Synthesis and Wear Performance of New Thiocarbamate Derivatives

Author(s):  
Y.-W. Kim ◽  
K. Chung ◽  
T.-K. Yang ◽  
D.-H. Hwang ◽  
W.-O. Cho

A series of sebacic acid esters containing mercaptobenzothiazole and dialkylenedithiocarbamate, which are potential environmentally friendly lubricating grease additives, were synthesized. The tribological properties as lubricating additives in Li-soap greases were evaluated using a 4-ball tester and SRV tester. The results show that the series of sebasic acid esters with dioctyldithiocarbamate group and mercaptobenzothiazole groups possess better antiwear performance than that of ZnDTP. Whereas, SRV EP characteristics showed worse than that of ZnDTP.

2021 ◽  
pp. 36-40
Author(s):  
F.F. Yusubov

Tribotechnical indicators of environmentally friendly frictional composite materials with phenol-formaldehyde matrix are studied. Friction tests were carried out on a MMW-1 vertical tribometer according to the pin-on-disk scheme. Keywords: brake pads, composites, friction and wear, plasticizers, degradation, porosity. [email protected]


2017 ◽  
Vol 69 (5) ◽  
pp. 645-654 ◽  
Author(s):  
Juozas Padgurskas ◽  
Raimundas Rukuiža ◽  
Ihor Mandziuk ◽  
Arturas Kupcinskas ◽  
Katerina Prisyazhna ◽  
...  

Purpose The purpose of this paper is to report on the tribological properties of beef tallow grease and improvements therein through modification with special processing, polymeric compounds and additives. Design/methodology/approach Pure original beef tallow grease was used as a biological lubricating grease reference material for the tribological research. Beef tallow was modified and synthesized by adding special biological anti-oxidant additives, LZ anti-wear additives, waste polyethylene terephthalate (PET) polymer compounds and thermally processed graphite. Findings Rheometric measurements indicate that the beef tallow grease modification technology used in this study enables control of the synthesis process to produce lubricants with the required microstructure. Investigation results of the tribological properties of differently modified greases show that beef tallow synthesized with polymer additives efficiently operates together with anti-wear additives to reduce friction and wear. The grease compound with thermally processed graphite has good tribological properties at 300 N load levels. The critical load level of lubricating greases could be significantly increased through the use of anti-wear additives and thermally processed graphite. Originality/value Investigation results of the tribological properties of differently modified beef tallow greases show that beef tallow synthesized with polymer additives efficiently operates together with anti-wear additives to reduce friction and wear. The critical load level of lubricating beef tallow greases could be significantly increased using anti-wear additives and thermally processed graphite.


Cellulose ◽  
2018 ◽  
Vol 25 (5) ◽  
pp. 3091-3103 ◽  
Author(s):  
Yanjuan Zhang ◽  
Liping Wei ◽  
Huayu Hu ◽  
Zengyan Zhao ◽  
Zuqiang Huang ◽  
...  

Author(s):  
Takashi Nogi

Some tribological properties of an ionic liquid were investigated by using a pin-on-disc friction and wear tester. Due to running-in, the coefficient of friction of the ionic liquid decreased with time to a very low value of 0.02 which suggests that the lubrication regime was hydrodynamic at the end of the tests. Anti-wear performance of the ionic liquid was substantially comparable to a paraffin-based oil.


Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1589 ◽  
Author(s):  
Mazin Tahir ◽  
Abdul Samad Mohammed ◽  
Umar Azam Muhammad

The effect of various operational factors, such as sliding speed, normal load and temperature on the tribological properties of Date palm fruit syrup (DPFS) as an environmentally friendly lubricant, is investigated. Ball-on-disc wear tests are conducted on mild steel samples in the presence of DPFS as a lubricant under different conditions and the coefficient of friction and wear rate are measured. Scanning electron microscopy, stylus profilometry, and Fourier transform infrared spectroscopy are used to evaluate the wear tracks to determine the underlying wear mechanisms. Results showed that DPFS has excellent tribological properties in terms of low friction and low wear rates making it a potential candidate to be used as a lubricant in tribological applications.


Lubricants ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 26 ◽  
Author(s):  
Aoxiang Lu ◽  
Wenxing Niu ◽  
Yingjing Dai ◽  
Hong Xu ◽  
Jinxiang Dong

The layered compound ZnS(NH2CH2CH2NH2)0.5 was evaluated as an additive in grease with different concentrations by using a four-ball tribometer. Results show that ZnS(NH2CH2CH2NH2)0.5 grease has good load bearing ability and excellent anti-wear properties. ZnS(NH2CH2CH2NH2)0.5 revealed better wear resistance than that of ZnS under all test conditions. The reason for this may be that the two-dimensional structure of ZnS(NH2CH2CH2NH2)0.5, with larger interspaces, facilitates an easier sliding process, improving the anti-wear performance. The mechanism was estimated through analysis of the worn surface with SEM, EDS, 3D, and XPS. XPS analysis results show that the tribofilm was mainly composed of FeS, ZnS, ZnO, FexOy, Feu(SO4)v, and ZnSO4. Owing to the simple synthetic method and superior tribological properties as a grease-based additive, ZnS(NH2CH2CH2NH2)0.5 holds great potential for use in demanding industrial applications in the future.


2014 ◽  
Vol 27 (6) ◽  
pp. 347-358 ◽  
Author(s):  
Raimondas Kreivaitis ◽  
Juozas Padgurskas ◽  
Milda Gumbytė ◽  
Artūras Kupčinskas

RSC Advances ◽  
2018 ◽  
Vol 8 (42) ◽  
pp. 23606-23614 ◽  
Author(s):  
Bo Yu ◽  
Kai Wang ◽  
Yiwen Hu ◽  
Feng Nan ◽  
Jibin Pu ◽  
...  

The dispersion of graphene-based materials in lubricating oil is a prerequisite for improving its friction and wear performance.


2014 ◽  
Vol 66 (4) ◽  
pp. 538-544 ◽  
Author(s):  
Tiedan Chen ◽  
Yanqiu Xia ◽  
Zhilu Liu ◽  
Zeyun Wang

Purpose – The mixture of attapulgite and bentonite was used as a thickener, and polyalphaolefin was used as the base oil to prepare the new lubricating grease. Some solid particles such as Polytetrafluoroethene (PTFE), MoS2, nano-calcium carbonate and graphite were added in the new lubricating grease as anti-wear additives to investigate the tribological sensitivity. Design/methodology/approach – The new lubricating grease was evaluated by optimol-SRV reciprocating friction and wear tester, and the wear volumes were determined using a MicroXAM-3D. At the same time, the dropping point and the cone penetration were investigated and analyzed. The tribological properties of the new lubricating grease and the sensitivity of some solid lubricating additives to the new lubricating base grease were investigated; pure organic-bentonite and pure organic-attapulgite base grease were used as contrast. Findings – The new lubricating grease based on the surface-modified bentonite/attapulgite clay base grease was synthesized with a relatively high dropping point, and the mass ratio is 25/75 bentonite/attapulgite clay base grease, having a better tribological performance. MoS2 was used as an anti-wear additive that has good tribological sensitivity to the new lubricating base grease. Originality/value – The main innovative thought of this work lies in the mixture of attapulgite and bentonite used as thickener. A relevant report is not available at present.


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