The Effect of Solid Solution Impurities on Dislocation Nucleation in a (001) Mo – 1.5 at.% Ir Single Crystal

2010 ◽  
Vol 662 ◽  
pp. 85-93
Author(s):  
Sergey Dub ◽  
Igor Zasimchuk ◽  
Leonid Matvienko
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Shear Stress ◽  
Elastic Modulus ◽  
Single Crystal ◽  
Single Crystals ◽  
Free Volume ◽  
Dislocation Nucleation ◽  
Initial Portion ◽  
G 12

Mechanical properties of (001) Mo and (001) Mo – 1.5 at.% Ir single crystals have been studied by nanoindentation. It has been found that the iridium addition to molybdenum leads to an increase in both hardness and elastic modulus. An abrupt elasto-plastic transition (pop-in) at a depth of about 20 - 40 nm caused by dislocation nucleation in previously dislocation-free volume has been observed in the initial portion of the loading curve. It has shown that the Ir addition essentially affects the dislocation nucleation. Mean shear stress required for the dislocation nucleation increased from 10.8 GPa (G/12) for a Mo single crystal to 18.2 GPa (G/8) for the Mo – 1.5 at% Ir solid solution. Thus, the Ir solution in a Mo single crystal affects not only the resistance to the motion of dislocations (hardness) but the nucleation of them as well. The latter is likely to occur as a result of an increase in the structure perfection of the Mo – 1.5 at% Ir solid solution as compared to the pure Mo single crystal.

scholarly journals The Stress Induced Martensite-Austenite Interface in Fe-15Ni-15Cr Single Crystals

1973 ◽  
Vol 31 ◽  
pp. 110-111
Author(s):  
G. A. Stone ◽  
G. Thomas
Keyword(s):  
Shear Stress ◽  
Slip System ◽  
Single Crystal ◽  
Single Crystals ◽  
Habit Plane ◽  
Maximum Shear Stress ◽  
Crystal Axis ◽  
Surface Study

A single crystal stressed in the [3]𝛄 direction at 185°K was transformed to 5% 𝛂 martensite and 2% Ɛ martensite by volume. The austenite slip system of maximum shear stress is the (11)𝛄 [01)𝛄. Fig. 1 shows a two surface study using the electron and optical microscopes. The a martensite is confined between £martensite plates with the (0001)Ɛ ∥ (11)𝛄. The size of the acicular martensite crystals is controlled by the spacing of the £ martensite plates. These £ martensite plates are seen in Fig. 1A as dark vertical bands. The axes of the acicular crystals lie in the (11)𝛄 plane. The £ martensite habit plane is defined as the plane perpendicular to the (11)𝛄 containing the vector defining the crystal axis.

Influences of the γ′ Phase on the Mechanical Properties of a Nickel-Based Single Crystal Superalloy

2021 ◽  
Vol 1023 ◽  
pp. 45-52
Author(s):  
Xiao Yan Wang ◽  
Meng Li ◽  
Zhi Xun Wen
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Single Crystal ◽  
Tensile Properties ◽  
Room Temperature ◽  
Solution Treatment ◽  
Single Crystal Superalloy ◽  
Original Material ◽  
Solid Solution Treatment ◽  
The Matrix

After solid solution treatment at 1335°C for 4 hours and cooling to room temperature at different rate, the nickel-based single crystal superalloy were made into three kinds of nickel-based single crystal superalloy materials containing different size γ′ phases, respectively. The tensile test of I-shaped specimens was carried out at 980°C, and their effect of γ′ phase microstructure on the tensile properties was studied. The results show that the yielding strength of the material air-cooled to room temperature was lower than that with cooling rate at 0.15°C/s, but both of them were lower than the yielding strength of original material. Little difference was found on the elastic modulus of I-shaped specimens made of three kinds of materials. When the cubic degree of the γ′ phase is higher and the size is larger, the tensile properties of the material is better, which can be attributed to the larger size and narrower channel of the matrix phase that lead to higher dislocation resistance.

scholarly journals The critical shear stress of mercury single crystals

1937 ◽  
Vol 163 (912) ◽  
pp. 34-53 ◽  
Keyword(s):  
Plastic Deformation ◽  
Shear Stress ◽  
Melting Point ◽  
Single Crystal ◽  
Single Crystals ◽  
Critical Shear Stress ◽  
Impurity Content ◽  
Thermal Agitation ◽  
Plastic Yield ◽  
Metal Single Crystals

The influence of very small quantities of impurity on the critical shear stress of metal single crystals has an important bearing on the mechanism of their plastic deformation. For investigations in this field, mercury is a very suitable metal: its impurity content can easily be reduced to an extremely low level (Hulett 1911) and it contains no dissolved gases (Hulett 1911). Also, as first pointed out by Andrade (1914), single crystal wires of this metal can be prepared without difficulty. The low melting point of mercury (-38∙8° C.) is far from being a disadvantage. The crystals can be maintained at -60° C., and at a temperature so near the melting point the thermal agitation may be expected to accentuate phenomena not observable at lower temperatures, if such agitation plays the important part in the mechanism of glide ascribed to it (Taylor 1934; Polanyi 1934; Orowan 1934). As a possible instance of this, the experiments to be described have revealed the existence of a preliminary “set” preceding the true plastic yield. Widely differing forms of slip band have also been observed, and are described elsewhere (Greenland 1937). It is hoped that these results will throw further light on the mechanism of glide.

Micro pulling down growth of very thin shape memory alloys single crystals

2017 ◽  
Vol 10 (01) ◽  
pp. 1740003 ◽  
Author(s):  
I. López-Ferreño ◽  
J. San Juan ◽  
T. Breczewski ◽  
G. A. López ◽  
M. L. Nó
Keyword(s):  
Mechanical Properties ◽  
Shape Memory Alloys ◽  
Single Crystal ◽  
Shape Memory ◽  
Single Crystals ◽  
Functional Materials ◽  
Small Scale ◽  
Cylindrical Shape ◽  
Minimum Diameter ◽  
Wide Range

Shape memory alloys (SMAs) have attracted much attention in the last decades due to their thermo-mechanical properties such as superelasticity and shape memory effect. Among the different families of SMAs, Cu–Al–Ni alloys exhibit these properties in a wide range of temperatures including the temperature range of 100–200[Formula: see text]C, where there is a technological demand of these functional materials, and exhibit excellent behavior at small scale making them more competitive for applications in Micro Electro-Mechanical Systems (MEMS). However, polycrystalline alloys of Cu-based SMAs are very brittle so that they show their best thermo-mechanical properties in single-crystal state. Nowadays, conventional Bridgman and Czochralski methods are being applied to elaborate single-crystal rods up to a minimum diameter of 1[Formula: see text]mm, but no works have been reported for smaller diameters. With the aim of synthesizing very thin single-crystals, the Micro-Pulling Down ([Formula: see text]-PD) technique has been applied, for which the capillarity and surface tension between crucible and the melt play a critical role. The [Formula: see text]-PD method has been successfully applied to elaborate several cylindrical shape thin single-crystals down to 200[Formula: see text][Formula: see text]m in diameter. Finally, the martensitic transformation, which is responsible for the shape memory properties of these alloys, has been characterized for different single-crystals. The experimental results evidence the good quality of the grown single-crystals.

Length Scale Effects in Materials Deformation of Nano and Microscale Au Structures

2009 ◽  
Author(s):  
Jie Lian ◽  
Junlan Wang
Keyword(s):  
Mechanical Properties ◽  
Elastic Modulus ◽  
Size Effect ◽  
Sample Size ◽  
Atomistic Simulation ◽  
Scale Effects ◽  
Elastic Recovery ◽  
Boundary Effect ◽  
Dislocation Nucleation ◽  
Atomistic Simulations

In this study, intrinsic size effect — strong size dependence of mechanical properties — in materials deformation was investigated by performing atomistic simulation of compression on Au (114) pyramids. Sample boundary effect — inaccurate measurement of mechanical properties when sample size is comparable to the indent size — in nanoindentation was also investigated by performing experiments and atomistic simulations of nanoindentation into nano- and micro-scale Au pillars and bulk Au (001) surfaces. For intrinsic size effect, dislocation nucleation and motions that contribute to size effect were analyzed for studying the materials deformation mechanisms. For sample boundary effect, in both experiments and atomistic simulation, the elastic modulus decreases with increasing indent size over sample size ratio. Significantly different dislocation motions contribute to the lower value of the elastic modulus measured in the pillar indentation. The presence of the free surface would allow the dislocations to annihilate, causing a higher elastic recovery during the unloading of pillar indentation.

Pseudoelasticity in High Strengthening Fcc Single Crystals

1996 ◽  
Vol 459 ◽  
Author(s):  
Yu.I. Chumlyakov ◽  
I. V. Kireeva ◽  
G. S. Kapasova ◽  
E. I. Litvinova
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Single Crystals ◽  
Stress Level ◽  
Deformation Mechanism ◽  
Crystal Orientation ◽  
Dispersion Hardening ◽  
Solid Solution Strengthening ◽  
Solution Strengthening ◽  
Applied Stresses

ABSTRACTIt was experimentally shown that the achievement of a high deforming stress level due to dispersion hardening and solid solution strengthening of FCC single crystals with a low stacking-fault energy leads to the deformation mechanism changing from slip to twinning, the dependence of mechanical properties on a crystal orientation and a sign of applied stresses. During deformation by twinning at T<150–300K effects of pseudoelasticity associated with elastic twinning is observed.

Switching Current in Pb(Zn1/3Nb2/3)O3-PbTiO3 Single Crystals

1999 ◽  
Vol 604 ◽  
Author(s):  
Uma Belegundu ◽  
Xiaohong Du ◽  
Kenji Uchino
Keyword(s):  
Solid Solution ◽  
Barium Titanate ◽  
Single Crystal ◽  
Single Crystals ◽  
Applied Field ◽  
Exponential Dependence ◽  
Polarization Reversal ◽  
Switching Current ◽  
Linear Fit ◽  
Two Phases

AbstractSwitching current measurements have been carried out on relaxorferroelectric single crystal-pure PZN, and the solid solution (1-x) Pb(Zni1/3 Nb2/3)O3 - x PbTiO3 with x= 0.04, 0.09, 0.10. Measurements have been done for crystallographic directions [001] and [111] for all these compositions. Switching times versus the applied field showed the following results. Pure PZN along [111] and 0.90PZN—O. 10PT along [001], and [111] showed an exponential dependence. Along [001] the PZN showed a linear fit. For solid solution single crystals-0.96PZN -0.04PT and 0.91PZN £ 0.09PT, a linear fit was obtained for the reciprocal switch times versus applied field for both the directions. If we draw a parallel picture with the reported barium titanate data, it appears that the polarization reversal is controlled by nucleation along [111]- spontaneous direction for PZN and [001], [111]for 0.90PZN - O.10PT. The mobility of the reversed domains controls the reversal along [001] for PZN and the solid solution single crystals with rhombohedral composition along [001] and [111]. The transient current curves showed two maximum points for crystals with x = 0.04 and 0.09. This is attributed to the co-existence of the two phases in 0.96PZN -0.04PT and 0. 91PZN - 0.09PT crystals.

scholarly journals Orientation-dependent solid solution strengthening in zirconium: a nanoindentation study

2019 ◽  
Vol 55 (10) ◽  
pp. 4493-4503 ◽  
Author(s):  
Arijit Lodh ◽  
Prita Pant ◽  
Gulshan Kumar ◽  
K. V. Mani Krishna ◽  
Raghvendra Tewari ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Finite Element ◽  
Elastic Modulus ◽  
Constitutive Relationship ◽  
Insignificant Change ◽  
Solid Solution Strengthening ◽  
Pure Zirconium ◽  
Solution Strengthening ◽  
Peak Value

AbstractOrientation-dependent solid solution strengthening was explored through a combined microtexture plus nanoindentation study. Pure zirconium (6N purity crystal-bar Zr) and commercial Zircaloy-2 were investigated for comparison. Local mechanical properties were estimated through finite element (FE) simulations of the unloading part of the nanoindentation load–displacement response. Combinations of ‘averaging’ scheme and constitutive relationship were used to resolve uncertainty of FE-extracted mechanical properties. Comparing the two grades, non-basal oriented grains showed an overall hardening and increase in elastic modulus. In contrast, insignificant change was observed for basal (or near-basal) oriented grains. The strengthening of non-basal orientations appeared via elimination of the lowest hardness/stiffness values without a shift in the peak value. Such asymmetric development brought out the clear picture of orientation-dependent solid solution strengthening in zirconium.

scholarly journals Experimental Study on Physical-mechanical Properties and Fracture Behaviors of Saturated Yellow Sandstone Considering Coupling Effect of Freeze-Thaw and Specimen Inclination

2020 ◽  
Vol 12 (3) ◽  
pp. 1029 ◽  
Author(s):  
Liang Chen ◽  
Peng Wu ◽  
Yanlong Chen ◽  
Wei Zhang
Keyword(s):  
Mechanical Properties ◽  
Shear Stress ◽  
Elastic Modulus ◽  
Failure Mode ◽  
Inclination Angle ◽  
Compression Strength ◽  
Shear Loading ◽  
Cold Regions ◽  
Freeze Thaw ◽  
Peak Compression

The effect of freeze-thaw on the physical-mechanical properties and fracture behavior of rock under combined compression and shear loading was crucial for revealing the instability mechanism and optimizing the structure design of rock engineering in cold regions. However, there were few reports on the failure behavior of rock treated by freeze-thaw under combined compression and shear loading due to the lack of test equipment. In this work, a novel combined compression and shear test (C-CAST) system was introduced to carry out a series of uniaxial compression tests on saturated yellow sandstone under various inclination angles (θ = 0°, 5°, 10°, and 15°) and the number of freeze-thaw cycles (N = 0, 20, 40, and 60). The test results showed that the P-wave velocity dramatically decreased, while the rock quality and porosity increased gradually as N increased; the peak compression strength and elastic modulus obviously decreased with the increasing θ and N, while the peak shear stress increased gradually with the increasing θ and decreased with the increase of N, indicating that the shear stress component can accelerate the crack propagation and reduce its resistance to deformation. The acoustic emission (AE) results revealed that the change of crack initiation (CI) stress and crack damage (CD) stress with the θ and N had a similar trend as that of the peak compression strength and elastic modulus. Particularly, the CI and CD thresholds at 60 cycles were only 81.31% and 84.47% of that at 0° cycle and indicated a serious freeze-thaw damage phenomenon, which was consistent with the results of scanning electron microscopy (SEM) with the appearance of some large-size damage cracks. The fracture mode of sandstone was dependent on the inclination angle. The failure mode developed from both the tensile mode (0°) and combined tensile-shear mode (5°) to a pure shear failure (10°–15°) with the increasing inclination angle. Meanwhile, the freeze-thaw cycle only had an obvious effect on the failure mode of the specimen at a 5° inclination. Finally, a novel multivariate regression analysis method was used to predict the peak compression strength and elastic modulus based on the initial strength parameters (θ = 0°, N = 0). The study results can provide an important reference for the engineering design of rock subjected to a complex stress environment in cold regions.

Sign in / Sign up

Export Citation Format

Share Document