A Review of the Relative Merits of Low Powered WDXRF and EDXRF Spectrometers for Routine Quantitative Analysis

1990 ◽  
Vol 34 ◽  
pp. 193-199
Author(s):  
B. J. Price ◽  
J. Padur ◽  
N. S. Robson
Keyword(s):  
Quantitative Analysis ◽  
Energy Resolution ◽  
Spectral Resolution ◽  
X Ray ◽  
The Past

Historically, the development of XRF spectrometers has followed 2 main paths which are characterized by the means of spectral resolution they use. Those employing diffraction crystals and Braggs law to disperse the X-ray wavelengths are known as wavelength dispersive (WDX), whilst those usinq only the energy resolution of the detector, as enerqy dispersive (EDX). In the past these two have not normally been directly compared, because the WDX systems have always been the more expensive.

scholarly journals Atomic Data Needed for X-ray and EUV Astronomy

1992 ◽  
Vol 9 ◽  
pp. 573-574
Author(s):  
John C. Raymond
Keyword(s):  
Spectral Resolution ◽  
Atomic Data ◽  
Ionization State ◽  
Crystal Spectrometer ◽  
X Ray ◽  
Transmission Grating ◽  
Elemental Abundances ◽  
The Past ◽  
Accurate Temperature

AbstractThe astronomical X-ray and EUV satellites of the past generally had low enough spectral resolution that atomic data of modest quality was sufficient for most interpretation of the data. Typical proportional counter resolution Δ E/E ~ 1 permits a determination of the spectral shape sufficient for an estimate of the temperature of the emitting gas, but only the Fe K feature at 6.7 keV stands out as a distinct emission line. The higher spectral resolution Einstein Transmission Grating, Solid State Spectrometer, and Focal Plane Crystal Spectrometer instruments measured a score of emission lines or line blends, permitting determinations of the elemental abundances, temperature, and ionization state of the emitting gas. The higher spectral resolution and throughput of the BBXRT aboard the ASTRO mission and the instruments planned for EUVE, ASTRO-D, AXAF, and XMM will make possible a far more detailed analysis of the data. It should be possible to derive better abundances for more elements, accurate temperature distributions, electron densities, and accurate ionization states.

scholarly journals Binary Stucture of Accreting Neutron Stars

1998 ◽  
Vol 188 ◽  
pp. 105-106
Author(s):  
D.A. Leahy
Keyword(s):  
Neutron Stars ◽  
Spectral Resolution ◽  
Relevant Literature ◽  
Short Paper ◽  
X Rays ◽  
X Ray ◽  
The Past ◽  
Great Progress ◽  
Satellite Missions ◽  
X Ray Binaries

The study of X-ray binaries has made great progress with the advent in the past few years of a number of very capable X-ray astronomy missions. These are reviewed, for example, by Bradt et al 1992, and a set of recent relevant papers in Makino and Mitsuda, 1997. For example, ASCA has allowed a significant increase in sensitivity and spectral resolution in 0.5-10 keV X-rays (Tanaka et al 1994). Many recent Compton/GRO results on X-ray binaries are reviewed in the proceedings of the Second Compton Symposium (Fichtel et al 1994). Another source of recent results from analysis of data from several satellite missions is the proceedings of the Evolution of X-ray Binaries (Holt & Day, 1994). In this short paper, the emphasis is on guiding the reader to some relevant literature.

A Novel Method for Quantitative Analysis of Tetragonal Phase in Barium Titanate Powders by X-Ray Diffraction

2010 ◽  
Vol 156-157 ◽  
pp. 1006-1009
Author(s):  
Yong Ping Pu ◽  
Ning Xu ◽  
Xiao Long Chen
Keyword(s):  
Quantitative Analysis ◽  
Barium Titanate ◽  
Tetragonal Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Standard Curve ◽  
The Past ◽  
Integrated Intensity ◽  
Powder Samples ◽  
Novel Method

Quantitative analysis of tetragonal phase in barium titanate powders and fundament of standard curve was discussed from the result of X-ray diffraction (XRD) experiment via testing the standard series prepared powder samples. Some different conclusions compared with the past researches were drawn by analyzing the XRD data including the integrated intensity of a certain diffraction peak, difference in 2θ between peak (002) and (200) △2θ and d (interplanar spacing) value. Thus a useful method was provided for quantitative analysis tetragonal phase in barium titanate powders by synthesized by hydrothermal method.

Axial Observation of X-Ray Spectra from a Beam-Foil Source

1988 ◽  
Vol 102 ◽  
pp. 339-342
Author(s):  
J.M. Laming ◽  
J.D. Silver ◽  
R. Barnsley ◽  
J. Dunn ◽  
K.D. Evans ◽  
...  
Keyword(s):  
Spectral Resolution ◽  
Heavy Ion ◽  
Ion Beams ◽  
Beam Axis ◽  
Doppler Broadening ◽  
X Ray ◽  
Beam Foil

AbstractNew observations of x-ray spectra from foil-excited heavy ion beams are reported. By observing the target in a direction along the beam axis, an improvement in spectral resolution, δλ/λ, by about a factor of two is achieved, due to the reduced Doppler broadening in this geometry.

The Use of Advanced Analytical Techniques for Characterization of the Chemical, Physical, and Crystallographic Nature of a Surface

1973 ◽  
Vol 31 ◽  
pp. 132-133 ◽  
Author(s):  
R. E. Herfert
Keyword(s):  
Surface Characterization ◽  
Analytical Techniques ◽  
X Ray Diffraction ◽  
Depth Of Penetration ◽  
X Ray ◽  
The Past ◽  
Transmission Electron ◽  
Scanning Electron

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.

Quantification of Silica Uptake by Alveolar Macrophages - An Emperical Scanning Electron Microprobe Method

1982 ◽  
Vol 40 ◽  
pp. 332-333
Author(s):  
V. V. Damiano ◽  
R. P. Daniele ◽  
H. T. Tucker ◽  
J. H. Dauber
Keyword(s):  
Quantitative Analysis ◽  
Alveolar Macrophages ◽  
Bulk Sample ◽  
Silica Particles ◽  
Empirical Method ◽  
Phagocytic Cells ◽  
Calibration Standards ◽  
X Ray ◽  
Accurate Quantitative Analysis ◽  
Scanning Electron

An important example of intracellular particles is encountered in silicosis where alveolar macrophages ingest inspired silica particles. The quantitation of the silica uptake by these cells may be a potentially useful method for monitoring silica exposure. Accurate quantitative analysis of ingested silica by phagocytic cells is difficult because the particles are frequently small, irregularly shaped and cannot be visualized within the cells. Semiquantitative methods which make use of particles of known size, shape and composition as calibration standards may be the most direct and simplest approach to undertake. The present paper describes an empirical method in which glass microspheres were used as a model to show how the ratio of the silicon Kα peak X-ray intensity from the microspheres to that of a bulk sample of the same composition correlated to the mass of the microsphere contained within the cell. Irregular shaped silica particles were also analyzed and a calibration curve was generated from these data.

Lateral resolution of the electron microbeam analysis

1978 ◽  
Vol 36 (1) ◽  
pp. 542-543
Author(s):  
H.J. Dudek
Keyword(s):  
Quantitative Analysis ◽  
Depth Resolution ◽  
Lateral Resolution ◽  
Cylindrical Particle ◽  
Correction Procedure ◽  
X Ray ◽  
Element Concentrations ◽  
Microbeam Analysis ◽  
The Matrix

The chemical inhomogenities in modern materials such as fibers, phases and inclusions, often have diameters in the region of one micrometer. Using electron microbeam analysis for the determination of the element concentrations one has to know the smallest possible diameter of such regions for a given accuracy of the quantitative analysis.In th is paper the correction procedure for the quantitative electron microbeam analysis is extended to a spacial problem to determine the smallest possible measurements of a cylindrical particle P of high D (depth resolution) and diameter L (lateral resolution) embeded in a matrix M and which has to be analysed quantitative with the accuracy q. The mathematical accounts lead to the following form of the characteristic x-ray intens ity of the element i of a particle P embeded in the matrix M in relation to the intensity of a standard S

RNA polymerase: Preparation and structural analysis of helical polymers

1984 ◽  
Vol 42 ◽  
pp. 152-153
Author(s):  
E. Loren Buhle ◽  
Pamela Rew ◽  
Ueli Aebi
Keyword(s):  
Structural Analysis ◽  
Rna Polymerase ◽  
Molecular Level ◽  
X Ray Diffraction ◽  
Helical Polymers ◽  
X Ray ◽  
E Coli ◽  
The Past ◽  
Ordered Arrays ◽  
Low Ionic Strength

While DNA-dependent RNA polymerase represents one of the key enzymes involved in transcription and ultimately in gene expression in procaryotic and eucaryotic cells, little progress has been made towards elucidation of its 3-D structure at the molecular level over the past few years. This is mainly because to date no 3-D crystals suitable for X-ray diffraction analysis have been obtained with this rather large (MW ~500 kd) multi-subunit (α2ββ'ζ). As an alternative, we have been trying to form ordered arrays of RNA polymerase from E. coli suitable for structural analysis in the electron microscope combined with image processing. Here we report about helical polymers induced from holoenzyme (α2ββ'ζ) at low ionic strength with 5-7 mM MnCl2 (see Fig. 1a). The presence of the ζ-subunit (MW 86 kd) is required to form these polymers, since the core enzyme (α2ββ') does fail to assemble into such structures under these conditions.

Bence-albee after 25 years: A new superior α-factor correction procedure for the quantitative analysis of oxides and silicates

1992 ◽  
Vol 50 (2) ◽  
pp. 1744-1745
Author(s):  
John T. Armstrong
Keyword(s):  
Quantitative Analysis ◽  
Electron Microprobe ◽  
Binary Systems ◽  
Correction Procedure ◽  
Geological Samples ◽  
The Past ◽  
Large Matrix ◽  
Computational Speed ◽  
Microprobe Data ◽  
Geological Sciences

One of the most cited papers in the geological sciences has been that of Albee and Bence on the use of empirical " α -factors" to correct quantitative electron microprobe data. During the past 25 years this method has remained the most commonly used correction for geological samples, despite the facts that few investigators have actually determined empirical α-factors, but instead employ tables of calculated α-factors using one of the conventional "ZAF" correction programs; a number of investigators have shown that the assumption that an α-factor is constant in binary systems where there are large matrix corrections is incorrect (e.g, 2-3); and the procedure’s desirability in terms of program size and computational speed is much less important today because of developments in computing capabilities. The question thus exists whether it is time to honorably retire the Bence-Albee procedure and turn to more modern, robust correction methods. This paper proposes that, although it is perhaps time to retire the original Bence-Albee procedure, it should be replaced by a similar method based on compositiondependent polynomial α-factor expressions.

Quantitative Analysis Of X-Ray Images From Geological Materials

1990 ◽  
Vol 48 (2) ◽  
pp. 244-245
Author(s):  
J. M. Paque ◽  
R. Browning ◽  
P. L. King ◽  
P. Pianetta
Keyword(s):  
Quantitative Analysis ◽  
Bulk Composition ◽  
Principal Component ◽  
Analytical Description ◽  
Bulk Sample ◽  
Geological Samples ◽  
X Ray ◽  
Software And Hardware ◽  
And Storage ◽  
Insight Into

Geological samples typically contain many minerals (phases) with multiple element compositions. A complete analytical description should give the number of phases present, the volume occupied by each phase in the bulk sample, the average and range of composition of each phase, and the bulk composition of the sample. A practical approach to providing such a complete description is from quantitative analysis of multi-elemental x-ray images.With the advances in recent years in the speed and storage capabilities of laboratory computers, large quantities of data can be efficiently manipulated. Commercial software and hardware presently available allow simultaneous collection of multiple x-ray images from a sample (up to 16 for the Kevex Delta system). Thus, high resolution x-ray images of the majority of the detectable elements in a sample can be collected. The use of statistical techniques, including principal component analysis (PCA), can provide insight into mineral phase composition and the distribution of minerals within a sample.

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