scholarly journals Development and Performance Evaluation of Very High Early Strength Geopolymer for Rapid Road Repair

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Abideng Hawa ◽  
Danupon Tonnayopas ◽  
Woraphot Prachasaree ◽  
Pichai Taneerananon

High early strength is the most important property of pavement repair materials to allow quick reopening to traffic. With this in mind, we have experimentally investigated geopolymers using low cost raw materials available in Thailand. The geopolymer mortar was metakaolin (MK), mixed with parawood ash (PWA, rubberwood ash) or oil palm ash (OPA) as binder agent. Rubberwood is often used as raw material for biomass power plants in Thailand, especially at latex glove factories and seafood factories, and burning rubberwood generates PWA. Both PWA and OPA are therefore low cost residual waste, locally available in mass quantities. The geopolymer samples were characterized for compressive strength, drying shrinkage, and bond strength to Portland cement mortar with slant shear test. The experimental design varied the contents of PWA and OPA and the heat curing time (1, 2 and 4 h) after hot mixture process. The hot mixture process resulted in very high early strength. In addition, we achieved high compressive strengths, low drying shrinkage, and very significant bond strength enhancement by use of the ashes.

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Abideng Hawa ◽  
Danupon Tonnayopas ◽  
Woraphot Prachasaree

This study reports on the microstructure, compressive strength, and drying shrinkage of metakaolin (MK) based geopolymers produced by partially replacing MK by oil palm ash (OPA). The OPA was used as raw material producing different molar ratios of SiO2/Al2O3and CaO/SiO2. The geopolymer samples were cured at 80°C for 1, 2, or 4 hours and kept at ambient temperature until testing. The compressive strength was measured after 2, 6, and 24 hours and 7 and 28 days. The testing results revealed that the geopolymer with 5% OPA (SiO2 : Al2O3 = 2.88 : 1) gave the highest compressive strength. Scanning electron microscopy (SEM) indicated that the 5% OPA sample had a dense-compact matrix and less unreacted raw materials which contributed to the higher compressive strength. In the X-ray diffraction (XRD) patterns, the change of the crystalline phase after heat curing for 4 hours was easily detectable compared to the samples subjected to a shorter period of heat curing.


2018 ◽  
Vol 7 (2) ◽  
Author(s):  
Firman L. Sahwan

Organic materials that are generally used as raw material for organic fertilizer granules (POG) is a natural organic material that has been degrade, smooth and dry. One of the main raw materials are always used with a very high percentage of usage, is manure. Manure potential in Indonesia is very high, amounting to 113.6 million tons per year, or 64.7 million tons per year to the island of Java. From this amount, it will be generated numbers POG production potential of 17.5 million tons per year (total Indonesia) or 9.9 million tons per year for the island of Java. While the realistic POG production predictions figures made from raw manure is 2.5 million tons annually, a figure that has been unable to meet the number requirement of POG greater than 4 million tons per year. Therefore, in producing POG, it should be to maximize the using of the potential of other organic materials so that the use of manure can be saved. With the use of a small amount of manure (maximum 30% for cow manure), it would be useful also to avoid the production of POG with high Fe content.keywods: organic material, manure, granule organic fertilizer


2000 ◽  
Vol 15 (1) ◽  
pp. 2-8 ◽  
Author(s):  
N.C. Wagner ◽  
S. Ramaswamy ◽  
U. Tschirner

AbstractA pre-economic feasibility study was undertaken to determine the potential of cereal straw for industrial utilization in Minnesota. Specifically, utilizing straw for pulp and paper manufacture was of interest. The availability of cereal straw fiber supplies at various locations across the state of Minnesota, along with pre-processing issues such as transportation, harvesting, handling, and storage, are discussed and priced. The greatest economic advantage of straw for industrial use appears to be the low cost of the raw material compared to traditional raw materials. This also provides an excellent opportunity for additional income for farmers. The methodology and information provided here should be helpful in evaluating the feasibility of utilizing straw for other industrial purposes in other parts of the world. However, in some Third World countries, long-standing on-farm, traditional uses of cereal straws for fuel, fiber, and animal feed may limit their availability for industrial utilization.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Lokesh Kumar ◽  
Susanta Kumar Jana

Abstract Sulfur dioxide is considered as an extremely harmful and toxic substance among the air pollutants emitted from the lignite- and other high-sulfur-coal based power plants, old tires processing units, smelters, and many other process industries. Various types of absorbents and desulfurization technologies have been developed and adopted by the industries to reduce the emission rate of SO2 gas. The present paper focuses on the ongoing advances in the development of varieties of regenerative and non-regenerative absorbents viz., Ca-based, Mg-based, Fe-based, Na-based, N2-based, and others along with various FGD technology, viz., wet, dry or semi-dry processes. Additionally, different types of contactors viz., packed column, jet column, spray tower, and slurry bubble columns along with their significant operational and design features have also been discussed. In the existing or newly installed limestone-based FGD plants, an increasing trend of the utilization of newly developed technologies such as limestone forced oxidation (LSFO) and magnesium-enhanced lime (MEL) are being used at an increasing rate. However, the development of low-cost sorbents, particularly suitable solid wastes, for the abatement of SO2 emission needs to be explored sincerely. Many such wastes cause air pollution by way of entrainment of fine particulate matter (PM), groundwater contamination by its leaching, or brings damage to crops due to its spreading onto the cultivation land. One such pollutant is marble waste and in this work, this has been suggested as a suitable substitute to limestone and cost-effective sorbent for the desulfurization of flue gases. The product of this process being sellable in the market or may be used as a raw material in several industries, it can also prove to be an important route of recycling and reuse of one of the air and water-polluting solid wastes.


Proceedings ◽  
2018 ◽  
Vol 2 (23) ◽  
pp. 1467 ◽  
Author(s):  
José Ignacio Arranz ◽  
María Teresa Miranda ◽  
Francisco José Sepúlveda ◽  
Irene Montero ◽  
Carmen Victoria Rojas

Brewing industry generates a main residue, brewers’ spent grain (BSG), which has good properties both for use in animal consumption and for thermal use, but contains a very high content of moisture (20–25% dry matter content), so that its elimination or treatment should be immediate, since it can cause degeneration problems of the product. Currently, brewers often supply this material at low cost for use as livestock feed. This solution is not efficiently carried out without reporting too much benefit to the brewers more than to eliminate waste from their facilities. However, BSG is a raw material of interest for application in different areas due to its low price, availability throughout the year and a valuable chemical composition, so it seems necessary to look for an alternative use to give value to these characteristics. In this paper a drying study is carried out in order to establish the foundations for its energy use by thermal of BSG. BSG has been used from a craft brewery located at Badajoz, Spain. Drying analysis was carried out for various temperatures and inlet air flow by means a convective dryer. The properties studied show that BSG can be used for thermal utilization in large installations, being necessary heat drying processes as a pretreatment in order to obtain a biofuel with acceptable efficiency.


2018 ◽  
Vol 56 ◽  
pp. 04003
Author(s):  
Sergei Tkach

The article deals with the problems of mineral raw material losses of quality and quantity management in developing of large-scale complex-structure and composition deposits of solid minerals. It is shown that a very high degree of mining and geological conditions variability in time and space for the development of mining units is typical for such deposits. This significantly complicates the qualitative and quantitative operating losses setting and accounting of mineral raw materials during its extraction in the framework of existing general and industry regulatory documents. Conceptual principles for face-by-face operational setting of losses and impoverishment of minerals for the conditions of bulk mining of complex-structure deposits with the formation of gross mining flow with economically feasible and specified level of quality (the content of commercial and harmful components) are stated. These principles generally do not contradict effective instructions main provisions and are made to minimize the total operating losses during the processing of several mine sections (faces).


2014 ◽  
Vol 936 ◽  
pp. 986-991
Author(s):  
Chuan Hui Gao ◽  
Li Ding ◽  
Yu Min Wu ◽  
Chuan Xing Wang ◽  
Jun Xu

A low-cost raw material, bittern obtained from the production process of sea salt, was used to prepare magnesium oxysulfate hydrate (MgSO4·5Mg (OH)2·2H2O, abbreviated as 152MOS) whiskers via hydrothermal synthesis with ammonia and magnesium sulfate as the other starting raw materials. The bittern was firstly filtered and then used directly without de-coloring. X-ray powder diffraction (XRD), transmission electron microscope (TEM), selected area electron diffraction (SAED), energy dispersive X-ray spectroscopy (EDX) and scanning electron microscope (SEM) were employed to investigate the composition and morphology of the products. It was found that the 152MOS whiskers synthesized from bittern at 190°C for 3 hours exhibited fanlike morphology. The formation of the fanlike whiskers was inhibited and most of the whiskers presented as single fibers when ethanol was used as crystal control agent in the hydrothermal process. From the two-dimensional steps observed at tips of the whiskers, a possible growth mechanism was speculated that it was the extension of dislocations that made the growth of the whiskers.


2020 ◽  
Author(s):  
Katarina Šter ◽  
Sabina Kramar

<p>Al-rich mineral resources are one of the essential components for the production of the novel sustainable mineral binders. Belite-sulfoaluminate (BCSA) cements, which are considered as low-carbon and low-energy, allows the substitution of natural raw materials with secondary ones. In East-Southeast European countries (ESEE) there are huge amounts of various industrial and mine residues that are either landfilled or currently have a low recycling rate. These residues are generated from mining activities (mine waste) and as a by product of different types of industry, such as thermal power plants, steel plants or the aluminium industry (slags, ashes, red mud, etc.). Within the framework of the RIS-ALiCE project, in cooperation with 15 project partners from Slovenia, Austria, France, Hungary, Serbia, Bosnia and Herzegovina and Macedonia, a network of relevant stakeholders has been established in the field of currently unused aluminium-containing mine and industrial residues. Inside the created network mine and industrial residues have been mapped and valorised in order to evaluate their suitability for the use in innovative and sustainable low CO<sub>2</sub>-mineral binder production. Aluminium-containing residues are characterized with respect to their chemical, physical and radiological composition using different analytical methods such as X ray fluorescence spectroscopy, ICP optical emission spectrophotometry, gravimetry, X ray powder diffraction, gamma spectroscopy, etc. The long-term activity of network between wastes holders/producers and mineral end users will be enabled via developed Al-rich residues registry, including a study of the potential technological, economic and environmental impacts of applying the innovative methodology of the sustainable secondary raw materials management in ESEE region. Developed registry with the data valuable for both, waste providers as waste users in ESEE region, can be later-on upscaled also to other regions of Europe. It will provide the data on the available and appropriate Al-rich secondary resources, which will enablethe production of innovative low-CO<sub>2 </sub>cements.</p><p><strong>Keywords:</strong> secondary raw material, alternative binders, Al-rich residues, networking, mapping, valorisation, registry.</p>


2012 ◽  
Vol 724 ◽  
pp. 103-106
Author(s):  
Yoo Taek Kim ◽  
Chang Sub Jang ◽  
Yun Jae Choi

This study was conducted to evaluate the feasibility of using bottom ash after magnetic separation and dredged soil from the coal power plants as raw materials for artificial lightweight aggregate (ALA). The dependence of composition and sintering temperature on physical properties of ALA was investigated. Fe compounds play an important role in the bloating reaction, thus specimens containing more ferrous materials such as Fe3O4 are more easily bloated. Both black core region and bloating phenomenon were increased with an increase in the contents of dredged soil. Specimens made use of MBA(Magnetic separated bottom ash which has magnetic components) showed lower bulk density than those of NMBA(non-magnetic separated bottom ash which has much less ferrous materials. It was confirmed that MBA could be used as an effective raw material for making ALA having low density because the ferrous components in it act as bloating agents.


Author(s):  
M. Kurylo ◽  
V. Bala

The purpose of this study is to analyze and systematize criteria by which, in domestic and international practice, the industrial value of coal deposits with small and insignificant reserves is determined. The analysis and systematization of such factors in general for all coal deposits with the definite definition of the most influential characteristics for small stocks are carried out. Mining and geological factors, which are caused by natural characteristics of the deposit and directly related to the concrete object, are determined, and there have been singled out factors concerning the minerals in general or characterizing the external conditions of industrial development of deposits. For coal deposits with insignificant reserves, the criteria that directly affect the most critical parameter - the value of coal reserves and, consequently, the lifetime of the mining enterprise have paramount importance. Such criteria are the quality of coal, which defines the direction of use and its liquidity, the degree of geological study, which expresses the geological risks of reserves confirmation, and the complexity of mining technical conditions that define methods and systems for the reserves disclosure and development. In general, external factors for coal deposits are most affected by the availability of raw material substitutes and market conditions, and coal prices. For deposits with insignificant reserves, prices and possibility of mining, which involves availability of licenses and social permits, may have a greater impact. Industrial significance of deposit with insignificant reserves may appear favorable of all other conditions of development - mining and technical conditions that form low cost of production, coal quality, favorable market conditions for mineral raw materials, localization of the deposit near consumers, etc. At the same time, the main prerequisite for attracting objects with insignificant reserves to exploitation should be their high degree of geological study. Decision about possible industrial significance should be taken after detailed technical and economic calculations.


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