The synthesis, photophysical and dielectric properties of ball-type dinuclear zinc phthalocyanine

2012 ◽  
Vol 16 (07n08) ◽  
pp. 826-832 ◽  
Author(s):  
Mevlüde Canlıca ◽  
Ahmet Altındal ◽  
Tebello Nyokong
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Temperature Dependence ◽  
Zinc Phthalocyanine ◽  
Frequency Range ◽  
H Nmr ◽  
Peripheral Position ◽  
Ft Ir ◽  
Polarizability Contribution

The synthesis of ball-type dinuclear Zn(II) phthalocyanine containing four 4,4′-(9H-fluorene-9,9-diyl)diphenol substituents at the non-peripheral position is presented. The structure of the synthesized compound was characterized using elemental analyzes, and UV-vis, FT-IR,1H NMR and mass spectroscopies. The ΦFvalue was 0.16 and ΦTvalue was 0.72. The complex showed reasonably long triplet lifetimes with τT7210 μs in DMSO. The frequency and temperature dependence of the dielectric properties of ZnPc were also investigated in the frequency range of 40–105Hz and in the temperature range of 300–440 °K. It has been observed that both dielectric constant ε′ and dielectric loss ε″ decrease with the rise in frequency as they increase with the rise in temperature. The decrease in ε′ with increasing frequency is attributed to the fact that as the frequency increases, the polarizability contribution from orientation sources decreases and finally disappears.

Effect of moisture content on dielectric properties of banana leaves and peels in frequency range of 1–20 GHz

Frequenz ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Soumya Sundar Pattanayak ◽  
Soumen Biswas
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Moisture Content ◽  
Measurement Data ◽  
Banana Peel ◽  
Frequency Range ◽  
Proposed Model ◽  
Banana Leaves ◽  
Banana Leaf

Abstract The quality of agricultural products can be remotely sensed and enhanced by determining the dielectric properties. This paper studies the dielectric properties of banana leaf and banana peel over the frequency range 1–20 GHz using the open-ended coaxial probe (OCP) method. A new curve fitting model is proposed to characterize the dielectric properties of banana leaf and banana peel. The different moisture content (MC) levels are considered for both banana leaf and banana peel samples and, their dielectric properties are characterized. Further, the banana leaf and banana peel’s measurement data are compared with the data obtained using the proposed model. In addition, Root Mean Square Error (RMSE) and R-squared (R 2) are calculated to validate the performance of the proposed model. In case of banana leaf at 68.26% MC, the dielectric constant achieves the value of R 2 and RMSE of 0.98 and 0.0648, respectively. Similarly, dielectric loss achieves the value of R 2 and RMSE of 0.88 and 0.0795, respectively. Further, for banana peel at 80.89% MC, the dielectric constant achieves the value of R 2 and RMSE of 0.99 and 0.2989, respectively. Similarly, dielectric loss achieves the value of R 2 and RMSE of 0.96 and 0.6132, respectively.

Effect of Fungicide Treatment on Dielectric Properties of a Vegetable Seed

2015 ◽  
Vol 5 (2) ◽  
Author(s):  
Vishal Singh Chandel ◽  
Atiq UR Rahmanm ◽  
J. P. Shukla ◽  
Rajiv Manohar ◽  
Mohd. Shafi Khan
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Moisture Content ◽  
Considerable Change ◽  
Frequency Range ◽  
Dielectric Parameters ◽  
Hewlett Packard ◽  
Fungicide Treatment ◽  
Vegetable Seed

Effect of fungicides' (thiram, captan, carbendazim, bagalol) treatment on dielectric constant and dielectric loss of a vegetable seed, namely the brinjal at given moisture content and bulk density was examined using Hewlett-Packard (HP-4194A) impedance/gain phase analyzer over the frequency range of 0.01 to 10 MHz and temperature range of 30-450C. Julabo (temperature controller, F-25, Germany) was used for keeping the temperature of seeds constant. Study showed that fungicide treatment cast considerable change in dielectric parameters namely the dielectric constant and dielectric loss.

Preparation and Dielectric Properties of POSS-NH2/Cyanate Ester Resin Organic-Inorganic Hybrids

2011 ◽  
Vol 216 ◽  
pp. 635-639 ◽  
Author(s):  
Zeng Ping Zhang ◽  
Jian Zhong Pei ◽  
Shuan Fa Chen ◽  
Hong Zhao Du ◽  
Yong Wen
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Cyanate Ester ◽  
Cyanate Ester Resin ◽  
Curing Reaction ◽  
Ft Ir ◽  
Different Content

In order to improve the dielectric and overal properties of cyanate ester (CE) resin, a functional POSS monomer(octa(aminopropyl)silsesquioxane, POSS-NH2), was employed to modify CE. A series of POSS-NH2/CE hybrids (CE, CE1, CE2, CE3 and CE4) containing different content of POSS have been prepared by melt casting and then curing. The curing reaction of the resin systems were monitored by FT-IR. Dielectric properties of the hybrids were investigated in detail. FT-IR results showed the almost disappearance of the –OCN for all resin systems, suggesting the complete curing of CE using the experimental curing technique. Dielectric investigation indicates that CE1 which contains 1 wt% of POSS has the best dielectric properties with not only lowest dielectric constant but also lowest dielectric loss.

scholarly journals Study of Dielectric Properties of Fenugreek Seeds (Trigonella Foenum Graecum)

2014 ◽  
Vol 66 (1) ◽  
pp. 17-28 ◽  
Author(s):  
Mohd. Shafi Khan ◽  
Vishal Singh Chandel ◽  
Rajiv Manohar ◽  
Jagdeesh Prasad Shukla
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Moisture Content ◽  
Ac Conductivity ◽  
Frequency Range ◽  
Fenugreek Seeds ◽  
Temperature Controller ◽  
Trigonella Foenum Graecum ◽  
Fenugreek Seed

Abstract The present paper studied the dielectric constant, dielectric loss, and ac conductivity of fenugreek seed, a medicinal seed (Trigonella foenum graecum), within the frequency range of 10 kHz and 10 MHz and the temperature range of 30°C and 50°C. Impedance gain/phase analyser (HP 4194 A) was used to measure the dielectric constant and the dielectric loss and Julabo (temperature controller, F-25, Germany) was used for keeping the temperature of fenugreek seeds constant. It was found that the dielectric constant and the dielectric loss decrease with the increase in the frequency while the same increase with the increase in temperature and moisture content. The ac conductivity increased with the increase in frequency, moisture and temperature.

scholarly journals Dielectric and Conductivity Properties of Some Wood Composites

2016 ◽  
Vol 8 ◽  
pp. 51-60
Author(s):  
K.Ch. Varada Rajulu ◽  
B.N. Mohanty
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Low Temperature ◽  
Temperature Region ◽  
Loss Factor ◽  
Wood Composites ◽  
Frequency Range ◽  
Increasing Temperature ◽  
Coaxial Probe

This study presents the dielectric and conductivity properties as function of temperature and frequency of wood based composites. These properties were measured by an open-ended coaxial probe at frequency range between 100 kHz to 100MHz, temperature from 30OC to 200OC which is fully computer interfaced. It has been observed that dielectric constant (ε') and dielectric loss factor (ε") increase with increasing temperature and decrease with increasing frequency. At low temperature region, the conductivity depends significantly on the frequency. However, with the increase in temperature dielectric relaxation takes place and the dependency of the conductivity on frequency get reduced. The patterns of variation were established for the studied specimens and discrepancies were discussed. The study of dielectric properties will help in improving the drying, heating and gluing processes of wood and wood based products.

Solid State Sintering and Microstructural Evolution on Wide Frequency Range Dielectric Responses of Mechanically Activated CaTiO3 Ceramics

2015 ◽  
Vol 1107 ◽  
pp. 38-44
Author(s):  
Wong Yick Jeng ◽  
Hassan Jumiah ◽  
Mansor Hashim
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Sintering Temperature ◽  
Microstructural Analysis ◽  
High Energy ◽  
Wide Frequency Range ◽  
Milling Process ◽  
Frequency Range ◽  
Wide Range

The CaTiO3samples were prepared by high-energy ball milling process followed by sintering process from 1040 to 1200°C. X-ray diffraction (XRD), microstructural analysis, and dielectric properties over a wide range of frequency varying from 0.01 Hz to 1 GHz at room temperature were investigated. The formation of a single phase CaTiO3with orthorhombic structure was achieved at 1120°C and above. From a morphological point of view, sintering temperature promoted grain growth. Dielectric properties in the frequency range 0.01 Hz - 1 MHz revealed a relaxation-type process. Interfacial phenomena were the possible physical mechanisms that gave rise to these relaxation-type plots. Extending the frequencies above ~1 MHz yielded a frequency-independent characteristic of dielectric constant (ε'). These turned out to the relatively small dielectric loss (tan δ) values. The origin of the dielectric responses in the frequency range 1 MHz - 1 GHz was attributed to the domination of dipolar polarization. The grain size effect in sintered CaTiO3samples was prominent, notably in dielectric responses above ~1 MHz. Increase in sintering temperature remarkably led to an enhancement in dielectric constant values and reduction in dielectric loss values. Therefore, a significant correlation existed between microstructural features and dielectric properties.

Dielectric Properties of PMN/CB/CIIR Composites

2009 ◽  
Vol 66 ◽  
pp. 234-237 ◽  
Author(s):  
Hao Yan ◽  
Zhi Xiong Huang ◽  
Yan Bing Wang
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Carbon Black ◽  
Lead Titanate ◽  
High Frequency ◽  
Dielectric Constants ◽  
Frequency Range ◽  
Magnesium Niobate ◽  
Chlorobutyl Rubber

The Magnesium Niobate-Lead Titanate (PMN) / conductive carbon black (CB)/ chlorobutyl rubber(CIIR) composites were prepared by blending-vulcanization method, and the dielectric properties were studied. The results showed that the dielectric constant and dielectric loss of composites increased nonlinearly when increasing the content of PMN or CB. From the curve of dielectric constant vs frequency, it is obtained that in the frequency range from 103 to 106 Hz, the dielectric constant of PMN/CB/CIIR composites decreased with the frequency increasing and the dielectric constants are more stable under high frequency.

Characterization and dielectric properties of sodium fluoride doped talc

Clay Minerals ◽  
2014 ◽  
Vol 49 (4) ◽  
pp. 551-558
Author(s):  
S. Gümüştas ◽  
K. Köseoğlu ◽  
E. E. Yalçinkaya ◽  
M. Balcan
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Firing Temperature ◽  
Room Temperature ◽  
Dielectric Measurements ◽  
Frequency Range ◽  
Detailed Characterization ◽  
Circuit Element

AbstractThe purpose of this paper is to determine the effect of NaF and firing temperature on the dielectric properties (dielectric constant and dielectric loss) of talc, which is used in the electrical and electronic industries as a circuit element. A detailed characterization of the samples was made by XRD, FTIR, SEM and TG-DTG methods. Dielectric measurements were performed in the frequency range from 1 MHz to 80 MHz at room temperature. The dielectric constant value increased with an increase in firing temperature due to the removal of polarizable compounds from the talc structure. The higher dielectric constant values were obtained by addition of NaF. The dielectric loss of NaF doped talc decreased with the increase of firing temperature and increased with the increase of the amount of NaF.

Dielectric Properties of Iron Phthalocyanine Compounds

1998 ◽  
Vol 02 (03) ◽  
pp. 223-230 ◽  
Author(s):  
JAYASHREE BIJWE ◽  
NEELAM PHOUGAT
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Dielectric Constants ◽  
Iron Phthalocyanine ◽  
Frequency Range ◽  
Large Dielectric Constant ◽  
Temperature Dependences

Monomeric and polymeric iron phthalocyanine compounds were synthesized and their dielectric properties were measured in the frequency range from 100 Hz to 10 MHz between 25 and 200 °C. The dielectric constant and dielectric loss showed strong frequency and temperature dependences. Interestingly, large dielectric constants were observed around 100 °C for both monomers and polymers. A dielectric constant as high as 5000 at 110 Hz was observed for the iron phthalocyanine polymer. The origin of the large dielectric constant in metallophthalocyanines is discussed.

scholarly journals Dielectric Properties of Azo Polymers: Effect of the Push-Pull Azo Chromophores

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Xuan Zhang ◽  
Ziqi Wen ◽  
Hongxing Zhang ◽  
Weihua Han ◽  
Jinyi Ma ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Acid Ethyl Ester ◽  
Coupling Reaction ◽  
Random Copolymer ◽  
Azo Polymers ◽  
H Nmr ◽  
Azo Polymer ◽  
Ft Ir ◽  
The Relationship

The relationship between the structure and the dielectric properties of the azo polymers was studied. Four azo polymers were synthesized through the azo-coupling reaction between the same precursor (PAZ) and diazonium salts of 4-aminobenzoic acid ethyl ester, 4-aminobenzonitrile, 4-nitroaniline, and 2-amino-5-nitrothiazole, respectively. The precursor and azo polymers were characterized by 1H NMR, FT-IR, UV-vis, GPC, and DSC. The dielectric constant and dielectric loss of the samples were measured in the frequency range of 100 Hz–200 kHz. Due to the existence of the azo chromophores, the dielectric constant of the azo polymers increases compared with that of the precursor. In addition, the dielectric constant of the azo polymers increases with the increase of the polarity of the azo chromophores. A random copolymer (PAZ-NT-PAZ) composed of the azo polymer PAZ-NT and the precursor PAZ was also prepared to investigate the content of the azo chromophores on the dielectric properties of the azo polymers. It showed that the dielectric constant increases with the increase of the azo chromophores. The results show that the dielectric constant of this kind of azo polymers can be controlled by changing the structures and contents of azo chromophores during the preparation process.

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