gas fired engine. The computation results were conducted by a numerical model, which consists of the three-dimension compressible k–ε model for turbulent flow and PPDF (presumed probability density function) model for combustion process. As the syngas is substituted for methane, the fuel flow rate and the total heat input to the combustor from the methane/syngas blended fuels are varied with syngas compositions and syngas substitution percentages. The computed results presented the syngas substitution effects on the combustion and emission characteristics at different syngas percentages (up to 90%) for three typical syngas compositions and the conditions where syngas applied at fixed fuel flow rate and at fixed heat input were examined. Results showed the flame structures varied with different syngas substitution percentages. The high temperature regions were dense and concentrated on the core of the primary zone for H2-rich syngas, and then shifted to the sides of the combustor when syngas percentages were high. The NOx emissions decreased with increasing syngas percentages, but NOx emissions are higher at higher hydrogen content at the same syngas percentage. The CO2 emissions decreased for 10% syngas substitution, but then increased as syngas percentage increased. Only using H2-rich syngas could produce less carbon dioxide. The detailed flame structures, temperature distributions, and gas emissions of the combustor were presented and compared. The exit temperature distributions and pattern factor (PF) were also discussed. Before syngas fuels are utilized as an alternative fuel for the micro gas turbine, further experimental testing is needed as the modeling results provide a guidance for the improved designs of the combustor.


Author(s):  
Masato Hiramatsu ◽  
Yoshifumi Nakashima ◽  
Sadamasa Adachi ◽  
Yudai Yamasaki ◽  
Shigehiko Kaneko

One approach to achieving 99% combustion efficiency (C.E.) and 10 ppmV or lower NOx (at 15%O2) in a micro gas turbine (MGT) combustor fueled by biomass gas at a variety of operating conditions is with the use of flameless combustion (FLC). This paper compares experimentally obtained results and CHEMKIN analysis conducted for the developed combustor. As a result, increase the number of stage of FLC combustion enlarges the MGT operation range with low-NOx emissions and high-C.E. The composition of fuel has a small effect on the characteristics of ignition in FLC. In addition, NOx in the engine exhaust is reduced by higher levels of CO2 in the fuel.


2017 ◽  
Vol 140 (2) ◽  
Author(s):  
Andreas Schwärzle ◽  
Thomas O. Monz ◽  
Andreas Huber ◽  
Manfred Aigner

Jet-stabilized combustion is a promising technology for fuel flexible, reliable, highly efficient combustion systems. The aim of this work is a reduction of NOx emissions of a previously published two-stage micro gas turbine (MGT) combustor (Zanger et al., 2015, “Experimental Investigation of the Combustion Characteristics of a Double-Staged FLOX-Based Combustor on an Atmospheric and a Micro Gas Turbine Test Rig,” ASME Paper No. GT2015-42313 and Schwärzle et al., 2016, “Detailed Examination of Two-Stage Micro Gas Turbine Combustor,” ASME Paper No. GT2016-57730), where the pilot stage (PS) of the combustor was identified as the main contributor to NOx emissions. The geometry optimization was carried out regarding the shape of the pilot dome and the interface between PS and main stage (MS) in order to prevent the formation of high-temperature recirculation zones. Both stages have been run separately to allow a detailed understanding of the flame stabilization within the combustor, its range of stable combustion, the interaction between both stages, and the influence of the modified geometry. All experiments were conducted at atmospheric pressure and an air preheat temperature of 650  °C. The flame was analyzed in terms of shape, length, and lift-off height, using OH* chemiluminescence (OH-CL) images. Emission measurements for NOx, CO, and unburned hydrocarbons (UHC) emissions were carried out. At a global air number of λ = 2, a fuel split variation was carried out from 0 (only PS) to 1 (only MS). The modification of the geometry leads to a decrease in NOx and CO emissions throughout the fuel split variation in comparison with the previous design. Regarding CO emissions, the PS operations are beneficial for a fuel split above 0.8. The local maximum in NOx emissions observed for the previous combustor design at a fuel split of 0.78 was not apparent for the modified design. NOx emissions were increasing, when the local air number of the PS was below the global air number. In order to evaluate the influence of the modified design on the flow field and identify the origin of the emission reduction compared to the previous design, unsteady Reynolds-averaged Navier–Stokes simulations were carried out for both geometries at fuel splits of 0.93 and 0.78, respectively, using the DLR (German Aerospace Center) in-house code turbulent heat release extension of the tau code (theta) with the k–ω shear stress transport turbulence model and the DRM22 (Kazakov and Frenklach, 1995, “DRM22,” University of California at Berkeley, Berkeley, CA, accessed Sept. 21, 2017, http://www.me.berkeley.edu/drm/) detailed reaction mechanism. The numerical results showed a strong influence of the recirculation zones on the PS reaction zone.


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