THE EFFECT OF ORIENTATION AND IMPURITIES ON THE MECHANICAL PROPERTIES OF MOLYBDENUM SINGLE CRYSTALS

1967 ◽  
Vol 45 (2) ◽  
pp. 1063-1074 ◽  
Author(s):  
D. F. Stein

Molybdenum single crystals containing less than 10 p.p.m. of carbon, 5 p.p.m. of nitrogen, and 5 p.p.m. of oxygen have been prepared by zone melting and hydrogen gas purification. The mechanical properties of the crystals have been measured in tension and compression over a range of temperature from 20 to 298 °K. It was found that the critical resolved shear stress and the temperature dependence of the critical resolved shear stress decreased with increasing purity. It was found that at all test temperatures the CRSS law fails. The critical resolved shear stress is a minimum in the (100) tension axis orientation and reaches a maximum with the tensile axis along the (110)(111) line of the stereographic triangle. It was also found that the ductility of molybdenum single crystals was not improved by purification.

2013 ◽  
Vol 1516 ◽  
pp. 243-248
Author(s):  
Yoshisato Kimura ◽  
Masato Kawakita ◽  
Hiroyasu Yuyama ◽  
Yaw-Wang Chai

ABSTRACTSingle crystals of E21 (L12) Ni3AlC1-x were prepared by the unidirectional solidification using the optical floating zone melting method to determine their mechanical properties. Particularly the effects of interstitial carbon atoms on mechanical properties were evaluated by compression tests at room temperature. Operative slip system of E21 Ni3AlC is {111}<011> type which is the same as that of L12 Ni3Al. Strength of Ni3AlC single crystals increases with carbon concentration due to the solid solution effect, though the stress relief of yielding behavior is enhanced at the intermediate carbon content at around 3at%. A large gap appears in the carbon concentration dependence of critical resolved shear stress (as well as yield stress) at almost the same carbon content. This discontinuity in strengthening is attributed to the interaction between multiple solute carbon atoms and mobile dislocations.


2018 ◽  
Vol 941 ◽  
pp. 1360-1365 ◽  
Author(s):  
Ryota Morioka ◽  
Ken Cho ◽  
Hiroyuki Y. Yasuda

In this study, to clarify the effects of Mo addition on deformation behavior of Ti-Mn alloys, the mechanical properties and the deformation structures of the alloys were investigated using Ti-Mn and Ti-Mn-Mo alloys polycrystals and single crystals. We found that the elongation of Ti-Mn alloys are improved from approximately 5% to 30% by Mo addition, with maintaining ultimate tensile strength of 900 MPa. The excellent strength-ductility balance of Ti-Mn-Mo alloys is caused by {332}<113> twinning, which is unique twinning for metastable β-type titanium alloys. Additionally, the deformation behavior of Ti-Mn and Ti-Mn-Mo alloys was investigated in detail by using single crystals focusing on a critical resolved shear stress (CRSS). As a result, we found for the first time that CRSS for {332}<113> twinning in Ti-Mn-Mo alloy was lower than that in Ti-Mn alloy. Moreover, in Ti-Mn-Mo alloy, CRSS for {332}<113> twinning was lower than that for {112}<111> slip. These results suggest that CRSS for {332}<113> twinning in Ti-Mn alloys is decreased by Mo addition.


RSC Advances ◽  
2021 ◽  
Vol 11 (38) ◽  
pp. 23719-23724
Author(s):  
Md. Lokman Ali

The effect of transition-metals (TM) addition on the mechanical properties of CrCoNi medium entropy alloys (MEAs) was investigated.


2010 ◽  
Vol 662 ◽  
pp. 85-93
Author(s):  
Sergey Dub ◽  
Igor Zasimchuk ◽  
Leonid Matvienko

Mechanical properties of (001) Mo and (001) Mo – 1.5 at.% Ir single crystals have been studied by nanoindentation. It has been found that the iridium addition to molybdenum leads to an increase in both hardness and elastic modulus. An abrupt elasto-plastic transition (pop-in) at a depth of about 20 - 40 nm caused by dislocation nucleation in previously dislocation-free volume has been observed in the initial portion of the loading curve. It has shown that the Ir addition essentially affects the dislocation nucleation. Mean shear stress required for the dislocation nucleation increased from 10.8 GPa (G/12) for a Mo single crystal to 18.2 GPa (G/8) for the Mo – 1.5 at% Ir solid solution. Thus, the Ir solution in a Mo single crystal affects not only the resistance to the motion of dislocations (hardness) but the nucleation of them as well. The latter is likely to occur as a result of an increase in the structure perfection of the Mo – 1.5 at% Ir solid solution as compared to the pure Mo single crystal.


2007 ◽  
Vol 561-565 ◽  
pp. 459-462
Author(s):  
Katsushi Tanaka ◽  
Hiromitsu Ide ◽  
Yoshinori Sumi ◽  
Kyosuke Kishida ◽  
Haruyuki Inui

Compressive deformation of L10-ordered single crystals of FePd whose c/a ratio less than unity have been investigated from room temperature to 823 K. The results show that the critical resolved shear stress (CRSS) for octahedral glide of ordinary dislocations is smaller than that of super-lattice dislocations in all the temperature range investigated, that is the opposite sense to the case of Ti-56 mol% Al. The CRSS for ordinary dislocations virtually independent to the temperature. On the other hand, the CRSS for super dislocations exhibits a weak positive temperature dependence from room temperature up to 573 K and decreases in higher temperatures.


1990 ◽  
Vol 213 ◽  
Author(s):  
R.D. Field ◽  
D.F. Lahrman ◽  
R. Darolia

ABSTRACTA detailed study of deformation of NiAl single crystals in two soft orientations, <110> and <111>, has been conducted. The Schmid factor favors {100} slip in the former and {110} slip in the latter. Detailed dislocation analysis, critical resolved shear stress measurements, and slip trace analysis have been performed to determine the nature of dislocation motion and interactions in this material. Particular attention is given to prismatic loops formed during deformation, since the shapes of these loops reveal the active slip planes. Similar loop morphologies observed in elevated temperature [001] oriented tensile specimens are also discussed.


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