scholarly journals STUDY OF MULTIELEMENTAL ADSORPTION ON ACTIVATED CARBON

2012 ◽  
Vol 06 ◽  
pp. 121-126
Author(s):  
LE THI XUAN THUY ◽  
MIKITO YASUZAWA ◽  
TOMOKI YABUTANI
Keyword(s):  
Activated Carbon ◽  
Metal Concentration ◽  
Contact Time ◽  
Adsorption Process ◽  
Adsorption Rate

In this study, multielemental adsorption on activated carbon (AC) was investigated. The treatment parameters (pH, AC concentration, metal concentration and contact time) in the adsorption process of multiple metals such as Bi , Cd , Co , Ga , Mn , Mo , Ni , In , Pb , Pd , Sn , Rh , Ru and W were experimented. Three types of characteristic behaviors of analyte elements were observed when the pH was varied. The adsorption rate of Bi , Co , Ga , Ni , In , Pb , Sn , Ru and W were over 80% within 30 min.

scholarly journals STUDI ADSORPSI ZAT WARNA NAPHTHOL YELLOW S PADA LIMBAH CAIR MENGGUNAKAN KARBON AKTIF DARI AMPAS TEBU

Jurnal Kimia ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 104
Author(s):  
W. P. Utoo1 ◽  
E. Santoso ◽  
G. Yuhaneka ◽  
A. I. Triantini ◽  
M. R. Fatqi ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Surface Area ◽  
Contact Time ◽  
Adsorption Process ◽  
Activation Process ◽  
Adsorption Model ◽  
High Adsorption ◽  
Prolonged Contact ◽  
Test Result

The aim of this research is to get activated carbon from sugarcane bagasse with high adsorption capacity to Naphthol Yellow S and to know factors influencing the adsorption capacity. Activated carbon is prepared by incomplete combustion of sugracane bagasse. The resulting carbon is activated with H2SO4 with concentration variation of 0.5; 1.0; 1.5 and 2.0 M and is continued by calcination at 400 °C. The measurement of the surface area of ??activated carbon by the methylene blue method indicates that the activation process successfully extends the surface area of carbon from 31.87 m2/g before activation to 66-72 m2/g after activation. Activated carbon with concentration of 2.0 M H2SO4 showed the highest surface area of ??71.85 m2/g, however, the best adsorption was shown by activated carbon with a concentration of 0.5 M H2SO4 with the adsorption capacity of 83.93%. The adsorption test showed that the best amount of adsorbent was 0.2 g with contact time for 30 minutes. Prolonged contact time can decrease the amount of Naphthol Yellow S adsorbed. The best adsorption test result was shown by sample with activator concentration of 0,5 M, mass of 0,2 g and contact time of 30 min with adsorption capacity 95,81% or amount of dye adsorbed equal to 143,72 mg/g. The adsorption study also showed that the entire Naphthol Yellow S adsorption process followed the Langmuir isothemal adsorption model. Qualitative testing of real batik waste indicates that activated carbon can reduce the dyes waste containing Naphthol Yellow Sexhibited by the color of batik waste which is more faded.  

scholarly journals Phenol removal from aqueous solution using silica and activated carbon derived from rice husk

2019 ◽  
Vol 14 (4) ◽  
pp. 897-907 ◽  
Author(s):  
Hosseinali Asgharnia ◽  
Hamidreza Nasehinia ◽  
Roohollah Rostami ◽  
Marziah Rahmani ◽  
Seyed Mahmoud Mehdinia
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Water Treatment ◽  
Organic Pollutants ◽  
Rice Husk ◽  
Contact Time ◽  
Adsorption Process ◽  
Phenol Removal ◽  
Initial Concentration ◽  
Maximum Removal

Abstract Phenol and its derivatives are organic pollutants with dangerous effects, such as poisoning, carcinogenicity, mutagenicity, and teratogenicity in humans and other organisms. In this study, the removal of phenol from aqueous solution by adsorption on silica and activated carbon of rice husk was investigated. In this regard, the effects of initial concentration of phenol, pH, dosage of the adsorbents, and contact time on the adsorption of phenol were investigated. The results showed that the maximum removal of phenol by rice husk silica (RHS) and rice husk activated carbon (RHAC) in the initial concentration of 1 mgL−1 phenol, 2 gL−1 adsorbent mass, 120 min contact time, and pH 5 (RHS) or pH 6 (RHAC) were obtained up to 91% and 97.88%, respectively. A significant correlation was also detected between increasing contact times and phenol removal for both adsorbents (p < 0.01). The adsorption process for both of the adsorbents was also more compatible with the Langmuir isotherm. The results of this study showed that RHS and RHAC can be considered as natural and inexpensive adsorbents for water treatment.

scholarly journals “Batik” Industry Wastewater Treatment via Coagulation-Flocculation Process and Adsorption Using Teak Sawdust Based Activated Carbon

2019 ◽  
Vol 8 (1) ◽  
pp. 08-13
Author(s):  
Prima Astuti Handayani ◽  
Umi Cholifah ◽  
Ria Ulviana ◽  
Achmad Chafidz
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Contact Time ◽  
Adsorption Process ◽  
Optimum Concentration ◽  
Water Stream ◽  
Untreated Wastewater ◽  
Flocculation Process ◽  
Industry Wastewater ◽  
Sequencing Process

Untreated wastewater of Batik industry can pollute the environment because it contains metal compound, COD, BOD, which are higher than the allowable values. Therefore, a treatment of this wastewater prior discharging to water stream (i.e. river) is very important. This research aims to investigate the use of Teak sawdust as activated carbon, and also the effect of adsorbent concentration, adsorption contact time, as well as coagulation-flocculation-adsorption sequencing process to the level of COD, BOD, and Zn in Batik wastewater. The Batik wastewater used for this research obtained from Batik industry in Rembang, which mostly used naphtol as the coloring agent. The wastewater was initially treated by coagulation-flocculation process, followed by adsorption process. The coagulant-flocculant used in this research was 1 g/L of alum and 3 g/L of lime. Whereas, the adsorbent used was activated carbon made from Teak sawdust with variation of concentrations: 10, 16, 23, and 26 g/L. Whereas, the adsorption contact times were 20, 40, 100, 160, and 220 minutes. The results showed that the coagulation-flocculation process was able to decrease the levels of COD, BOD, and Zn by 73.28%, 73.62%, and 79.21% respectively. Additionally, the adsorption process by activated carbon also further decreased the levels of COD, BOD, and Zn significantly. Based on the results, the optimum concentration of activated that gave the best result was 26 g/L with 220 minutes contact time. Overall, the combination of coagulation-flocculation and adsorption sequencing process was able to decrease the level of COD, BOD, and Zn up to 96.69%, 96.90%, and 91.90% respectively.

Preparation of mesoporous activated carbon from date stones for the adsorption of Bemacid Red

2019 ◽  
Vol 79 (7) ◽  
pp. 1357-1366 ◽  
Author(s):  
Rabia Boudia ◽  
Goussem Mimanne ◽  
Karim Benhabib ◽  
Laurence Pirault-Roy
Keyword(s):  
Activated Carbon ◽  
Textile Industry ◽  
Contact Time ◽  
Adsorption Process ◽  
Agricultural Waste ◽  
Organic Pollutant ◽  
Second Order ◽  
Textile Dye ◽  
Solution Ph ◽  
Pseudo Second Order

Abstract This work concerns the elimination of the organic pollutant; Bemacid Red (BR), a rather persistent dye present in wastewater from the textile industry in western Algeria, by adsorption on carbon from an agricultural waste in the optimal conditions of the adsorption process. An active carbon was synthesized by treating an agro-alimentary waste, the date stones that are very abundant in Algeria, physically and chemically. Sample after activation (SAA) with phosphoric acid was highly efficient for the removal of BR. The characterization of this porous material has shown a specific surface area that exceeds 900 m2/g with the presence of mesopores. The iodine value also indicates that the activated carbon obtained has a large micro porosity. The reduction of the infrared spectroscopy (FTIR) bands reveals that the waste has been synthesized and activated in good conditions. Parameters influencing the adsorption process have been studied and optimized, such as contact time, adsorbent mass, solution pH, initial dye concentration and temperature. The results show that for a contact time of 60 min, a mass of 0.5 g and at room temperature, the adsorption rate of the BR by the SAA is at its maximum. Pseudo-first-order, pseudo-second-order and intraparticle diffusion models were studied to analyse adsorption kinetics. The result shows the adsorption kinetic is best with the pseudo-second-order model. In this study, Langmuir, Freundlich and Temkin isotherms were investigated for adsorption of BR onto SAA. The Freundlich and Temkin isotherms have the highest correlations coefficients. The suggested adsorption process involves multilayer adsorption with the creation of chemical bonds. The mechanism of adsorption of BR by SAA is spontaneous and exothermic, and the Gibbs free energy values confirm that the elimination of the textile dye follows a physisorption.

scholarly journals Langmuir and Freundlich isotherm equation test on the adsorption process of Cu (II) metal ions by cassava peel waste (Manihot esculenta crantz)

2021 ◽  
Vol 2126 (1) ◽  
pp. 012022
Author(s):  
S Nuryanti ◽  
Suherman ◽  
S Rahmawati ◽  
M Amalia ◽  
T Santoso ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Manihot Esculenta ◽  
Contact Time ◽  
Adsorption Process ◽  
Freundlich Isotherm ◽  
Maximum Adsorption Capacity ◽  
Manihot Esculenta Crantz ◽  
Isotherm Equations ◽  
Cassava Peel

Abstract This Study aims to determine the adsorption process of Cu (II) metal by cassava peel waste (Manihot esculenta crantz) meeting the Langmuir equation and Freundlich. Research method cassava peel made into activated carbon, then determine the mass, pH and optimum contact time. Then the determination of the maximum adsorption capacity was carried out by testing with the Langmuir isotherm and Freundlich isotherm equations. The results showed that the best conditions (optimal conditions) were obtained with the addition of 0.5 grams of active carbs from cassava peels. The percentage of Cu ion adsorption in these conditions was 97.72%, at pH 6 and a contact time of 60 minutes and the absorption capacity was 98.49%. The maximum adsorption capacity of cassava peel activated carbon to Cu(II) ions at the optimum condition was determined based on the Langmuir and Freundlich isotherm equations. The results obtained were-51.813 mg/g and 26,792 mg/g, respectively.

scholarly journals Desorption and Re-Adsorption of Procion Red MX-5B Dye on Alumina-Activated Carbon Composite

2018 ◽  
Vol 18 (2) ◽  
pp. 222 ◽  
Author(s):  
Fatma Fatma ◽  
Poedji Loekitowati Hariani ◽  
Fahma Riyanti ◽  
Wiwin Sepriani
Keyword(s):  
Activated Carbon ◽  
Contact Time ◽  
Adsorption Process ◽  
Carbon Composite ◽  
Desorption Process ◽  
Desorption Kinetic ◽  
First Order ◽  
Before And After ◽  
Sem Micrograph ◽  
Pseudo First Order

The alumina-activated carbon has the ability to adsorb and desorb the procion red MX-5B. The research evaluated the influence of desorption agent, contact time, and temperature on desorption process of procion red MX-5B dye with alumina-activated carbon composite and the adsorption capacity of the composite after desorption process. The desorption agents used in desorption process were solution with pH 2−10, H2O2 30 % (v/v), methanol 70% (v/v) and ethanol 70% (v/v). The variation of contact time was in the range from 30 to 270 min and the temperature was set between 30−75 °C. The result concluded that the highest desorption efficiency up to 98.56% was achieved using ethanol 70% (v/v) for 240 min at 45 °C. The desorption kinetic followed the pseudo-first-order with the release constant (kdes) of 6.56 × 10-2 min-1. The SEM micrograph showed there is a more porous surface on the composite after the desorption compared to before the desorption. The EDX analysis indicated that alumina content in the composite was reduced after desorption process. FTIR spectra of the composite before and after desorption process showed a peak of Al−O at 592 and 590 cm-1 which was proved that alumina still exists in the composite after the desorption process. The alumina-activated carbon composite was re-used to adsorb procion red MX-5B dye. After three times of desorption and re-adsorption process, the capacity adsorption was decreased from 12.38 to 7.38 mg/g.

scholarly journals Reductive Adsorption of Chromium(VI) with Activated Carbon

2021 ◽  
Vol 333 ◽  
pp. 04004
Author(s):  
Anh Viet Hoang ◽  
Ya Wen Chen ◽  
Ya-Fen Wang ◽  
Syouhei Nishihama ◽  
Kazuharu Yoshizuka
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Contact Time ◽  
Adsorption Process ◽  
Acidic Ph ◽  
High Adsorption ◽  
Varying Parameters ◽  
High Ph ◽  
Chromium Vi ◽  
Ph Range

Reductive adsorption of chromium (Cr) has been investigated, employing coal-based activated carbon with batchwise study. The adsorption was carried out by varying parameters such as pH of the aqueous solution and contact time. Cr(III) was hardly adsorbed on activated carbon, and it was precipitated at high pH region. High adsorption amounts of Cr(VI) was obtained at pH range 4.5 – 5.5. In the adsorption process, reduction of Cr(VI) to Cr(III) was occurred at especially acidic pH region, and thus most of Cr remained in the aqueous solution in this pH region was Cr(III).

scholarly journals Kinetics and Thermodynamics Studies of Copper(II) Adsorption onto Activated Carbon Prepared from Salacca zalacca Peel

Molekul ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 63
Author(s):  
Dewi Yuanita Lestari ◽  
Endang Widjajanti Laksono
Keyword(s):  
Activated Carbon ◽  
Contact Time ◽  
Metal Ion ◽  
Adsorption Process ◽  
Biogenic Carbon ◽  
Adsorption Data ◽  
Batch Technique ◽  
Langmuir Isotherm Model ◽  
G Value ◽  
Highly Porous

Highly porous and stable materials, such as alumina, silica, carbon, zeolite, and bentonite,  are well known and have been used as metal ion adsorbents. However, the use of biogenic carbon as adsorbent is relatively rare. The adsorption of copper(II) onto activated carbon extracted from Salcaca zalacca peel was studied. The effect of initial copper concentration, contact time, and a series temperature was studied. Adsorption was carried out in a batch technique. The adsorption equilibrium was reached after 60 minutes of contact time. The adsorption data had a better fitting line for the Langmuir isotherm model. The Langergren and also Ho and Mc Kay equations were used to predict the adsorption kinetics. The adsorption process obeyed a second-order kinetics model. The Thermodynamic parameters were ∆H°= -42.4180 kJ/mol; ∆S°= -0.0843 kJ/mol; ∆G°<0. These values indicated that the adsorption was exothermic and spontaneous. The low ∆G° value revealed that the main mechanism controlling the adsorption process was physisorption.

Odor removal by powdered activated carbon (PAC) in low turbidity drinking water

2016 ◽  
Vol 16 (4) ◽  
pp. 1017-1023 ◽  
Author(s):  
Qiulai He ◽  
Lin Zhong ◽  
Hongyu Wang ◽  
Zhuocheng Zou ◽  
Dan Chen ◽  
...  
Keyword(s):  
Drinking Water ◽  
Activated Carbon ◽  
Contact Time ◽  
Adsorption Process ◽  
Powdered Activated Carbon ◽  
Raw Water ◽  
Batch Experiments ◽  
Order Model ◽  
Coagulant Dosage ◽  
Odor Removal

The potential of powdered activated carbon (PAC) adsorption for odor removal in low turbidity drinking water was investigated. The batch experiments were conducted under various conditions including PAC species, dosage, contact time and dosing point. The effects of pre-chlorination and PAC dosage on turbidity were also studied. Results showed that adsorption was quite vulnerable to initial threshold odor number (TON), and higher influent TON required a larger dosage. Both PAC species (derived from coal and wood) presented excellent adsorption capacity for odorants. The adsorption process versus time had three steps and the adsorption kinetics were well fitted by the second order model. Pre-chlorination had an adverse effect on both raw water TON and odor removal. PAC adsorption was enhanced by dosing during coagulation and could, in turn, save coagulant dosage.

scholarly journals Application of Modified Agricultural Waste in the Adsorption of Bromocresol Green Dye

2020 ◽  
pp. 15-24
Author(s):  
Onu Chijioke Elijah ◽  
Oguanobi Nonso Collins ◽  
Okonkwo Callistus Obumneme ◽  
Nnamdi-Bejie Jessica
Keyword(s):  
Activated Carbon ◽  
Rice Husk ◽  
Contact Time ◽  
Adsorption Process ◽  
Research Work ◽  
Isotherm Models ◽  
Bromocresol Green ◽  
Order Kinetic ◽  
Adsorptive Removal ◽  
Kinetics Of

Background: The adsorptive removal of anionic dye (Bromocresol green) from aqueous solution was investigated using activated carbon prepared from rice husk. Place of Study: The research work took place at Nnamdi Azikiwe Univeristy Awka, Nigeria. Methods: The rice husk which was obtained from rice mills in Awka was activated with tetraoxophosphoric acid and carbonized in a furnace. The adsorption process was investigated by varying the contact time, temperature, dosage, pH and initial concentration in a batch process. Five isotherm models (Langmuir, Freundlich, Temkin, Halsay and Harkin-Jura) were employed in the equilibrium studies. Thermodynamics and kinetics of the adsorption were carried out. Results: The result indicated that increase in contact time, adsorbent dosage and temperature increased the percent uptake of the Bromocresol green dye. Maximum percentage adsorption of about 93% was obtained. Langmuir and Harkin-Jura isotherm models best described the equilibrium data of the adsorption process. Pseudo second-order kinetic model best correlates the kinetics of the experimental data. The thermodynamic study showed that the Gibbs free energy (ΔG), enthalpy change (ΔH) and entropy change (ΔS) were –2.541 kJ/mol,  -7.401 kJ/mol and –15.52 kJ/mol K respectively. Conclusion: This work has shown that activated carbon prepared from rice husk can be used in adsorptive removal of bromocresol green dye from solution and that the adsorption process was spontaneous and exothermic.

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