Effects of the Potassium Titanate Functional Filler Types on the Thermal Protection Performance of Heat Resistant Ablative Coated Fabrics

NANO ◽  
2018 ◽  
Vol 13 (02) ◽  
pp. 1850014 ◽  
Author(s):  
Guoyi Liu ◽  
Yuanjun Liu ◽  
Xiaoming Zhao

Considering sub-micron potassium titanate whiskers (BX-101), nanoscale potassium titanate whiskers (AX-301), sub-micron potassium titanate whiskers (AX-316) and high strength potassium titanate crystal (AX-319) as functional fillers, heat resistant ablative coated fabrics which have high radiant heat reflectivity were prepared. The effect of the type of functional filler on the thermal protection performance of heat resistant ablative coated fabrics was mainly discussed. Research showed that the microstructure of potassium titanate functional filler had a significant impact on the radiant heat reflectivity and thermal insulation performance of the prepared coated fabric. The coated fabric which took nanoscale potassium titanate whiskers (AX-301) with a minimum diameter and greater length-diameter ratio as functional filler has the highest thermal reflectivity and the best insulation property. Heat ray reflectivity of potassium titanate coated fabrics had positive correlation with their crystallinities. The higher the coated fabric crystallinity was, the greater the heat ray reflectivity. Thermogravimetric analysis results showed that after adding four kinds of potassium titanate fillers, the thermal stability of the prepared coated fabrics was enhanced, and the nanoscale potassium titanate whiskers (AX-301) coated fabrics had the best thermal stability.

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Guoyi Liu ◽  
Yuanjun Liu ◽  
Xiaoming Zhao

In the high temperatures experienced in fire, radiant heat accounts for 80% of the total heat flow; therefore, improving the radiation protection is the best way to enhance the thermal protective performance of thermal insulation ablation resistant coated fabrics. To achieve this goal, the coating process and the ingredients used were optimized, spherical nano-SiO2 and other particles were added, and thermal insulation ablation resistant coated fabrics with high radiant heat reflectivity were prepared. The influence of the spherical nano-SiO2 content on the thermal protection performance of the prepared coated fabrics was investigated. Research showed that (1) the radiant heat reflectivity of the prepared coated fabrics improves significantly with increasing content of spherical nano-SiO2; when the mass fraction of spherical nano-SiO2 is 15%, the reflectivity of coated fabrics is at its largest, and its average value was 74.30%. At present, the average size of grains in samples increased 1.9 times; (2) after adding the spherical nano-SiO2, the thermal stability of the thermal insulation ablation resistant coated fabrics is significantly improved; the residual mass is as high as 88.49% at 1200°C, which is 18.77% higher than the residual mass of the coated fabrics with no spherical nano-SiO2 added at the same temperature.


2014 ◽  
Vol 84 (19) ◽  
pp. 2015-2025 ◽  
Author(s):  
Vesna Marija Potočić Matković ◽  
Ivana Salopek Čubrić ◽  
Zenun Skenderi

Polyurethane-coated knitted fabrics are of interest because they exhibit several positive properties, they are more stretchable, elastic and comfortable than coated woven fabrics and yet they are little studied. Information of weather durability, as well as thermal properties, is essential to ensure thermal protection for textile materials intended for outdoor use. In the presented research, a series of coated knitted fabrics for protective clothing were developed and exposed to weathering in summer and winter seasons. After three months of outdoor exposure, thermal resistance of all the tested materials decreased by 13% after the summer season and 25% after the winter season. A very good correlation of knitted fabric mass per unit area and thermal resistance of knitted fabric, coated fabric and aged coated fabric occurred. The studied materials experienced a partial degradation of the polyurethane layer, which is not related to the deterioration of the knitted substrate. The presented investigation of thermal resistance of coated fabrics and their dependence on the knitted substrate, as well as the influence of environmental conditions, allows the improvement of coated fabrics with the aim of better thermal protection.


2021 ◽  
Vol 8 ◽  
Author(s):  
Ling Lin ◽  
Ziyin Li ◽  
Haiyan Mao ◽  
Wenyao Li ◽  
Chaoxia Wang

Application of SiO2 aerogel in thermal protective clothing has been limited due to its brittle nature, ordinary mechanical properties, and poor film forming performance. This work is aimed to develop thermal protective cotton fabrics by coating blended OPU/SiO2 aerogel with enhanced mechanical properties and thermal protection performance. The OPU/SiO2 aerogel composites with different ratio were applied onto cotton fabrics by knife-coating. The morphology, chemical component, crystalline structure, thermal stability and compression strength were characterized by scanning electron microscopy (SEM), Fourier transfer Infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG) and compression test, respectively. Besides, the warmth retention performance and heat protection performance together with air and moisture permeability of the coated fabrics were studied. The results showed that OPU/SiO2 aerogel were successfully coated onto cotton fabrics with enhanced mechanical properties and thermal stability together with better film forming capacity. The heat transfer coefficient of the coated cotton fabrics was distinctly dropped due to the synergistic effect of OPU and SiO2 aerogel, which resulted in higher warmth retention. The OPU/SiO2 aerogel coated fabrics exhibited obvious heat insulation performance with its surface temperate almost 4°C than the uncoated fabrics. This work demonstrates a new strategy of fabricating stronger thermal insulating textiles using OPU/SiO2 aerogel composites.


2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Zhenrong Zheng ◽  
Wei Zhi ◽  
Kezhu Mao ◽  
Qian Zhang ◽  
Lijuan Luo

Purpose The purpose of this paper is to study the ablative behavior of the silicone resin-coated carbon fabric (coated fabric) that will swell significantly during ablation. Design/methodology/approach The ablation experiments of three coated fabrics were conducted by quartz lamp radiant. Based on the experimental analysis, a numerical model was proposed for the coated fabrics to study the ablative process in term of the energy balance, mass conservation and thermal decomposition equations. Findings Results showed that the average relative errors between the simulated temperatures and experimental values of back surfaces of coated fabric 1, 2 and 3 were 10.01, 7.53 and 7.32%, respectively. The average density of silicone resin of coated fabric 1 was reduced by 47.96%, and the closer the distance from the heated surface was, the more the density decreased. The thermal conductivity and specific heat capacity of silicone resin of coated fabric 1 increased with time. Before 50 s, each decomposition rate curve showed an inflection point, at which the silicone resin decomposed most intensely. Research limitations/implications Based on experimental observations, the ablative behavior of the material with fixed expansion layer was simulated. In the further research, the moving expansion layer could be considered. Originality/value This paper provides the theoretical basis to evaluate the effectiveness of thermal protection materials that will swell during ablation.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2903
Author(s):  
Juvenal Giogetti Nemaleu Deutou ◽  
Rodrigue Cyriaque Kaze ◽  
Elie Kamseu ◽  
Vincenzo M. Sglavo

The present project investigated the thermal stability of cold-setting refractory composites under high-temperature cycles. The proposed route dealt with the feasibility of using fillers with different particle sizes and studying their influence on the thermo-mechanical properties of refractory geopolymer composites. The volumetric shrinkage was studied with respect to particle sizes of fillers (80, 200 and 500 µm), treatment temperature (1050–1250 °C) and amount of fillers (70–85 wt.%). The results, combined with thermal analysis, indicated the efficiency of refractory-based kyanite aggregates for enhancing thermo-mechanical properties. At low temperatures, larger amounts of kyanite aggregates promoted mechanical strength development. Flexural strengths of 45, 42 and 40 MPa were obtained for geopolymer samples, respectively, at 1200 °C, made with filler particles sieved at 80, 200 and 500 µm. In addition, a sintering temperature equal to 1200 °C appeared beneficial for the promotion of densification as well as bonding between kyanite aggregates and the matrix, contributing to the reinforcement of the refractory geopolymer composites without any sign of vitrification. From the obtained properties of thermal stability, good densification and high strength, kyanite aggregates are efficient and promising candidates for the production of environmentally friendly, castable refractory composites.


Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 525
Author(s):  
Ana Kiš ◽  
Snježana Brnada ◽  
Stana Kovačević

In this work, aramid fibers were used to develop new, high-performance fabrics for high-temperature protective clothing. The research was based on the impact of the weave structure on fabric resistance to radiant heat. The goals of the research were primarily related to the development of new fabric structures created by the weave structure, which gives better protection of the body against high temperatures in relation to the standard weave structures that are used today. According to the results obtained it can be concluded that the fabric weave significantly affects the fabric structure, which consequently determines the effectiveness of protection against high temperatures. The justification for the use of multi-weft and strucks weave structure, which provides greater thermal protection and satisfactory breathability than commonly used weave structures, was ascertained.


RSC Advances ◽  
2016 ◽  
Vol 6 (23) ◽  
pp. 19417-19429 ◽  
Author(s):  
Kai Wang Chan ◽  
Cheng Zhu Liao ◽  
Hoi Man Wong ◽  
Kelvin Wai Kwok Yeung ◽  
Sie Chin Tjong

The WST-1 assay shows that the PEEK/15 vol% nHA–1.9 vol% CNF hybrid composite has excellent biocompatibility.


1989 ◽  
Vol 21 (3) ◽  
pp. 199-204 ◽  
Author(s):  
G. J. Knight ◽  
W. W. Wright

2016 ◽  
Vol 47 (5) ◽  
pp. 853-869 ◽  
Author(s):  
Yun Su ◽  
Jun Li

Protection from steam burns is beneficial to reduce the nonfatal injuries of firefighters in firefighting and rescue operations. A new multifunctional testing apparatus was employed to study heat and steam transfer in protective clothing under low-pressure steam and low-level thermal radiation. Single-, double-, and triple-layered fabric assemblies were selected in this experiment. It is indicated that the existence of hot steam weakens the positive influence of the fabric’s thickness, but increases the importance of the air permeability on the thermal protection. The fabric assemblies entrapping moisture barrier can better resist the penetration of steam through the fabric system, and significantly improve the thermal protection in low steam and thermal radiation exposure due to the low air permeability. Additionally, the total transmitted energy ( Qe) and dry thermal energy ( Qd) under low steam and thermal radiation are dramatically larger than that under thermal radiation ( p < 0.05), while hot steam insignificantly reduces the thermal energy during the cooling ( p = 0.143 > 0.05). The understanding of steam heat transfer helps to provide proper guidance to improve the thermal protection of the firefighter’s clothing and reduce steam burns.


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