The Thermal Transport Properties of Ethylene Glycol Based MGO Nanofluids

Author(s):  
Wei Yu ◽  
Hua-Qing Xie ◽  
Yang Li ◽  
Li-Fei Chen

Ethylene glycol based nanofluids containing MgO nanoparticles (MgO-EG) were prepared, and the transport properties including thermal conductivity and viscosity were measured. The results show that the thermal conductivity of MgO-EG nanofluid depends strongly on particle concentration, and it increases nonlinearly with the volume fraction of nanoparticles. The thermal conductivity of MgO-EG nanofluids is larger than that of nanofluids containing the same volume fraction of TiO2, ZnO, Al2O3 and SiO2, maybe due to its lowest viscosity among the tested metallic oxide nanofluids. Thermal conductivity enhancement of MgO-EG nanofluids appears weak dependence on temperature from 10 to 60°C, and the enhanced ratios are almost constant. Viscosity measurements show that MgO-EG nanofluids demonstrate Newtonian behavior, and the viscosity significantly decreases with temperature. The thermal conductivity and viscosity increments of nanofluids are higher than those of the existing classical models for the solid-liquid mixture.

Author(s):  
Wei Yu ◽  
Huaqing Xie ◽  
Lifei Chen ◽  
Yang Li ◽  
Dehui Li

The work presents a method to prepare stable nanofluids containing graphene oxide nanosheets (GO-EG nanofluid). The hydrophilic surfaces let graphene oxide nanosheets have good compatibility with ethylene glycol. The thermal conductivity of the nanofluids was measured by a short hot wire technique, and the result shows that the thermal conductivity of GO-EG nanofluids is almost constant within 7 days, and it reflects the high stability of GO-EG nanofluids. The thermal conductivity enhancement ratios of GO-EG nanofluids were almost constant with tested temperatures vary. GO-EG nanofluids have substantially higher thermal conductivities than the base fluids. When the loading is 5.0 vol.%, the enhancement ratios is up to 61%, much larger than those of metallic oxide. For 1.0 vol.% GO-EG nanofluid, the enhancement ratios is 10.5%, less than those of CNT with the same loading. The reason may be due to the defects, caused by the treatment with strong Oxidants. In our opinion, heat transport in the GO nanosheet is one of the major contributions to the increase of the effective thermal conductivity of nanofluids.


2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
B. Usowicz ◽  
J. B. Usowicz ◽  
L. B. Usowicz

A physical-statistical model for predicting the effective thermal conductivity of nanofluids is proposed. The volumetric unit of nanofluids in the model consists of solid, liquid, and gas particles and is treated as a system made up of regular geometric figures, spheres, filling the volumetric unit by layers. The model assumes that connections between layers of the spheres and between neighbouring spheres in the layer are represented by serial and parallel connections of thermal resistors, respectively. This model is expressed in terms of thermal resistance of nanoparticles and fluids and the multinomial distribution of particles in the nanofluids. The results for predicted and measured effective thermal conductivity of several nanofluids (Al2O3/ethylene glycol-based and Al2O3/water-based; CuO/ethylene glycol-based and CuO/water-based; and TiO2/ethylene glycol-based) are presented. The physical-statistical model shows a reasonably good agreement with the experimental results and gives more accurate predictions for the effective thermal conductivity of nanofluids compared to existing classical models.


2019 ◽  
Vol 141 (3) ◽  
Author(s):  
Hamid Loulijat ◽  
Hicham Zerradi

In this work, the equilibrium molecular dynamics (MD) simulation combined with the Green–Kubo method is employed to calculate the thermal conductivity and investigate the impact of the liquid layer around the solid nanoparticle (NP) in enhancing thermal conductivity of nanofluid (argon–copper), which contains the liquid argon as a base fluid surrounding the spherical or cylindrical NPs of copper. First, the thermal conductivity is calculated at temperatures 85, 85.5, 86, and 86.5 K and for different volume fractions ranging from 4.33% to 11.35%. Second, the number ΔN of argon atoms is counted in the liquid layer formed at the solid–liquid interface with the thickness of Δr = 0.3 nm around the NP. Finally, the number density n of argon atoms in this layer formed is calculated in all cases. Also, the results for spherical and cylindrical NPs are compared with one another. It is observed that the thermal conductivity of the nanofluid increased with the increasing volume fraction and the number ΔN. Likewise, the thermal conductivity of nanofluid containing spherical NPs is higher than that of nanofluid containing cylindrical NPs. Furthermore, the number density n of argon atoms near the surface of spherical NPs is higher than that of argon atoms attached in the curved surface of cylindrical NPs. As a result, the liquid layer around the solid NP has been considered one of the mechanisms responsible contributing to the thermal conductivity enhancement in nanofluids.


Author(s):  
Jing Fan ◽  
Liqiu Wang

The recent first-principle model shows a dual-phase-lagging heat conduction in nanofluids at the macroscale. The macroscopic heat-conduction behavior and the thermal conductivity of nanofluids are determined by their molecular physics and microscale physics. We examine numerically effects of particle-fluid thermal conductivity ratio, particle volume fraction, shape, aggregation, and size distribution on macroscale thermal properties for nine types of nanofluids, without considering the interfacial thermal resistance and dynamic processes on particle-fluid interfaces and particle-particle contacting surfaces. The particle radius of gyration and non-dimensional particle-fluid interfacial area in the unit cell are two very important parameters in characterizing the effect of particles’ geometrical structures on thermal conductivity of nanofluids. Nanofluids containing cross-particle networks have conductivity which practically reaches the Hashin-Shtrikman bounds. Moreover, particle aggregation influences the effective thermal conductivity only when the distance between particles is less than the particle dimension. Uniformly-sized particles are desirable for the conductivity enhancement, although to a limited extent.


2014 ◽  
Vol 66 (2) ◽  
pp. 238-243 ◽  
Author(s):  
Ayush Jain ◽  
Imbesat Hassan Rizvi ◽  
Subrata Kumar Ghosh ◽  
P.S. Mukherjee

Purpose – Nanofluids exhibit enhanced heat transfer characteristics and are expected to be the future heat transfer fluids particularly the lubricants and transmission fluids used in heavy machinery. For studying the heat transfer behaviour of the nanofluids, precise values of their thermal conductivity are required. For predicting the correct value of thermal conductivity of a nanofluid, mathematical models are necessary. In this paper, the effective thermal conductivity of various nanofluids has been reported by using both experimental and mathematical modelling. The paper aims to discuss these issues. Design/methodology/approach – Hamilton and Crosser equation was used for predicting the thermal conductivities of nanofluids, and the obtained values were compared with the experimental findings. Nanofluid studied in this paper are Al2O3 in base fluid water, Al2O3 in base fluid ethylene glycol, CuO in base fluid water, CuO in base fluid ethylene glycol, TiO2 in base fluid ethylene glycol. In addition, studies have been made on nanofluids with CuO and Al2O3 in base fluid SAE 30 particularly for heavy machinery applications. Findings – The study shows that increase in thermal conductivity of the nanofluid with particle concentration is in good agreement with that predicted by Hamilton and Crosser at typical lower concentrations. Research limitations/implications – It has been observed that deviation between experimental and theoretical results increases as the volume concentration of nanoparticles increases. Therefore, the mathematical model cannot be used for predicting thermal conductivity at high concentration values. Originality/value – Studies on nanoparticles with a standard mineral oil as base fluid have not been considered extensively as per the previous literatures available.


2009 ◽  
Vol 60-61 ◽  
pp. 394-398 ◽  
Author(s):  
Gen Sheng Wu ◽  
Jue Kuan Yang ◽  
Shu Lin Ge ◽  
Yu Juan Wang ◽  
Min Hua Chen ◽  
...  

The stable and homogeneneous aqueous suspension of carbon nanotubes was prepared in this study. The stability of the nanofluids was improved greatly due to the use of a new dispersant, humic acid. The thermal conductivity of the aqueous suspension was measured with the 3ω method. The experimental results showed that the thermal conductivity of the suspensions increases with the temperature and also is nearly proportional to the loading of the nanoparticles. The thermal conductivity enhancement of single-walled carbon nanotubes (SWNTs) suspensions is better than that of the multi-walled carbon nanotubes (MWNTs) suspensions. Especially for a volume fraction of 0.3846% SWNTs, the thermal conductivity is enhanced by 40.5%. Furthermore, the results at 30°C match well with Jang and Choi’s model.


2020 ◽  
Vol 1008 ◽  
pp. 47-52
Author(s):  
Abdallah Yousef Mohammed Ali ◽  
Ahmed Hassan El-Shazly ◽  
Marwa Farouk El-Kady ◽  
Hesham Ibrahim Elqady ◽  
Kholoud Madih ◽  
...  

Magnesium oxide (MgO) nanoparticles were synthesized using the sol-gel technique then characterized. Cetyl Trimethyl Ammonium Bromide (CTAB) surfactant was added to reduce Van der Waal forces among MgO nanoparticles and distilled water forming a stable nanofluid using two-step method with aid of ultrasound sonication. Pure distilled water and nanofluids with different volume fractions of 0.25, 0.5, 0.75, and 1% are used as working fluids. Thermophysical properties of prepared nanofluids were measured experimentally and determined theoretically. Effect of solid volume fraction on the thermophysical properties; including thermal conductivity, heat capacity, viscosity, and density of MgO-water nanofluids are discussed. Moreover, experimental results have been compared with the suitable correlations for MgO-water nanofluid. The findings show that thermal conductivity, viscosity, and density of nanofluid increases with increasing solid volume fraction.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
M. C. Mbambo ◽  
M. J. Madito ◽  
T. Khamliche ◽  
C. B. Mtshali ◽  
Z. M. Khumalo ◽  
...  

Abstract We report on the synthesis and thermal conductivity of gold nanoparticles (AuNPs) decorated graphene nanosheets (GNs) based nanofluids. The GNs-AuNPs nanocomposites were synthesised using a nanosecond pulsed Nd:YAG laser (wavelength = 1,064 nm) to ablate graphite target followed by Au in ethylene glycol (EG) base fluid to obtain GNs-AuNPs/EG hybrid nanofluid. The characterization of the as-synthesised GNs-AuNPs/EG hybrid nanofluid confirmed a sheet-like structure of GNs decorated with crystalline AuNPs with an average particle diameter of 6.3 nm. Moreover, the AuNPs appear smaller in the presence of GNs which shows the advantage of ablating AuNPs in GNs/EG. The thermal conductivity analysis in the temperature range 25–45 °C showed that GNs-AuNPs/EG hybrid nanofluid exhibits an enhanced thermal conductivity of 0.41 W/mK compared to GNs/EG (0.35 W/mK) and AuNPs/EG (0.39 W/mK) nanofluids, and EG base fluid (0.33 W/mK). GNs-AuNPs/EG hybrid nanofluid displays superior enhancement in thermal conductivity of up to 26% and this is due to the synergistic effect between AuNPs and graphene sheets which have inherent high thermal conductivities. GNs-AgNPs/EG hybrid nanofluid has the potential to impact on enhanced heat transfer technological applications. Also, this work presents a green synthesis method to produce graphene-metal nanocomposites for various applications.


Author(s):  
Huaqing Xie ◽  
Lifei Chen ◽  
Yang Li ◽  
Wei Yu

Multiwalled carbon nanotubes (CNTs) have been treated by using a mechanochemical reaction method to enhance their dispersibility for producing CNT nanofluids. The thermal conductivity was measured by a short hot wire technique and the viscosity was measured by a rotary viscometer. The thermal conductivity enhancement reaches up to 17.5% at a volume fraction of 0.01 for an ethylene glycol based nanofluid. Temperature variation was shown to have no obvious effects on the thermal conductivity enhancement for the as prepared nanofluids. With an increase in the thermal conductivity of the base fluid, the thermal conductivity enhancement of a nanofluid decreases. At low volume fractions (<0.4 Vol%), nanofluids have lower viscosity than the corresponding base fluid due to lubricative effect of nanoparticles. When the volume fraction is higher than 0.4 Vol%, the viscosity increases with nanoparticle loadings. The prepared nanofluids, with no contamination to medium, good fluidity, stability, and high thermal conductivity, would have potential applications as coolants in advanced thermal systems.


2006 ◽  
Vol 129 (3) ◽  
pp. 298-307 ◽  
Author(s):  
Sang Hyun Kim ◽  
Sun Rock Choi ◽  
Dongsik Kim

The thermal conductivity of water- and ethylene glycol-based nanofluids containing alumina, zinc-oxide, and titanium-dioxide nanoparticles is measured using the transient hot-wire method. Measurements are performed by varying the particle size and volume fraction, providing a set of consistent experimental data over a wide range of colloidal conditions. Emphasis is placed on the effect of the suspended particle size on the effective thermal conductivity. Also, the effect of laser-pulse irradiation, i.e., the particle size change by laser ablation, is examined for ZnO nanofluids. The results show that the thermal-conductivity enhancement ratio relative to the base fluid increases linearly with decreasing the particle size but no existing empirical or theoretical correlation can explain the behavior. It is also demonstrated that high-power laser irradiation can lead to substantial enhancement in the effective thermal conductivity although only a small fraction of the particles are fragmented.


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