scholarly journals A chiral switchable photovoltaic ferroelectric 1D perovskite

2020 ◽  
Vol 6 (9) ◽  
pp. eaay4213 ◽  
Author(s):  
Yang Hu ◽  
Fred Florio ◽  
Zhizhong Chen ◽  
W. Adam Phelan ◽  
Maxime A. Siegler ◽  
...  
Keyword(s):  
Electric Fields ◽  
Mirror Symmetry ◽  
Degrees Of Freedom ◽  
Electrical Measurements ◽  
Temperature Dependent ◽  
Paraelectric Phase Transition ◽  
Strongly Coupled ◽  
Yield Phenomena ◽  
Hybrid Perovskite ◽  
Low Dimensional

Spin and valley degrees of freedom in materials without inversion symmetry promise previously unknown device functionalities, such as spin-valleytronics. Control of material symmetry with electric fields (ferroelectricity), while breaking additional symmetries, including mirror symmetry, could yield phenomena where chirality, spin, valley, and crystal potential are strongly coupled. Here we report the synthesis of a halide perovskite semiconductor that is simultaneously photoferroelectricity switchable and chiral. Spectroscopic and structural analysis, and first-principles calculations, determine the material to be a previously unknown low-dimensional hybrid perovskite (R)-(−)-1-cyclohexylethylammonium/(S)-(+)-1 cyclohexylethylammonium) PbI3. Optical and electrical measurements characterize its semiconducting, ferroelectric, switchable pyroelectricity and switchable photoferroelectric properties. Temperature dependent structural, dielectric and transport measurements reveal a ferroelectric-paraelectric phase transition. Circular dichroism spectroscopy confirms its chirality. The development of a material with such a combination of these properties will facilitate the exploration of phenomena such as electric field and chiral enantiomer–dependent Rashba-Dresselhaus splitting and circular photogalvanic effects.

scholarly journals An Analytical Theory of Hall-Effect Devices with Three Contacts

2018 ◽  
Vol 4 (1) ◽  
pp. 14-42 ◽  
Author(s):  
Udo Ausserlechner
Keyword(s):  
Hall Effect ◽  
Sheet Resistance ◽  
Mirror Symmetry ◽  
Degrees Of Freedom ◽  
Signal To Noise Ratio ◽  
Electrical Measurements ◽  
Small Magnetic Field ◽  
Specific Device ◽  
Exact Shape ◽  
The One

Object:Vertical Hall-effect devices (VHalls) and split-drain MAG-FETs often have three contacts and a single mirror symmetry. We discuss the Equivalent Resistor Circuit (ERC) at small magnetic field, relate it to the electrical degrees of freedom, and compare it to traditional Hall plates with four contacts.Methods:In contrast to devices with four contacts, it is not possible to determine the sheet resistance of devices with three contacts by electrical measurements like the one of van der Pauw. However, for both types of devices, the output voltage over input current depends only on resistances of the ERC, the sheet resistance, and the Hall angle, irrespective of the exact shape of the devices and the size of the contacts.Result:This allows one to explore the maximum Signal-to-Noise Ratio (SNR) in a very general sense without consideration of any specific device geometry. It is shown how VHalls with all three contacts on the top face of the Hall tub can have electrical symmetry with maximum SNR.

Geometry and Physics: Volume II

2018 ◽  
Keyword(s):  
Moduli Spaces ◽  
Mirror Symmetry ◽  
Geometric Analysis ◽  
Mathematical Physics ◽  
Poisson Geometry ◽  
Special Holonomy ◽  
Low Dimensional Topology ◽  
Generalized Complex Structures ◽  
Wide Range ◽  
Low Dimensional

These volumes contain the proceedings of the conference held at Aarhus, Oxford and Madrid in September 2016 to mark the seventieth birthday of Nigel Hitchin, one of the world’s foremost geometers and Savilian Professor of Geometry at Oxford. The proceedings contain twenty-nine articles, including three by Fields medallists (Donaldson, Mori and Yau). The articles cover a wide range of topics in geometry and mathematical physics, including the following: Riemannian geometry, geometric analysis, special holonomy, integrable systems, dynamical systems, generalized complex structures, symplectic and Poisson geometry, low-dimensional topology, algebraic geometry, moduli spaces, Higgs bundles, geometric Langlands programme, mirror symmetry and string theory. These volumes will be of interest to researchers and graduate students both in geometry and mathematical physics.

scholarly journals MoS2 Based Photodetectors: A Review

Sensors ◽  
2021 ◽  
Vol 21 (8) ◽  
pp. 2758
Author(s):  
Alberto Taffelli ◽  
Sandra Dirè ◽  
Alberto Quaranta ◽  
Lucio Pancheri
Keyword(s):  
Electric Fields ◽  
Spectral Range ◽  
Performance Metrics ◽  
Transition Metal Dichalcogenides ◽  
Visible Spectral Range ◽  
Detector Performance ◽  
Strong Light ◽  
Near Ultraviolet ◽  
Passivation Layers ◽  
Low Dimensional

Photodetectors based on transition metal dichalcogenides (TMDs) have been widely reported in the literature and molybdenum disulfide (MoS2) has been the most extensively explored for photodetection applications. The properties of MoS2, such as direct band gap transition in low dimensional structures, strong light–matter interaction and good carrier mobility, combined with the possibility of fabricating thin MoS2 films, have attracted interest for this material in the field of optoelectronics. In this work, MoS2-based photodetectors are reviewed in terms of their main performance metrics, namely responsivity, detectivity, response time and dark current. Although neat MoS2-based detectors already show remarkable characteristics in the visible spectral range, MoS2 can be advantageously coupled with other materials to further improve the detector performance Nanoparticles (NPs) and quantum dots (QDs) have been exploited in combination with MoS2 to boost the response of the devices in the near ultraviolet (NUV) and infrared (IR) spectral range. Moreover, heterostructures with different materials (e.g., other TMDs, Graphene) can speed up the response of the photodetectors through the creation of built-in electric fields and the faster transport of charge carriers. Finally, in order to enhance the stability of the devices, perovskites have been exploited both as passivation layers and as electron reservoirs.

scholarly journals Quantum information probes of charge fractionalization in large-N gauge theories

2021 ◽  
Vol 2021 (5) ◽  
Author(s):  
Brandon S. DiNunno ◽  
Niko Jokela ◽  
Juan F. Pedraza ◽  
Arttu Pönni
Keyword(s):  
Degrees Of Freedom ◽  
Gauge Theories ◽  
Entanglement Entropy ◽  
Coarse Grained ◽  
Strongly Coupled ◽  
Information Theoretic ◽  
Large N ◽  
Wide Range ◽  
Charge Fractionalization ◽  
Electric Flux

Abstract We study in detail various information theoretic quantities with the intent of distinguishing between different charged sectors in fractionalized states of large-N gauge theories. For concreteness, we focus on a simple holographic (2 + 1)-dimensional strongly coupled electron fluid whose charged states organize themselves into fractionalized and coherent patterns at sufficiently low temperatures. However, we expect that our results are quite generic and applicable to a wide range of systems, including non-holographic. The probes we consider include the entanglement entropy, mutual information, entanglement of purification and the butterfly velocity. The latter turns out to be particularly useful, given the universal connection between momentum and charge diffusion in the vicinity of a black hole horizon. The RT surfaces used to compute the above quantities, though, are largely insensitive to the electric flux in the bulk. To address this deficiency, we propose a generalized entanglement functional that is motivated through the Iyer-Wald formalism, applied to a gravity theory coupled to a U(1) gauge field. We argue that this functional gives rise to a coarse grained measure of entanglement in the boundary theory which is obtained by tracing over (part) of the fractionalized and cohesive charge degrees of freedom. Based on the above, we construct a candidate for an entropic c-function that accounts for the existence of bulk charges. We explore some of its general properties and their significance, and discuss how it can be used to efficiently account for charged degrees of freedom across different energy scales.

scholarly journals Pressure-induced Jahn-Teller Switch in the Homoleptic Hybrid Perovskite [(CH3)2NH2]Cu(HCOO)3: Orbital Reordering by Unconventional Degrees of Freedom

2021 ◽  
Author(s):  
Rebecca Scatena ◽  
Michał Andrzejewski ◽  
Roger D Johnson ◽  
Piero Macchi
Keyword(s):  
Phase Transition ◽  
High Pressure ◽  
Coordination Polymer ◽  
Degrees Of Freedom ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hybrid Perovskite ◽  
Jahn Teller

Through in-situ, high-pressure x-ray diffraction experiments we have shown that the homoleptic perovskite-like coordination polymer [(CH3)2NH2]Cu(HCOO)3 undergoes a pressure-induced orbital reordering phase transition above 5.20 GPa. This transition is distinct...

scholarly journals Spin-Mechanics with Nitrogen-Vacancy Centers and Trapped Particles

Micromachines ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 651
Author(s):  
Maxime Perdriat ◽  
Clément Pellet-Mary ◽  
Paul Huillery ◽  
Loïc Rondin ◽  
Gabriel Hétet
Keyword(s):  
Degrees Of Freedom ◽  
Theoretical Background ◽  
Nitrogen Vacancy ◽  
Full Potential ◽  
Strongly Coupled ◽  
Trapped Particles ◽  
Quantum Regime ◽  
Atomic Spins ◽  
Nitrogen Vacancy Centers ◽  
Mechanical Oscillators

Controlling the motion of macroscopic oscillators in the quantum regime has been the subject of intense research in recent decades. In this direction, opto-mechanical systems, where the motion of micro-objects is strongly coupled with laser light radiation pressure, have had tremendous success. In particular, the motion of levitating objects can be manipulated at the quantum level thanks to their very high isolation from the environment under ultra-low vacuum conditions. To enter the quantum regime, schemes using single long-lived atomic spins, such as the electronic spin of nitrogen-vacancy (NV) centers in diamond, coupled with levitating mechanical oscillators have been proposed. At the single spin level, they offer the formidable prospect of transferring the spins’ inherent quantum nature to the oscillators, with foreseeable far-reaching implications in quantum sensing and tests of quantum mechanics. Adding the spin degrees of freedom to the experimentalists’ toolbox would enable access to a very rich playground at the crossroads between condensed matter and atomic physics. We review recent experimental work in the field of spin-mechanics that employ the interaction between trapped particles and electronic spins in the solid state and discuss the challenges ahead. Our focus is on the theoretical background close to the current experiments, as well as on the experimental limits, that, once overcome, will enable these systems to unleash their full potential.

Dielectric Behavior of Mechano-chemically Synthesized [(CH3NH3)3Bi2Br9]: A Lead Free Hybrid Perovskite

2021 ◽  
Author(s):  
Swagatalaxmi Pujaru ◽  
Priyabrata Sadhukhan ◽  
Basudev Ghosh ◽  
Arup Dhara ◽  
Sachindranath Das
Keyword(s):  
Impedance Spectroscopy ◽  
Complex Impedance ◽  
Negative Temperature ◽  
Dielectric Behavior ◽  
Lead Free ◽  
Published Data ◽  
Temperature Dependent ◽  
Microstructural Parameters ◽  
Hybrid Perovskite ◽  
Refinement Method

Abstract Lead free hybrid halide perovskite (CH3NH3)3Bi2Br9 has been successfully synthesized by mechano-chemical method. The microstructure analysis by Rietveld’s refinement method revealed that the crystal belongs to trigonal system with space group P3 ̅m1. The obtained microstructural parameters are well in agreement with the previously published data. Temperature-dependent ac conductivity, impedance spectroscopy, and complex dielectric properties have been investigated in detail. The negative temperature coefficient of resistance behaviour reveals the semiconducting nature of the materials. The complex impedance spectroscopy also supports the semiconducting nature of the sample with activation energy for conduction ~0.38 eV.

scholarly journals Optimizing the structure and movement of a robotic bat with biological kinematic synergies

2018 ◽  
Vol 37 (10) ◽  
pp. 1233-1252 ◽  
Author(s):  
Jonathan Hoff ◽  
Alireza Ramezani ◽  
Soon-Jo Chung ◽  
Seth Hutchinson
Keyword(s):  
Principal Component Analysis ◽  
Topological Structure ◽  
Degrees Of Freedom ◽  
Dimensional Space ◽  
Principal Component ◽  
Biologically Inspired ◽  
Wing Kinematics ◽  
Wing Motion ◽  
Kinematic Synergies ◽  
Low Dimensional

In this article, we present methods to optimize the design and flight characteristics of a biologically inspired bat-like robot. In previous, work we have designed the topological structure for the wing kinematics of this robot; here we present methods to optimize the geometry of this structure, and to compute actuator trajectories such that its wingbeat pattern closely matches biological counterparts. Our approach is motivated by recent studies on biological bat flight that have shown that the salient aspects of wing motion can be accurately represented in a low-dimensional space. Although bats have over 40 degrees of freedom (DoFs), our robot possesses several biologically meaningful morphing specializations. We use principal component analysis (PCA) to characterize the two most dominant modes of biological bat flight kinematics, and we optimize our robot’s parametric kinematics to mimic these. The method yields a robot that is reduced from five degrees of actuation (DoAs) to just three, and that actively folds its wings within a wingbeat period. As a result of mimicking synergies, the robot produces an average net lift improvesment of 89% over the same robot when its wings cannot fold.

Temperature-dependent neutron powder diffraction evidence for splitting of the cationic sites in ferroelectric PbHf0.4Ti0.6O3

1999 ◽  
Vol 55 (1) ◽  
pp. 8-16 ◽  
Author(s):  
C. Muller ◽  
J.-L. Baudour ◽  
V. Madigou ◽  
F. Bouree ◽  
J.-M. Kiat ◽  
...  
Keyword(s):  
Powder Diffraction ◽  
Paraelectric Phase ◽  
Neutron Powder Diffraction ◽  
Cubic Phase ◽  
Temperature Dependent ◽  
Paraelectric Phase Transition ◽  
Type Method ◽  
Space Group ◽  
Atomic Displacements ◽  
The Mean

Temperature-dependent neutron powder diffraction experiments (diffractometer 3T2-LLB, Saclay, France, λ = 1.227 Å) have been performed on the perovskite-like lead hafnate titanate PbHf0.4Ti0.6O3. This compound belongs to the solid solution denoted PHT, which derives from the well known ferroelectric PZT series. It exhibits a ferroelectric-to-paraelectric phase transition around 620 K, between the low-temperature tetragonal phase and the high-temperature cubic phase. The tetragonal structure of the ferroelectric phase has been refined at 10 and 300 K using a Rietveld-type method: space group P4mm with Z = 1; at = 3.999 (1), ct = 4.120 (1) Å, c/a = 1.030, V = 65.89 Å3 at 10 K; at = 4.012 (1) and ct = 4.100 (1) Å, c/a = 1.022, V = 65.99 Å3 at 300 K. The cubic structure of the paraelectric phase has also been refined at 720 K: space group Pm3¯m, Z = 1, ac = 4.046 (1) Å, V = 66.23 Å3. Cation displacements and oxygen-octahedra elongations have been observed as a function of temperature. Evidence for peculiar behaviour associated with the relative shifts of the Hf and Ti atoms (thought until now to be on the same crystallographic site) was found through an anomaly of the mean-square atomic displacements of the Hf/Ti pseudo-nucleus. The PDF Nos for PbHf0.4Ti0.6O3 are 48-49-9 and 48-49-10.

scholarly journals Design and Analysis of a 1D Actively Stabilized System with Viscoelastic Damping Support

Actuators ◽  
2019 ◽  
Vol 8 (2) ◽  
pp. 33
Author(s):  
Josef Passenbrunner ◽  
Gerald Jungmayr ◽  
Wolfgang Amrhein
Keyword(s):  
Degrees Of Freedom ◽  
Nonlinear Behavior ◽  
Axial Rotation ◽  
Test System ◽  
Axial Position ◽  
Viscoelastic Damping ◽  
Temperature Dependent ◽  
Temperature Dependent Properties ◽  
Rotor Dynamic ◽  
Damping Capability

Passively magnetically stabilized degrees of freedom yield the benefit of reduced complexity and therefore costs. However, the application of passive magnetic bearings (PMBs) also features some drawbacks. The poor damping capability leads to exaggerated deflection amplitudes when passing the resonance speeds of the applied system. This results in the necessity of external damping. Complying with the goal of costs and complexity, viscoelastic materials offer a suitable solution. However, these materials show high frequency and temperature dependent properties which induce the necessity of a proper model. Thus, the design of systems, as presented in this paper, requires accurate modeling of the dynamic behavior including the nonlinear characteristic of damping elements to predict the system displacements. In the investigated setup only two degrees of freedom remain to be controlled actively. These are the axial rotation and the axial position of the rotor which are controlled by the motor and an active magnetic axial bearing (AMB). This article focuses on the rotor dynamic modeling of a radial passively magnetically stabilized system especially considering the nonlinear behavior of viscoelastic damping elements. Finally, the results from the analytic model are verified by measurements on a manufactures test system.

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