scholarly journals Numerical Simulation of Decontamination of Airborne Fission Products during In-Vessel Release Phase by Containment Spray

2018 ◽  
Vol 2018 ◽  
pp. 1-19
Author(s):  
Khurram Mehboob
Keyword(s):  
Droplet Size ◽  
Failure Time ◽  
Ph Value ◽  
Removal Rate ◽  
Droplet Diameter ◽  
Fission Products ◽  
Product Release ◽  
Spray System ◽  
Spray Solution ◽  
Proposed Model

The containment spray system (CSS) has a significant role in limiting the risk of radioactive exposure to the environment. In this work, the optimal droplet size and pH value of spray water to prevent the fission product release have been evaluated to improve the performance of the spray system during in-vessel release phase. A semikinetic model has been developed and implemented in MATLAB. The sensitivity and removal rate of airborne isotopes with the spray system have been simulated versus the spray activation and failure time, droplet size, and pH value. The alkaline (Na2S2O3) spray solution and spray water with pH 9.5 have similar scrubbing properties for iodine. However, the removal rate from the CSS has been found to be an approximately inverse square of droplet diameter (1/d2) for Na2S2O3 and higher pH of spray water. The numerical results showed that 450 μm–850 μm droplet with 9.5 pH and higher or the alkaline (Na2S2O3) solution with 0.2 m3/s–0.35 m3/s flow rate is optimal for effective scrubbing of in-containment fission products. The proposed model has been validated with TOSQAN experimental data.

Effect of Spray System on in Containment Fission Product Washout During In-Vessel Release Phase

2017 ◽  
Author(s):  
Khurram Mehboob ◽  
Mohammad. S. Aljohani
Keyword(s):  
Sensitivity Analysis ◽  
Droplet Size ◽  
Removal Rate ◽  
Absorption Efficiency ◽  
Radioactive Isotopes ◽  
Activation Time ◽  
Spray System ◽  
Loss Of Coolant Accident ◽  
Loss Of Coolant ◽  
Mean Size

The response of containment sprinkles during the in-vessel release phase of low-pressure loss of coolant accident (LOCA) has for two-loop PWR been simulated. Cleaning and wash out of radioactive isotopes is essential to limit the risk of radioactive exposure. An uncontrolled LOCA has been selected for this study. In this work, numerical simulation of spray system with its parameter has been carried out to study the sensitivity analysis of airborne radioactive isotopes on spray system parameters. Therefore, we have developed a kinetic model and implemented in MATLAB which used the ORIGEN 2.2 as a subroutine code. The sensitivity analysis and airborne isotopes and removal rate has been carried out for spray activation time, droplet size. It has been seen that the droplets mean size plays an important role in containment washout. The droplet absorption ratio indicates that the smaller droplet size has higher absorption efficiency.

Invert Emulsion Droplet Size and Mycoherbicidal Activity ofColletotrichum truncatum

1993 ◽  
Vol 7 (2) ◽  
pp. 417-424 ◽  
Author(s):  
Grant H. Egley ◽  
James E. Hanks ◽  
C. Douglas Boyette
Keyword(s):  
Droplet Size ◽  
Droplet Diameter ◽  
Colletotrichum Truncatum ◽  
Emulsion Droplet ◽  
Conidia Germination ◽  
Spray System ◽  
Invert Emulsion ◽  
Hemp Sesbania ◽  
Appressoria Formation ◽  
Better Than

When formulated and sprayed in an invert emulsion (IE), conidia of the mycoherbicide,Colletotrichum truncatum, controlled hemp sesbania in the absence of dew. To optimize hemp sesbania control, formulation droplet size influence upon the pathogen's germination and pathogenicity was investigated. Conidia germination in manually produced IE droplets decreased from 46% to 5% as droplet diameter decreased from 2700 to 900μm. Droplet size did not affect appressoria formation. On a per conidium basis, 900-μm droplets were more pathogenic to detached hemp sesbania leaves than were 2100-μm droplets. An air-assist spray system produced droplet spectra with volume median diameters of 421 and 104μm, respectively. The spectrum of smaller droplets covered the target better than did that of larger droplets. When applied to whole hemp sesbania plants in greenhouse trials, conidia in the smaller and larger droplet spectra gave 90 and 94% control, respectively. Sufficient conidia germinated in IE droplets of a variety of sizes to control hemp sesbania excellently.

scholarly journals Lignocellulose@ Activated Clay Nanocomposite with Hierarchical Nanostructure Enhancing the Removal of Aqueous Zn(II)

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1710 ◽  
Author(s):  
Xiaotao Zhang ◽  
Yinan Hao ◽  
Zhangjing Chen ◽  
Yuhong An ◽  
Wanqi Zhang ◽  
...  
Keyword(s):  
Ph Value ◽  
Removal Rate ◽  
Weight Ratio ◽  
Order Kinetic ◽  
Adsorption Parameters ◽  
Hierarchical Nanostructure ◽  
Desorption Temperature ◽  
Desorption Time ◽  
Adsorption Temperature ◽  
Hcl Concentration

A lignocellulose@ activated clay (Ln@AC) nanocomposite with a hierarchical nanostructure was successfully synthesized by the chemical intercalation reaction and applied in the removal of Zn(II) from an aqueous solution. Ln@AC was characterized by N2 adsorption/desorption isotherms and X-Ray Diffraction (XRD), scanning Electron Microscope (SEM), transmission Electron Microscopy (TEM) and Fourier Transform Infrared Spectroscopy (FTIR) analysis, and the results indicate that an intercalated–exfoliated hierarchical nanostructure was formed. The effects of different adsorption parameters on the Zn(II) removal rate (weight ratio of Ln to AC, Ln@AC dosage, initial Zn(II) concentration, pH value, adsorption temperature, and time) were investigated in detail. The equilibrium adsorption capacity reached 315.9 mg/g under optimal conditions (i.e., the weight ratio of Ln to AC of 3:1, Ln@AC dosage of 1 g/L, initial Zn(II) concentration of 600 mg/L, pH value of 6.8, adsorption temperature of 65 °C, and adsorption time of 50 min). The adsorption process was described by the pseudo-second-order kinetic model, Langmuir isotherm model, and the Elovich model. Moreover, Zn(II) could be easily eluted by HCl, and the effects of HCl concentration, desorption temperature, and ultrasonic desorption time on desorbed amount were tested. Desorption studies revealed that with an HCl concentration of 0.25 mol/L, desorption temperature of 70 °C, and ultrasonic desorption time of 20 min, the maximum desorption capacity and efficiency were achieved at 202.5 mg/g and 64.10%, respectively. Regeneration experimental results indicated that the Ln@AC exhibited a certain recyclable regeneration performance. Due to such outstanding features, the novel Ln@AC nanocomposite proved to have great adsorption potential for Zn(II) removal from wastewater, and exhibited an extremely significant amount of adsorbed Zn(II) when compared to conventional adsorbents.

scholarly journals Product inhibition studies on bovine liver carbamoyl phosphate synthetase

1974 ◽  
Vol 141 (3) ◽  
pp. 817-824 ◽  
Author(s):  
Keith R. F. Elliott ◽  
Keith F. Tipton
Keyword(s):  
Inorganic Phosphate ◽  
Substrate Binding ◽  
Inorganic Ions ◽  
Bovine Liver ◽  
Product Inhibition ◽  
Carbamoyl Phosphate Synthetase ◽  
Carbamoyl Phosphate ◽  
Product Release ◽  
Proposed Model ◽  
Inhibition Studies

A study of the product-inhibition patterns of carbamoyl phosphate synthetase from bovine liver is reported. Inhibition by adenosine, AMP and inorganic ions is also reported. The results are in agreement with the previously proposed model in which the order of substrate binding is ATPMg, followed by HCO3−, ATPMg and NH4+. The order of product release on the basis of the reported results is carbamoyl phosphate, followed by ADPMg, ADPMg and inorganic phosphate.

Study on Spray on Degradation of TNT-RDX Explosives Wastewater by Synergetic Ozonation

2013 ◽  
Vol 726-731 ◽  
pp. 2316-2319
Author(s):  
Hai Xia Duan
Keyword(s):  
Gas Phase ◽  
Removal Rate ◽  
Droplet Diameter ◽  
Cod Removal ◽  
The Self ◽  
Cod Removal Rate

TNT-RDX wastewater is hard to biodegrade and highly toxic. The self-made reactor was used to degrade the wastewater, spray and the conditions of droplet diameter, number of nozzle, spray height were clearly observed. The results show that the average COD removal rate of TNT-RDX wastewater was 69.6%.The spray conditions can improve the dispersion of the wastewater and increase the use of the residual ozone in gas phase. Keywords: Spray; TNT-RDX wastewater; ozone; UV; GAC

scholarly journals Adsorption of aquatic Cd2+ using a combination of bacteria and modified carbon fiber

2017 ◽  
Vol 36 (3-4) ◽  
pp. 857-871 ◽  
Author(s):  
Chao Xue ◽  
Peishi Qi ◽  
Yunzhi Liu
Keyword(s):  
Aqueous Solution ◽  
Composite Material ◽  
Carbon Fiber ◽  
Active Sites ◽  
Ph Value ◽  
Removal Rate ◽  
Sorption Process ◽  
Acid Sites ◽  
Heterogeneous Distribution ◽  
Carbon Fiber Material

Batch experiments were conducted to investigate the capacity and mechanisms for adsorbing Cd2+ from aqueous solutions by the composite material. The composite material was manufactured with Plesiomonas shigelloides strain H5 and modified polyacrylonitrile-based carbon fiber. Experimental results showed that the surface areas of modified polyacrylonitrile-based carbon fiber increased by 58.54% and pore width increased by 40.19% compared with unmodified polyacrylonitrile-based carbon fiber. Boehm’s titration results show the surface acid sites of composite material were increased by 712% compared with unmodified polyacrylonitrile-based carbon fiber. The field emission scanning electron microscope results show P. shigelloides H5 can be grown on the surface of modified polyacrylonitrile-based carbon fiber closely. The equilibrium removal rate and sorption quantity of composite material were 71.56% and 7.126 mg g−1, respectively. With the pH value of aqueous solution increased, the removal rate of Cd2+ ions was also increased, but the change of temperature and ionic strength had no significant effect on the removal rate. Furthermore, the results showed the whole sorption process was a good fit to Lagergren pseudo-second-order model and Freundlich isotherms model. Therefore, the results infer that there was a heterogeneous distribution of active sites, and then the sorption process was chemical adsorption and multilayer adsorption. In a word, microbial composite carbon fiber material can adsorb Cd2+ ions from aqueous solution effectively, which might be helpful in wastewater treatment in the future.

Evaluation of Models for Droplet Shear Effect of Centrifugal Pump

2018 ◽  
Author(s):  
Ramin Dabirian ◽  
Shihao Cui ◽  
Ilias Gavrielatos ◽  
Ram Mohan ◽  
Ovadia Shoham
Keyword(s):  
Experimental Data ◽  
Size Distribution ◽  
Centrifugal Pump ◽  
Droplet Size ◽  
Separation Efficiency ◽  
Droplet Diameter ◽  
Droplet Size Distribution ◽  
Production Equipment ◽  
Transportation Equipment ◽  
Log Normal

During the process of petroleum production and transportation, equipment such as pumps and chokes will cause shear effects which break the dispersed droplets into smaller size. The smaller droplets will influence the separator process significantly and the droplet size distribution has become a critical criterion for separator design. In order to have a better understanding of the separation efficiency, estimation of the dispersed-phase droplet size distribution is very important. The objective of this paper is to qualitatively and quantitatively investigate the effect of shear imparted on oil-water flow by centrifugal pump. This paper presents available published models for the calculation of droplet size distribution caused by different production equipment. Also detailed experimental data for droplet size distribution downstream of a centrifugal pump are presented. Rosin-Rammler and Log-Normal Distributions utilizing dmax Pereyra (2011) model as well as dmin Kouba (2003) model are used in order to evaluate the best fit distribution function to simulate the cumulative droplet size distribution. The results confirm that applying dmax Pereyra (2011) model leads to Rosin-Rammler distribution is much closer to the experimental data for low shear conditions, while the Log-Normal distribution shows better performance for higher shear rates. Furthermore, the predictions of Modified Kouba (2003) dmin model show good results for predicting the droplet distribution in centrifugal pump, and even better predictions under various ranges of experiments are achieved with manipulating cumulative percentage at minimum droplet diameter F(Dmin).

A stochastic covariate failure model for assessing system reliability

2001 ◽  
Vol 38 (03) ◽  
pp. 761-767 ◽  
Author(s):  
Nader Ebrahimi
Keyword(s):  
System Reliability ◽  
Alternative Model ◽  
Failure Time ◽  
Failure Mechanisms ◽  
Failure Model ◽  
Proposed Model ◽  
Deterioration Process

Many failure mechanisms can be traced to an underlying deterioration process, and stochastically changing covariates may influence this process. In this paper we propose an alternative model for assessing a system's reliability. The proposed model expresses the failure time of a system in terms of a deterioration process and covariates. When it is possible to measure deterioration as well as covariates, our model provides more information than failure time for the purpose of assessing and improving system reliability. We give several properties of our proposed model and also provide an example.

A Study of Fenton’s Oxidation Pretreatment on Dye Wastewater Containing Acetic Acid

2014 ◽  
Vol 1044-1045 ◽  
pp. 215-218
Author(s):  
Xian Huan Qiu ◽  
Hai Yu ◽  
Peng Fei Deng
Keyword(s):  
Acetic Acid ◽  
Processing Time ◽  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Dye Wastewater ◽  
Fenton’S Oxidation ◽  
Effects Of Ph ◽  
Cod Removal Rate ◽  
Fenton's Oxidation

In the presence of acetic acid, the effects of pH, processing time, addition of Fe2+ and H2O2 on dye wastewater treatment were studied. Experimental results showed that in the presence of acetic acid, when the pH value was 4, the processing time was 30.0min, addition of ferrous sulfate was 4.8g/L, and addition of hydrogen peroxide was 56mL/L, the treatment effect was the best, COD removal rate reached 51.0%. Further studied of the effect of the presence of acetic acid on Fenton’s oxidation of dye wastewater, the results showed that without of acetic acid, the COD removal rate was higher than that with acetic acid. And the effect of Fenton's reagent on oxidation of dye substances was interfered by the presence of acetic acid.

Nanoparticle Fe3O4 magnetized activated carbon from Armeniaca sibirica shell for the adsorption of Hg(II) ions

BioResources ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. 6100-6120
Author(s):  
Yinan Hao ◽  
Yanfei Pan ◽  
Qingwei Du ◽  
Xudong Li ◽  
Ximing Wang
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Ph Value ◽  
Removal Rate ◽  
Freundlich Isotherm ◽  
Entropy Change ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Adsorption Parameters ◽  
Initial Concentration

Armeniaca sibirica shell activated carbon (ASSAC) magnetized by nanoparticle Fe3O4 prepared from Armeniaca sibirica shell was investigated to determine its adsorption for Hg2+ from wastewater. Fe3O4/ASSAC was characterized using XRD (X-ray diffraction), FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy), and BET (Brunauer–Emmett–Teller). Optimum adsorption parameters were determined based on the initial concentration of Hg2+, reaction time, reaction temperature, and pH value in adsorption studies. The experiment results demonstrated that the specific surface area of ASSAC decreased after magnetization; however the adsorption capacity and removal rate of Hg2+ increased 0.656 mg/g and 0.630%, respectively. When the initial concentration of Hg2+ solution was 250 mg/L and the pH value was 2, the adsorption time was 180 min and the temperature was 30 °C, and with the Fe3O4/ASSAC at 0.05 g, the adsorption reaching 97.1 mg/g, and the removal efficiency was 99.6%. The adsorption capacity of Fe3O4/ASSAC to Hg2+ was in accord with Freundlich isotherm models, and a pseudo-second-order kinetic equation was used to fit the adsorption best. The Gibbs free energy ΔGo < 0，enthalpy change ΔHo < 0, and entropy change ΔSo < 0 which manifested the adsorption was a spontaneous and exothermic process.

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