The Effect of Sulfonated Graphene on the Rheological Properties of Cement Paste

2020 ◽  
Vol 20 (12) ◽  
pp. 7495-7505
Author(s):  
Jia-Ming Wu ◽  
Guo-Jian Jing ◽  
Xiao-Lei Lu ◽  
Tian-Yu Lei ◽  
Shu-Xian Wang ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Cement Paste ◽  
Chemical Interaction ◽  
Cementitious Materials ◽  
Rheological Parameters ◽  
Physical Interaction ◽  
Mechanical And Thermal Properties ◽  
Practical Application ◽  
Sulfonated Graphene ◽  
Modified Graphene

With unique 2D nanostructures and excellent properties, graphene and its derivatives are a class of advanced nanosized reinforcements for cementitious materials. Sulfonated graphene (SG), one of the most important modified graphene materials, possesses sulfonate groups on the surface and significantly improves the mechanical and thermal properties of cement-based composites. It is important to investigate the influence of SG on cement-based materials as it is a prerequisite for practical applications. Herein, SG was prepared and introduced into cement paste to investigate its influence on the rheological properties of cement paste. With the increased addition of SG, a stable slurry was gradually obtained with low fluidity and high rheological parameters. The mechanism of the SG effect on the rheological properties of cement paste was also illustrated. Because of the high specific surface area and sulfonate groups of SG nanosheets, a large amount of flocculated structure was created by the complexing effect, chemical interaction, physical interaction and mechanical interlocking between SG and hydrated/unhydrated cement particles. Furthermore, polycarboxylate ether (PCE) superplasticizer was introduced to ensure fluidity and transportability in the practical application of SG. The results in this work lay a foundation for the practical application of modified graphene in cementitious materials.

scholarly journals Influence of polymer fibers on rheological properties of cement mortars

2017 ◽  
Vol 7 (1) ◽  
pp. 228-236 ◽  
Author(s):  
Dorota Malaszkiewicz
Keyword(s):  
Rheological Properties ◽  
Volume Fraction ◽  
Fiber Type ◽  
Cementitious Materials ◽  
Plastic Viscosity ◽  
Synthetic Fiber ◽  
Rheological Parameters ◽  
Model Parameters ◽  
Fine Aggregate ◽  
Bingham Model

AbstractThe reinforcing effect of fibers in cement composites often results in the improvement of the brittle nature of cementitious materials. But the decrease in the workability of fresh concrete is often the disadvantage of fibers addition. Conventional single-point workability tests cannot characterize workability of concrete in terms of fundamental rheological parameters. To this end, this paper describes an investigation of the influence of synthetic fiber additions (fiber length in the range 12–50 mm and volume fraction in the range 0–4%) on the rheological properties of fiber reinforced fresh mortar (FRFM) and development of these properties over time. The rheometer Viskomat XL was used in this study. Within the limitations of the instrument and testing procedure it is shown that FRFMs conform to the Bingham model. Natural postglacial sand 0/4 mm was used as a fine aggregate and cement CEMI 42.5 R was used as a binder. Three commercial synthetic fibers were selected for these examinations. Rheological properties were expressed in terms of Bingham model parameters g (yield value ) and h (plastic viscosity). Based on the test results it was found out that the fiber type and volume fraction affected both the yield stress and plastic viscosity.

scholarly journals Effects of Volume Fraction and Surface Area of Aggregates on the Static Yield Stress and Structural Build-Up of Fresh Concrete

2020 ◽  
Author(s):  
Irina Ivanova ◽  
Viktor Mechtcherine
Keyword(s):  
Rheological Properties ◽  
Yield Stress ◽  
Surface Area ◽  
Cement Paste ◽  
Volume Fraction ◽  
Fresh Concrete ◽  
Total Surface Area ◽  
Rheological Parameters ◽  
Static Yield ◽  
Static Yield Stress

With increasing interest in the use of additive manufacturing techniques in the construction industry, static rheological properties of fresh concrete have necessarily come into focus. In particular, the knowledge and control of static yield stress (SYS) and its development over time are crucial for mastering formwork-free construction, e.g. by means of layered extrusion. Furthermore, solid understanding of the influences of various concrete constituents on the initial SYS of the mixture and the structural build-up rate is required for purposeful material design. This contribution is concentrated on the effect of aggregates on these rheological parameters. The volume fraction of aggregates was varied in the range of 35 to 55 % by volume under condition of constant total surface area of the particles. The total surface area per unit volume of cement paste was equal to 5.00, 7.25 and 10.00 m²/l, conditioned on the constant volume fraction of aggregates. Both variations were enabled by changing the particle size distributions of the aggregates while holding the cement paste composition constant for all concrete mixtures. To characterise the SYS and the structural build-up, constant shear rate tests with a vane-geometry rotational rheometer were performed. It was found that in the ranges under investigation the variation in volume fraction had a more pronounced effect on the static rheological properties of concrete than did the variation in surface area. An accurate mathematical description of the relationship between the initial SYS of concrete and the relative volume fraction of aggregate based on the Chateau-Ovarlez-Trung model was proposed. Challenges in deriving a similar relationship for the structural build-up rate of concrete were highlighted.

scholarly journals Effects of Volume Fraction and Surface Area of Aggregates on the Static Yield Stress and Structural Build-Up of Fresh Concrete

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1551 ◽  
Author(s):  
Irina Ivanova ◽  
Viktor Mechtcherine
Keyword(s):  
Rheological Properties ◽  
Yield Stress ◽  
Surface Area ◽  
Cement Paste ◽  
Volume Fraction ◽  
Fresh Concrete ◽  
Total Surface Area ◽  
Rheological Parameters ◽  
Static Yield ◽  
Static Yield Stress

With increasing interest in the use of additive manufacturing techniques in the construction industry, static rheological properties of fresh concrete have necessarily come into focus. In particular, the knowledge and control of static yield stress (SYS) and its development over time are crucial for mastering formwork-free construction, e.g., by means of layered extrusion. Furthermore, solid understanding of the influences of various concrete constituents on the initial SYS of the mixture and the structural build-up rate is required for purposeful material design. This contribution is concentrated on the effect of aggregates on these rheological parameters. The volume fraction of aggregates was varied in the range of 35% to 55% by volume under condition of constant total surface area of the particles. The total surface area per unit volume of cement paste was equal to 5.00, 7.25 and 10.00 m²/L, conditioned on the constant volume fraction of aggregates. Both variations were enabled by changing the particle size distributions of the aggregates while holding the cement paste composition constant for all concrete mixtures. To characterise the SYS and the structural build-up, constant shear rate tests with a vane-geometry rotational rheometer were performed. It was found that in the ranges under investigation the variation in volume fraction had a more pronounced effect on the static rheological properties of concrete than did the variation in surface area. An accurate mathematical description of the relationship between the initial SYS of concrete and the relative volume fraction of aggregate based on the Chateau–Ovarlez–Trung model was proposed. Challenges in deriving a similar relationship for the structural build-up rate of concrete were highlighted.

scholarly journals Chemical interaction between polymer and cement in polymer-cement concrete

2016 ◽  
Vol 64 (4) ◽  
pp. 785-792 ◽  
Author(s):  
R. Wang ◽  
J. Li ◽  
T. Zhang ◽  
L. Czarnecki
Keyword(s):  
Cement Mortar ◽  
Chemical Interaction ◽  
Cement Composite ◽  
Cementitious Materials ◽  
Physical Interaction ◽  
Chemical Interactions ◽  
Concrete Technology ◽  
Different Types ◽  
Overall Performance ◽  
The Relationship

Abstract Polymers are widely used in cement mortar and concrete modification due to their significant role in improving the overall performance of cement-based materials. Their physical interaction is well-accepted, while less attention is given to chemical interaction between the polymers and cement. Through a review of prior arts, chemical interactions are discussed and summarized in this paper. Various chemical interactions may take place between cement and different types of polymers. Understanding these chemical interactions will play an important role in clarifying the relationship between microstructure and macrostructure of polymer-modified cementitious materials. Authors expressed and proved the conviction that the organic-inorganic (Polymer-Portland cement) composite with some components chemically bonded, in parallel to the physical interaction, will be the next stage in concrete technology progress.

scholarly journals The Influences of Cement Hydration and Temperature on the Thixotropy of Cement Paste

Materials ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 1853
Author(s):  
Julian Link ◽  
Thomas Sowoidnich ◽  
Christopher Pfitzner ◽  
Teba Gil-Diaz ◽  
Frank Heberling ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Cement Paste ◽  
Recovery Rate ◽  
Linear Trend ◽  
Linear Increase ◽  
Rheological Parameters ◽  
Degree Of Hydration ◽  
Structural Recovery ◽  
Limit Stress ◽  
Shear History

The rheological properties of fresh cement paste are highly influenced by a large number of parameters, among which the most important factors are the applied shear stress, and the shear history, the age of the sample and the temperature. The effects of these parameters on the yield stress (designated as structural limit stress in this work), the viscosity and the structural recovery rate (i.e., the change in dynamic viscosity with time at rest) were studied. In parallel, the changes in ion composition of the carrier liquid, mineral phase content and granulometry were investigated. The results reveal that all investigated rheological parameters exhibit an approximated bi-linear trend with respect to the degree of hydration, with a period of quasi-constant properties until a degree of hydration of approximately 0.07, followed by a non-linear increase. This increase could be attributed to the formation of calcium hydroxide (CH) and calcium-silicate-hydrate (C-S-H) via calorimetry results. With regard to the effect of the shear history of the sample on the rheological properties, the structural limit stress showed a minor dependency on the shear history immediately after the end of shearing, which, however, vanished within the first minute at rest. The same is true for the structural recovery rate. The presented results give detailed insights into the influences of hydration and shear on the rheological properties—especially the thixotropy—of fresh cement pastes.

scholarly journals Component Analysis of Bio-Asphalt Binder Using Crumb Rubber Modifier and Guayule Resin as an Innovative Asphalt Replacer

2020 ◽  
Author(s):  
Ahmed Hemida ◽  
Magdy Abdelrahman
Keyword(s):  
Rheological Properties ◽  
Elevated Temperatures ◽  
Chemical Interaction ◽  
Asphalt Binder ◽  
Thermo Gravimetric Analysis ◽  
Component Analysis ◽  
Crumb Rubber ◽  
Physical Interaction ◽  
Gravimetric Analysis ◽  
Asphalt Rubber

This research seeks to interpret the component analysis of an innovative bio-asphalt binder using guayule resin in addition to crumb rubber modifier (CRM) at high concentrations. Such asphalt modification aims to minimize the dependency on virgin asphalt binder and provide new solutions concerning sustainable, flexible pavement industry. Guayule resin is a promising bioresource for asphalt binder replacement. By now, it could be considered a no value byproduct extracted during the guayule natural rubber production. CRM is a recycled material derived from scrap tires. The provided interpretation could help in understanding the asphalt-rubber-guayule interaction mechanism. Fourier transform infrared spectroscopy (FTIR), supported by thermo-gravimetric analysis (TGA), was used to investigate the component analyses of guayule resin composition, asphalt guayule interaction, and asphalt rubber guayule interaction, compared to corresponding asphalt rubber interaction. Additionally, the rheological properties at elevated temperatures were provided to link the microscale properties with the final product performance. The study clarified the distinct carbon and hydrogen compositional elements of guayule resin. Asphalt and guayule resin have similarities in chemical composition and rheological behavior with temperature susceptibility. The asphalt guayule binder had physical interaction. However, when both interacted with rubber, a chemical interaction was attributed, with no difference in rubber dissolution tendency, in asphalt rubber guayule, compared to asphalt rubber. A bio-binder composed of 62.5% asphalt, 25% guayule and 12.5% CRM had the potential to provide rheological properties better than base asphalt. Such behavior was interpreted by a high release of rubber components.

Effects of ionic liquid types on the tribological, mechanical, and thermal properties of ionic liquid modified graphene/polyimide shape memory composites

2021 ◽  
pp. 095400832199676
Author(s):  
Yuting Ouyang ◽  
Qiu Zhang ◽  
Xiukun Liu ◽  
Ruan Hong ◽  
Xu Xu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Ionic Liquid ◽  
Composite Materials ◽  
Shape Memory ◽  
Recovery Rate ◽  
Shape Recovery ◽  
Graphene Nanosheets ◽  
Mechanical And Thermal Properties ◽  
Thermal And Mechanical Properties ◽  
Modified Graphene

Different ionic liquid modified graphene nanosheets (IG) were induced into polyimide (PI) to improve the tribological, thermal, and mechanical properties of shape memory IG/PI composites. The results demonstrated that when using 1-aminoethyl-3-methylimidazole bromide to modify graphene nanosheets (IG-1), the laser-driven shape recovery rate of IG-1/PI composites (IGPI-1) reached 73.02%, which was 49.36% higher than that of pure PI. In addition, the IGPI-1 composite materials reached the maximum shape recovery rate within 15 s. Additionally, under dry sliding, the addition of IG can significantly improve the tribological properties of composite materials. IGPI-1 exhibited the best self-lubricating properties. Compared with pure PI, the friction coefficient (0.19) and wear rate (2.62 × 10–5) mm3/Nm) were reduced by 44.1% and 24.2%, respectively, and the T10% of IGPI-1 increased by 32.2°C. The Tg of IGPI-1 reached 256.5°C, which was 8.4°C higher than that of pure PI. In addition, the tensile strength and modulus of IGPI-1 reached 82.3 MPa and 1.18 GPa, which were significantly increased by 33.6% and 29.8%, respectively, compared with pure PI. We hope that this work will be helpful for the preparation of shape memory materials with excellent tribological, thermal, and mechanical properties.

scholarly journals Influence of biopolymers on the rheological properties of seafloor sediments and the runout behavior of submarine debris flows

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jun Kameda ◽  
Hamada Yohei
Keyword(s):  
Rheological Properties ◽  
Debris Flows ◽  
Extracellular Polymeric Substances ◽  
Flow Behavior ◽  
Mass Movement ◽  
Rheological Parameters ◽  
Natural Environments ◽  
Natural Systems ◽  
Chemical Conditions ◽  
Seafloor Sediments

AbstractSubmarine debris flows are mass movement processes on the seafloor, and are geohazards for seafloor infrastructure such as pipelines, communication cables, and submarine structures. Understanding the generation and run-out behavior of submarine debris flows is thus critical for assessing the risk of such geohazards. The rheological properties of seafloor sediments are governed by factors including sediment composition, grain size, water content, and physico-chemical conditions. In addition, extracellular polymeric substances (EPS) generated by microorganisms can affect rheological properties in natural systems. Here we show that a small quantity of EPS (~ 0.1 wt%) can potentially increase slope stability and decrease the mobility of submarine debris flows by increasing the internal cohesion of seafloor sediment. Our experiments demonstrated that the flow behavior of sediment suspensions mixed with an analogue material of EPS (xanthan gum) can be described by a Herschel–Bulkley model, with the rheological parameters being modified progressively, but not monotonously, with increasing EPS content. Numerical modeling of debris flows demonstrated that the run-out distance markedly decreases if even 0.1 wt% of EPS is added. The addition of EPS can also enhance the resistivity of sediment to fluidization triggered by cyclic loading, by means of formation of an EPS network that binds sediment particles. These findings suggest that the presence of EPS in natural environments reduces the likelihood of submarine geohazards.

scholarly journals The Influence of Chosen Factors on the Rheological Properties of Cement Paste

2015 ◽  
Vol 108 ◽  
pp. 568-574 ◽  
Author(s):  
Alina Kaleta ◽  
Stefania Grzeszczyk
Keyword(s):  
Rheological Properties ◽  
Cement Paste

Using of Untreated Carbon Nanotubes in Cement Compositions

2016 ◽  
Vol 865 ◽  
pp. 6-11 ◽  
Author(s):  
Kateryna Pushkarova ◽  
Maryna Sukhanevych ◽  
Artur Martsikh
Keyword(s):  
Carbon Nanotubes ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Positive Influence ◽  
Mechanical Tests ◽  
Strength Characteristics ◽  
Concrete Durability ◽  
Cement Mortars ◽  
Optimum Decision ◽  
Cement System

One of the most important problem of concrete durability is increasing of waterproofing. Researches are devoted studying of cement mortars modified by carbon nanotubes, dispersed in plasticizers solutions. Were investigated physico-mechanical properties of cement paste, cement-sand mortar into which structure entered untreated carbon nanotubes (production of plant TM "Spetsmash" Kyiv, Ukraine) in various quantity. Were used as plasticizers in cement compositions additives substances of the various chemical nature – naphtaleneformaldehyde, melamineformaldehyde and polycarboxylate. Quantity of untreated nanotubes varied from 0,5%; 1,0% and to 1,5%. Concentration of additives was accepted taking into account recommendations of producers and made about 1% from the weight of cement. Were studied some technological processes of introduction untreated carbon nanotubes in cement system and is shown that the way of introduction of nanomodifiers has essential impact on strength characteristics of cementitious materials. Optimum decision introduction of untreated carbon nanotubes is using its in dispersion plasticizer of the working concentration prepared in an ultrasonic dispergator is established. Results of physico-mechanical tests of cement paste and cement-sand mortar showed positive influence at introduction of untreated carbon nanotubes as cement modifiers on strength characteristics of samples. Resalts is shown that the nanomodifier, used quantity about 1% in solution of lignosulfonate with polycarboxylate and melamineformaldehyde plasticizer has great impact on strength characteristics.

Sign in / Sign up

Export Citation Format

Share Document