Detrital zircon geochronology and provenance of Devono-Mississippian strata in the northern Canadian Cordilleran miogeoclineThis article is one of a series of papers published in this Special Issue on the theme of Geochronology in honour of Tom Krogh.Northwest Territories Geoscience Office Contribution 0047. Geological Survey of Canada Contribution 20100432.

2011 ◽  
Vol 48 (2) ◽  
pp. 515-541 ◽  
Author(s):  
Yvon Lemieux ◽  
Thomas Hadlari ◽  
Antonio Simonetti

U–Pb ages have been determined on detrital zircons from the Upper Devonian Imperial Formation and Upper Devonian – Lower Carboniferous Tuttle Formation of the northern Canadian Cordilleran miogeocline using laser ablation – multicollector – inductively coupled plasma – mass spectrometry. The results provide insights into mid-Paleozoic sediment dispersal in, and paleogeography of, the northern Canadian Cordillera. The Imperial Formation yielded a wide range of detrital zircon dates; one sample yielded dominant peaks at 1130, 1660, and 1860 Ma, with smaller mid-Paleozoic (∼430 Ma), Neoproterozoic, and Archean populations. The easternmost Imperial Formation sample yielded predominantly late Neoproterozoic – Cambrian zircons between 500 and 700 Ma, with lesser Mesoproterozoic and older populations. The age spectra suggest that the samples were largely derived from an extensive region of northwestern Laurentia, including the Canadian Shield, igneous and sedimentary provinces of Canada’s Arctic Islands, and possibly the northern Yukon. The presence of late Neoproterozoic – Cambrian zircon, absent from the Laurentian magmatic record, indicate that a number of grains were likely derived from an exotic source region, possibly including Baltica, Siberia, or Arctic Alaska – Chukotka. In contrast, zircon grains from the Tuttle Formation show a well-defined middle Paleoproterozoic population with dominant relative probability peaks between 1850 and 1950 Ma. Additional populations in the Tuttle Formation are mid-Paleozoic (∼430 Ma), Mesoproterozoic (1000–1600 Ma), and earlier Paleoproterozoic and Archean ages (>2000 Ma). These data lend support to the hypothesis that the influx of sediments of northerly derivation that supplied the northern miogeocline in Late Devonian time underwent an abrupt shift to a source of predominantly Laurentian affinity by the Mississippian.

2007 ◽  
Vol 44 (12) ◽  
pp. 1675-1693 ◽  
Author(s):  
Y Lemieux ◽  
R I Thompson ◽  
P Erdmer ◽  
A Simonetti ◽  
R A Creaser

The Kootenay Arc has been interpreted as the western limit of autochthonous continental margin strata, west of which occur Paleozoic to Mesozoic rocks of uncertain paleogeographic origin. Recent mapping has demonstrated stratigraphic linkage between the Kootenay Arc strata and rocks farther west. A U–Pb study of detrital zircons using laser ablation – multicollector – inductively coupled plasma – mass spectrometry (LA–MC–ICP–MS) was undertaken in the upper succession of the Monashee complex mantling gneiss and in mid-Paleozoic strata of the Chase Formation exposed in the northern Kootenay Arc area and adjacent outboard strata. The predominance of >1.75 Ga zircon matches well with basement domains of the western buried North American craton and indicates that most of the grains were derived from a source of North American affinity. Zircon between 1.00 and 1.30 Ga demonstrates a Neoproterozoic source of possible “Grenville” affinity. Additional populations in the Chase Formation are mid-Paleozoic, Ediacaran, 800–1000 Ma, and 1400–1750 Ma. We interpret them to have been derived from exposed sources of Proterozoic continental crust and (or) proximal late Neoproterozoic and middle Paleozoic magmatic sources. The investigated Proterozoic and Paleozoic successions confirm sedimentologic and depositional relationships with the ancestral North American margin, and as such are interpreted to represent outboard extensions of the Cordilleran miogeoclinal succession.


2017 ◽  
Vol 54 (2) ◽  
pp. 69-85 ◽  
Author(s):  
David Malone ◽  
John Craddock ◽  
Kacey Garber ◽  
Jarek Trela

The Aycross Formation is the basal unit of the Absaroka Volcanic Supergroup in the southern Absaroka Range and consists of volcanic sandstone, mudstone, breccia, tuff and conglomerate. The Aycross was deposited during the waning stages of the Laramide Orogeny and the earliest phases of volcanism in the Absaroka Range. U-Pb geo-chronology using laser ablation multicollector inductively coupled plasma mass spectrometry LA-ICP-MS was performed on detrital zircons collected from an Aycross sandstone bed at Falls Campground east of Togwotee Pass. The detrital zircon age spectrum ranged fom ca 47 to 2856 Ma. Peak ages, as indicated by the zircon age probability density plot are ca. 51, 61, and 72 Ma. Tertiary zircons were the most numerous (n = 32), accounting for 42% of the zircon ages spectrum. Of these 19 are Eocene, and 13 are Paleocene, which are unusual ages in the Wyoming-Idaho-Montana area. Mesozoic zircons (n = 21) comprise 27% of the age spectrum and range in age from 68–126 Ma; all but one being late Cretaceous in age. No Paleozoic zircons are present. Proterozoic zircons range in age from 1196–2483 Ma, and also consist of 27% of the age spectrum. The maximum depositional age of the Aycross Formation is estimated to be 50.05 +/− 0.65 Ma based on weighted mean of the eight youngest grains. The Aycross Formation detrital zircon age spectrum is distinct from that of other 49–50 Ma rocks in northwest Wyoming, which include the Hominy Peak and Wapiti Formations and Crandall Conglomerate. The Aycross must have been derived largely from distal westerly source areas, which include the late Cretaceous and Paleocene Bitteroot Lobe of the Idaho Batholith. In contrast, the middle Eocene units further to the north must have been derived from erosion of the Archean basement-cored uplift of the Laramide Foreland in southwest Montana.


2016 ◽  
Vol 53 (3) ◽  
pp. 219-230 ◽  
Author(s):  
Xiao Ma ◽  
Kunguang Yang ◽  
Xuegang Li ◽  
Chuangu Dai ◽  
Hui Zhang ◽  
...  

The Jiangnan Orogeny generated regional angular unconformities between the Xiajiang Group and the underlying Sibao Group in the western Jiangnan Orogen along the southeastern margin of the Yangtze Block in southeast Guizhou, South China. Laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) U–Pb zircon dating of two samples of the Motianling granitic pluton yielded U–Pb zircon ages of 826.2 ± 3.4 and 825.5 ± 6.1 Ma, with an average age of 825.6 ± 3.0 Ma, which is considered the minimum depositional age of the Sibao Group. The U–Pb ages of the youngest detrital zircon grains from the Sibao Group and the Xiajiang Group yielded average ages of 834.9 ± 3.8 and 794.6 ± 4.2 Ma, respectively. The depositional age of the Sibao Group can be constrained at 825–835 Ma, and deposition of the Xiajiang Group did not begin before ca. 800 Ma. These results suggest that the Jiangnan Orogeny, which led to the assembly of the Yangtze and Cathaysia blocks, ended at 795–835 Ma on the western segment of the Jiangnan Orogen. The detrital zircon distribution spectrums of the Sibao and Xiajiang groups suggest a provenance from Neoproterozoic basement sedimentary sequences along with a mixture of local Neoproterozoic subduction-related felsic granitoids, distant plutons from the western Yangtze Block and eastern Jiangnan Orogen, and recycled materials from the interior of the Yangtze Block. By comparing the basin evolution histories and magmatic and metamorphic events along the continental margins of the Rodinia supercontinent, it is proposed that the South China Block might have been located at the periphery, adjacent to North India and East Antarctica, rather than in the interior of Rodinia in Neoproterozoic time.


2011 ◽  
Vol 149 (3) ◽  
pp. 443-458 ◽  
Author(s):  
ELIŠKA ŽÁČKOVÁ ◽  
JIŘÍ KONOPÁSEK ◽  
JAN KOŠLER ◽  
PETR JEŘÁBEK

AbstractAge spectra of detrital zircons from metamorphosed quartzites of the Krkonoše–Jizera Massif in the northeastern part of the Saxothuringian Domain were obtained by U–Pb laser ablation inductively coupled plasma mass spectrometry dating. The zircon ages cluster in the intervals of 450–530 Ma and 550–670 Ma, and show individual data between 1.6 and 3.1 Ga. Zircons in the analysed samples are predominantly of Cambrian–Ordovician and Neoproterozoic age, and the marked peak at c. 525–500 Ma suggests a late Cambrian maximum age for the sedimentary protolith. Detritus of the quartzites probably originated from the erosion of Cambrian–Ordovician granitoids and their Neoproterozoic (meta)sedimentary or magmatic country rocks. The lack of Neoproterozoic (meta)sedimentary rocks in the central and eastern part of the Krkonoše–Jizera Massif suggests that the country rocks to voluminous Cambrian–Ordovician magmatic bodies were largely eroded during the formation of early Palaeozoic rift basins along the southeast passive margin of the Saxothuringian Domain. The detrital zircon age spectra confirm the previous interpretation that the exposed basement, dominated by Neoproterozoic to Cambrian–Ordovician granitoids, was overthrust during Devonian–Carboniferous subduction–collision processes by nappes composed of metamorphosed equivalents of the uppermost Cambrian–Devonian passive margin sedimentary formations. Only a negligible number of Mesoproterozoic ages, typically from the Grenvillian event, supports the interpretation that the Saxothuringian Neoproterozoic basement has an affinity to the West African Craton of the northwestern margin of Gondwana.


2021 ◽  
Author(s):  
Jiaopeng Sun ◽  
et al.

Table S1: Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) data of detrital zircons from Carboniferous and Permian sandstones from the East Kunlun–Qaidam area; Table S2: Compilation of detrital zircon U–Pb ages used for comparison in Figure 12 from the East Kunlun–Qaidam area and its vicinity.


2021 ◽  
Author(s):  
Jiaopeng Sun ◽  
et al.

Table S1: Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) data of detrital zircons from Carboniferous and Permian sandstones from the East Kunlun–Qaidam area; Table S2: Compilation of detrital zircon U–Pb ages used for comparison in Figure 12 from the East Kunlun–Qaidam area and its vicinity.


2015 ◽  
Vol 153 (3) ◽  
pp. 460-486 ◽  
Author(s):  
CLARISA VORSTER ◽  
JAN KRAMERS ◽  
NIC BEUKES ◽  
HERMAN VAN NIEKERK

AbstractThe Natal Group and Msikaba Formation remain relatively poorly understood with regards to their provenance and relative age of deposition; a much-needed geochronological study of the detrital zircons from these two units was therefore undertaken. Five samples of the Durban and Mariannhill Formations (Natal Group) and the Msikaba Formation (Cape Supergroup) were obtained. A total of 882 concordant U–Pb ages of detrital zircon populations from these units were determined by means of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Major Neoproterozoic and secondary Mesoproterozoic detrital zircon age populations are present in the detrital zircon content of all the samples. Smaller contributions from Archean-, Palaeoproterozoic-, Cambrian- and Ordovician-aged grains are also present. Due to the presence of a prominent major population of 800–1000 Ma zircons in all the samples, late Stenian – Tonian ancient volcanic arc complexes overprinted by Pan-African metamorphism of Mozambique, Malawi and Zambia, along with areas of similar age within Antarctica, India and Sri Lanka, are suggested as major sources of detritus. The Namaqua–Natal Metamorphic Complex is suggested as a possible source of minor late Mesoproterozoic-aged detritus. Minor populations of Archean and Palaeoproterozoic zircons were likely sourced from the Kaapvaal and Grunehogna Cratons. Post-orogenic Cambrian – Lower Ordovician granitoids of the Mozambique Belt (Mozambique) and the Maud Belt (Antarctica) made lesser contributions. In view of the apparent broad similarity of source areas for the Natal Group and Msikaba Formation, their sedimentation occurred in parts of the same large and evolving basin rather than localized in small continental basins, and the current exposures merely represent small erosional relicts.


2020 ◽  
Vol 16 ◽  
Author(s):  
Diogo L. R. Novo ◽  
Priscila T. Scaglioni ◽  
Rodrigo M. Pereira ◽  
Filipe S. Rondan ◽  
Gilberto S. Coelho Junior ◽  
...  

Background: Conventional analytical methods for phosphorus and sulfur determination in several matrices present normally analytical challenges regarding inaccuracy, detectability and waste generation. Objective: The main objective is proposing a green and feasible analytical method for phosphorus and sulfur determination in animal feed. Methods: Synergic effect between microwave and ultraviolet radiations during sample preparation was evaluated for the first time for the animal feed digestion associated with further phosphorus and sulfur determination by ion chromatography with conductivity detection. Dissolved carbon and residual acidity in final digests were used for the proposed method assessment. Phosphorus and sulfur values were compared with those obtained using conventional microwave-assisted wet digestion in closed vessels associated with inductively coupled plasma optical emission spectrometry and with those obtained using Association of Official Analytical Chemists International official method. Recovery tests and certified reference material analysis were performed. Animal feeds were analyzed using the proposed method. Results: Sample masses of 500 mg were efficiently digested using only 2 mol L -1 HNO3. The results obtained by the proposed method was not differing significantly (p > 0.05) from those obtained by the conventional and official methods. Suitable recoveries (from 94 to 99%), agreement with certified values (101 and 104%) and relative standard deviations (< 8%) were achieved. Phosphorus and sulfur content in commercial products varied in a wide range (P: 5,873 to 28,387 mg kg-1 and S: 2,165 to 4,501 mg kg-1 ). Conclusion: The proposed method is a green, safe, accurate, precise and sensitive alternative for animal feed quality control.


Micromachines ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 89
Author(s):  
Jongwon Lee ◽  
Kilsun Roh ◽  
Sung-Kyu Lim ◽  
Youngsu Kim

This is the first demonstration of sidewall slope control of InP via holes with an etch depth of more than 10 μm for 3D integration. The process for the InP via holes utilizes a common SiO2 layer as an InP etch mask and conventional inductively coupled plasma (ICP) etcher operated at room temperature and simple gas mixtures of Cl2/Ar for InP dry etch. Sidewall slope of InP via holes is controlled within the range of 80 to 90 degrees by changing the ICP power in the ICP etcher and adopting a dry-etched SiO2 layer with a sidewall slope of 70 degrees. Furthermore, the sidewall slope control of the InP via holes in a wide range of 36 to 69 degrees is possible by changing the RF power in the etcher and introducing a wet-etched SiO2 layer with a small sidewall slope of 2 degrees; this wide slope control is due to the change of InP-to-SiO2 selectivity with RF power.


2021 ◽  
Vol 9 (2) ◽  
pp. 336
Author(s):  
Laura Matarredona ◽  
Mónica Camacho ◽  
Basilio Zafrilla ◽  
Gloria Bravo-Barrales ◽  
Julia Esclapez ◽  
...  

Haloarchaea can survive and thrive under exposure to a wide range of extreme environmental factors, which represents a potential interest to biotechnology. Growth responses to different stressful conditions were examined in the haloarchaeon Haloferax mediterranei R4. It has been demonstrated that this halophilic archaeon is able to grow between 10 and 32.5% (w/v) of sea water, at 32–52 °C, although it is expected to grow in temperatures lower than 32 °C, and between 5.75 and 8.75 of pH. Moreover, it can also grow under high metal concentrations (nickel, lithium, cobalt, arsenic), which are toxic to most living beings, making it a promising candidate for future biotechnological purposes and industrial applications. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) analysis quantified the intracellular ion concentrations of these four metals in Hfx. mediterranei, concluding that this haloarchaeon can accumulate Li+, Co2+, As5+, and Ni2+ within the cell. This paper is the first report on Hfx. mediterranei in which multiple stress conditions have been studied to explore the mechanism of stress resistance. It constitutes the most detailed study in Haloarchaea, and, as a consequence, new biotechnological and industrial applications have emerged.


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