Laboratory determination of chloride diffusion coefficient in an intact shale

1990 ◽  
Vol 27 (2) ◽  
pp. 177-184 ◽  
Author(s):  
F. S. Barone ◽  
R. K. Rowe ◽  
R. M. Quigley
Keyword(s):  
Diffusion Coefficient ◽  
Pore Water ◽  
Water Reservoir ◽  
Water Concentration ◽  
Total Porosity ◽  
Effective Porosity ◽  
Chloride Diffusion ◽  
Fickian Diffusion ◽  
Distilled Water ◽  
Chloride Diffusion Coefficient

An experimental investigation of diffusive transport of a nonreactive solute (chloride) in saturated, intact Queenston Shale is described. Laboratory tests were performed by placing distilled water in contact with samples of shale having a high initial concentration of chloride in their pore water. Chloride was then permitted to diffuse out of the shale and into the distilled water reservoir for a period of up to 65 days. At the end of each test, the shale sample was sectioned to determine the variation in chloride pore-water concentration with depth through the sample. Fickian diffusion theory was then used to deduce the diffusion coefficient (D). The experimental diffusion coefficient for chloride at a temperature of 22 ± 1 °C ranged from 1.4 × 10−6 to 1.6 × 10−6 cm2/s, which corresponds to a tortuosity (τ) ranging from 0.095 to 0.108. Based on pore size measurements and consideration of the ionic diameter of hydrated chloride, the "effective porosity" available for chloride diffusion is estimated to be greater than 75% of the total porosity calculated from the moisture content of the shale. Key words: diffusion, chloride, rock matrix, Queenston Shale, laboratory study.

Effect of Stone Dust Content in Manufactured Sand on Chloride Diffusion Coefficient of Various Strength Grade Concretes

2011 ◽  
Vol 399-401 ◽  
pp. 1276-1281
Author(s):  
Peng Ping Li ◽  
Jian Bo Xiong ◽  
Zhi Hong Fan
Keyword(s):  
Diffusion Coefficient ◽  
Total Porosity ◽  
Immersion Test ◽  
Dust Content ◽  
Chloride Diffusion ◽  
Fine Aggregate ◽  
Chloride Diffusion Coefficient ◽  
Manufactured Sand ◽  
Stone Dust ◽  
Main Factor

The influence of stone dust content on chloride diffusion coefficient in C30, C40 and C50 grade concretes were investigated by means of the natural immersion test, XRD test, MIP test, SEM and TGA test, respectively. The experimental results showed that the chloride diffusion coefficient in C30 grade concretes decreased with increasing the stone dust content, but it decreased first and then increased with increasing the stone dust content in C40 and C50 grade concretes. The hydration degree for cementitious and compressive strength for concrete was slightly promoted by using stone dust replacing cementitious at a low level. For C30 grade concretes, the porosity decreased with increasing the stone dust content in fine aggregate, but for C40 and C50 grade concretes, the total porosity decreased first then increased with increasing the stone dust content. And the concrete pore structure was the main factor that influences the changes of chloride diffusion coefficient in concrete.

Inner Damage and Anti-Chloride Penetration of High-Performance Concrete under Axial Tensile Load

2011 ◽  
Vol 261-263 ◽  
pp. 1210-1214
Author(s):  
Fu Xiang Jiang ◽  
Lei Xin ◽  
Tie Jun Zhao ◽  
Xiao Mei Wan
Keyword(s):  
Diffusion Coefficient ◽  
High Performance ◽  
High Performance Concrete ◽  
Tensile Load ◽  
Total Porosity ◽  
Tensile Loading ◽  
Chloride Penetration ◽  
Chloride Diffusion ◽  
Uniaxial Tensile ◽  
Chloride Diffusion Coefficient

The total porosity of high performance concrete specimens after different level uniaxial tensile loading were measured to reflect the damage degree of mechanical load to the microstructure of the concrete. Meanwhile, considering the environmental characteristics of the ocean tidal zone, chloride penetration tests of the concrete were carried out with salt solution capillary absorption method. Based on the profile of chloride measured from specimens, chloride diffusion coefficients of the concrete under uniaxial tensile load with different levels are determined further by Fick’s second law. Results show that both of total porosity and chloride diffusion coefficient of the concrete are increased significantly after short-term tensile loading. And the evolutions of the porosity and chloride diffusion coefficient are similar with the development of micro-cracks under uniaxial tensile load.

scholarly journals Experimental Study on Effective Chloride Diffusion Coefficient of Cement Mortar by Different Electrical Accelerated Measurements

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 240
Author(s):  
Jianlan Chen ◽  
Jiandong Wang ◽  
Rui He ◽  
Huaizhu Shu ◽  
Chuanqing Fu
Keyword(s):  
Diffusion Coefficient ◽  
Cement Mortar ◽  
Early Stage ◽  
Chloride Concentration ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Cement Ratio ◽  
Water To Cement Ratio ◽  
Good Consistency ◽  
Determination Methods

This study investigated the effective chloride diffusion coefficient of cement mortar with different water-to-cement ratio (w/c) under electrical accelerated migration measurement. The cumulative chloride concentration in anode cell solution and the cumulative chloride concentration drop in the cathode cell solution was measured by RCT measurement and the results were further used to calculate the chloride diffusion coefficient by Nordtest Build 355 method and Truc method. The influence of w/c on cement mortar’s chloride coefficient was investigated and the chloride diffusion coefficient under different determination methods were compared with other researchers’ work, a good consistency between this work’s results and literatures’ results was obtained. The results indicated that the increased w/c of cement mortar samples will have a higher chloride diffusion coefficient. The cumulative chloride concentration drop in the cathode cell solution will have deviation in early stage measurement (before 60 h) which will result in overestimation of the effective chloride diffusion coefficient.

scholarly journals Comparative Study of Strength and Corrosion Resistant Properties of Plain and Blended Cement Concrete Types

2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
Velu Saraswathy ◽  
Subbiah Karthick ◽  
Han Seung Lee ◽  
Seung-Jun Kwon ◽  
Hyun-Min Yang
Keyword(s):  
Water Absorption ◽  
Corrosion Behaviour ◽  
Blended Cement ◽  
Effective Porosity ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Chloride Permeability ◽  
Corrosion Resistant ◽  
Lower Corrosion Rate ◽  
Portland Slag Cement

The relative performances of mechanical, permeability, and corrosion resistance properties of different concrete types were compared. Concrete types were made from ordinary Portland cement (OPC), Portland pozzolana cement (PPC), and Portland slag cement (PSC). Compressive strength test, effective porosity test, coefficient of water absorption, short-term accelerated impressed voltage test, and rapid chloride permeability test (RCPT) were conducted on M30 and M40 grades of concrete designed with OPC, PPC, and PSC cements for 28- and 90-day cured concrete types. Long-term studies such as microcell and electrochemical evaluation were carried out to understand the corrosion behaviour of rebar embedded in different concrete types. Better corrosion resistant properties were observed for PSC concrete by showing a minimum current flow, lowest free chloride contents, and lesser porosity. Besides, PSC concrete has shown less coefficient of water absorption, chloride diffusion coefficient (CDC), and lower corrosion rate and thereby the time taken for initiation of crack extended.

scholarly journals Effects after 1500 Hardening Days on the Microstructure and Durability-Related Parameters of Mortars Produced by the Incorporation of Waste Glass Powder as a Clinker Replacement

2021 ◽  
Vol 13 (7) ◽  
pp. 3979
Author(s):  
Rosa María Tremiño ◽  
Teresa Real-Herraiz ◽  
Viviana Letelier ◽  
Fernando G. Branco ◽  
José Marcos Ortega
Keyword(s):  
Diffusion Coefficient ◽  
Water Absorption ◽  
Glass Powder ◽  
Cementitious Materials ◽  
Cement Industry ◽  
Waste Glass ◽  
Supplementary Cementitious Materials ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Waste Glass Powder

One of the ways of lessening the CO2 emissions of cement industry consists of replacing clinkers with supplementary cementitious materials. The required service life of real construction elements is long, so it is useful to characterize the performance of these materials in the very long term. Here, the influence of incorporating waste glass powder as a supplementary cementitious material, regarding the microstructure and durability of mortars after 1500 hardening days (approximately 4 years), compared with reference mortars without additions, was studied. The percentages of clinker replacement by glass powder were 10% and 20%. The microstructure was studied using impedance spectroscopy and mercury intrusion porosimetry. Differential thermal and X-ray diffraction analyses were performed for assessing the pozzolanic activity of glass powder at the end of the time period studied. Water absorption after immersion, the steady-state diffusion coefficient, and length change were also determined. In view of the results obtained, the microstructure of mortars that incorporated waste glass powder was more refined compared with the reference specimens. The global solid fraction and pores volume were very similar for all of the studied series. The addition of waste glass powder reduced the chloride diffusion coefficient of the mortars, without worsening their behaviour regarding water absorption after immersion.

scholarly journals Influence of Hydrostatic Pressure and Cationic Type on the Diffusion Behavior of Chloride in Concrete

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2851
Author(s):  
Huanqiang Liu ◽  
Linhua Jiang
Keyword(s):  
Diffusion Coefficient ◽  
Hydrostatic Pressure ◽  
Diffusion Model ◽  
Coupling Effect ◽  
Experimental Results ◽  
Chloride Diffusion ◽  
Concrete Durability ◽  
Chloride Diffusion Coefficient ◽  
Diffusion Behavior ◽  
Diffusion Source

The durability of the concrete in underground and marine engineering is affected by the underground and ocean environment. Chloride diffusion coefficient under hydrostatic pressure is a key parameter of concrete durability design under corresponding conditions. Therefore, this paper studies the diffusion behavior of chloride in different diffusion source solutions by experiment and simulation. Based on the experimental results, this paper proposes a new chloride diffusion model under the coupling effect of diffusion and convection. The interaction of ions and compounds in the diffusion source solutions, concrete pore fluid, and concrete material are considered in the new chloride diffusion model. The experimental results show that chloride diffusion rate is significantly affected by hydrostatic pressure, which increases with the increase of hydrostatic pressure. The chloride diffusion coefficient shows a certain difference in difference diffusion source solutions. The chloride diffusion coefficient in divalent cationic diffusion source solutions is the largest, the chloride diffusion coefficient in the divalent and monovalent cationic compound ones is in the middle, and the chloride diffusion coefficient in the monovalent cationic ones is the smallest. There is a linear relationship between the chloride diffusion coefficient and the hydrostatic pressure whether in single or combined cationic diffusion source solutions.

scholarly journals MODELLING CHLORIDE DIFFUSION IN CONCRETE WITH INFLUENCE OF CONCRETE STRESS STATE

2017 ◽  
Vol 23 (7) ◽  
pp. 955-965 ◽  
Author(s):  
Jian WANG ◽  
Pui-Lam NG ◽  
Weishan WANG ◽  
Jinsheng DU ◽  
Jianyong SONG
Keyword(s):  
Experimental Data ◽  
Diffusion Coefficient ◽  
Stress State ◽  
Diffusion Model ◽  
Stress Ratio ◽  
Chloride Diffusion ◽  
Influence Coefficient ◽  
Chloride Diffusion Coefficient ◽  
Stress Influence ◽  
Concrete Stress

Under coastal or marine conditions, chloride erosion is the major accelerating factor of reinforcement corrosion. Therefore, it is of vital importance to investigate the chloride diffusion model. Research reveals that the concrete stress state has great influence on chloride diffusion; therefore a stress influence coefficient was incorporated in chloride diffusion coefficient model by many researchers. By referring to the experimental data from eight different researchers, the law between stress influence coefficient and concrete stress ratio is studied in detail, and equations relating the stress influence coefficient with the concrete stress ratio are established. Compared with three typical existing groups of equations, it is found that the proposed equations give the most accurate estim.ation of the stress influence coefficient. Hence, the proposed equations can be adopted to improve the valuation of chloride diffusion coefficient, and a modified chloride diffusion model is put forward. Three groups of experimental data are used to validate the modified chloride diffusion model, which is shown to be reasonable and having high prediction accuracy.

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