Evaluation of Degradation of SBS Modified Asphalt Binder Because of RTFO, PAV, and UV Aging using a Novel Extensional Deformation Test

2019 ◽  
Vol 2673 (6) ◽  
pp. 447-457 ◽  
Author(s):  
Roksana Hossain ◽  
Nazimuddin M. Wasiuddin
Keyword(s):  
Asphalt Binder ◽  
Uv Aging ◽  
Extensional Deformation ◽  
Modified Binders ◽  
Modified Asphalt Binder ◽  
Shear Mixing ◽  
Deformation Test ◽  
Modified Binder ◽  
Aged Binder ◽  
Styrene Butadiene

Styrene-butadiene-styrene (SBS) modified PG 64-22 and PG 76-22 binders are studied to investigate the degradation of polymer because of aging applied by: rolling thin film oven (RTFO), pressure aging vessel (PAV), and ultraviolet (UV). Upon observing the temperature increment of unmodified binder during high shear mixing, a polymer mixing procedure has been established. SBS (2%, 4%, and 6%), polyphosphoric acid (PPA) (0.5%, 2%, and 3.5%), and PPA (2%)-SBS (0.5%, 2%, and 3.5%) are mixed with PG 64-22 binder. Sentmanat extensional rheometer, based on dynamic shear rheometer, is used to investigate the extensional deformation characteristics in which SBS modified binders exhibit both first peak elongation force, F1, and second peak elongation force, F2, whereas, unmodified binders and PPA modified binders exhibit no F2. SBS is the most effective in increasing F2 with an increasing rate of 1.16N/% of SBS polymer. At 12°C and 16°C, F2 of RTFO aged SBS modified binder reduces, which indicates the polymer is degrading. In the case of PAV aged SBS modified binder, no F2 is found at 12°C and 16°C. With the increment of temperature, the PAV aged sample shows F2, but the value is less than the F2 of the original and RTFO aged binder of similar stiffness (F1). A normalized parameter, F2/F1, also shows that RTFO and PAV aging degrade SBS. Evaluation of UV aged SBS modified binder shows no F2 at any temperature while oven aged binder shows F2 value at similar aging temperature, duration, and thickness, indicating SBS completely degrades because of UV aging.

scholarly journals Characterization of Recovery in Asphalt Binders

Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 920 ◽  
Author(s):  
Fuquan Ma ◽  
Xue Luo ◽  
Zhiyi Huang ◽  
Jinchang Wang
Keyword(s):  
Activation Energy ◽  
Internal Stress ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Asphalt Pavements ◽  
Loading Conditions ◽  
Recovery Model ◽  
Modified Asphalt Binder ◽  
Modified Binder ◽  
Styrene Butadiene

The recovery property of asphalt binders plays an important role in the performance and service life of asphalt pavements. Since the internal stress is the driving force for the recovery of asphalt binders, the accurate measurement of the internal stress is full of significance. Based on this rationale, this paper aims to measure the internal stress of asphalt binders using a creep and step-loading recovery (CSR) test and characterizing the recovery behaviors by the internal stress. One base asphalt binder and one styrene–butadiene–styrene (SBS)-modified binder are selected in this study. The key elements of the CSR test are carefully designed and its accuracy is verified in three aspects, including the loading conditions, the effect of disturbance by step-loads, and accuracy of measured internal stress. Then, a kinetics-based recovery model is proposed to evaluate and predict the recovery properties of asphalt binders from its causal relationship. The constant-rate recovery activation energy indicates a major difference with nondestructive and destructive loading conditions, while the fast-rate recovery activation energy keeps almost constant regardless of the loading conditions. After that, the healing activation energy is calculated by using the kinetics-based recovery model and the results indicate that SBS modified asphalt binder shows better healing abilities than a base binder.

scholarly journals The Use of SBS-Modified Binder to Eliminate the Aggregate Gradation Deviation Effects in Asphalt Mixtures

2021 ◽  
Vol 27 (10) ◽  
pp. 68-85
Author(s):  
Dhuha F. Abbas ◽  
Hasan Al Mosawe
Keyword(s):  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Assessment Method ◽  
Good Tool ◽  
Aggregate Gradation ◽  
Coarse Aggregates ◽  
Modified Asphalt Binder ◽  
Modified Binder ◽  
Styrene Butadiene ◽  
The Impact

  Asphalt Hot Mix (HMA) is mainly applied in highway construction in Iraq because of its economic advantage and easy maintenance. Various factors impact the performance of HMA in the field. It is one of the significant impacts on aggregate gradation. The Universal Specification for Roads and Bridges in Iraq (SCRB) limits the different types of asphalt layers and allows for designed tolerance aggregate gradation. It is quite hard for contractors in the present asphalt industries to achieve the required job mix because of sieves' control problems. This study focuses on the effects on the required specification performance of aggregate deviations by using original and modified asphalt binder with AC(40-50) and 4% SBS, respectively. A mid gradation of the base asphalt mixture was selected as a reference mix, and more than 24 deviated mixtures were then prepared. Typical Marshall routine studies on prepared compounds were performed to assess the properties of the mixture. Bailey's theory (CA, Fac ratios) was also employed for understanding the impact of these deviations on the arrangement of particles and blending performance. Results show that the mixture performance is not affected greatly by minor aggregate deviations. However, a significant deviation in coarse aggregates leads to a decrease in Marshall properties. Results showed that a good tool for understanding mixing performance is the Bailey performance assessment method. This paper aims to study the effects of using  4% Styrene Butadiene Styrene (SBS) and eliminating the effect of aggregate gradation deviations on the mixture performance.

scholarly journals Effect of Nanoclays on Moisture Susceptibility of SBS-Modified Asphalt Binder

2020 ◽  
Vol 2020 ◽  
pp. 1-15
Author(s):  
Han Wang ◽  
Yinchuan Guo ◽  
Aiqin Shen ◽  
Xiaolong Yang ◽  
Peng Li
Keyword(s):  
Asphalt Binder ◽  
Moisture Susceptibility ◽  
Force Microscopy ◽  
Modified Asphalt ◽  
Atomic Force ◽  
Modified Binders ◽  
Modified Asphalt Binder ◽  
Water Damage ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt

Moisture susceptibility plays an important role in the damage of asphalt pavement. Failure occurs when asphalt is removed from the aggregate particles due to the decreased adhesion between the asphalt and aggregate in comparison with that between water and the aggregate. In recent years, efforts utilizing nanomaterials to improve the diverse properties of asphalt have proven to be effective. In this study, three types of nanoclays were used to modify styrene-butadiene-styrene- (SBS-) modified asphalt. The resistances to water damage of the modified binders were evaluated using the surface free energy (SFE) and atomic force microscopy (AFM). The results revealed that the total SFE decreased and the energy ratio (ER) increased when the asphalt binder was modified with the nanoclays, indicating that the addition of nanoclays can improve the moisture resistance of these aggregate-binder systems. After immersion, a decreased amount of bee structures was observed in both the SBS and nanoclay-modified asphalts due to the interactions between water and bitumen. However, the residual amount of bee structures was higher in the nanoclay-modified asphalts than in the SBS-modified asphalt, indicating that the addition of nanoclay makes the surface morphology of asphalt more resistant to water damage. Finally, freeze-thaw splitting tests were used to verify the results obtained through the SFE and AFM tests.

RHEOLOGICAL BEHAVIOUR OF COCONUT SHELL POWDER MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (7-3) ◽  
Author(s):  
Rosnawati Buhari ◽  
Nur Fareesya Zabidi ◽  
Mohd Ezree Abdullah ◽  
Siti Khatijah Abu Bakar ◽  
Nurul Hidayah Mohd Kamarudin
Keyword(s):  
Rheological Properties ◽  
Softening Point ◽  
Asphalt Binder ◽  
Rheological Behaviour ◽  
Coconut Shell ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Modified Binder ◽  
Coconut Shell Powder ◽  
Shell Powder

The objectives of this study were to determine the blending parameters of coconut shell powder (CSP) modified asphalt binder and to evaluate the rheological properties of CSP modified asphalt binder. CSP of 2%, 4%, 6%, 8% and 10% by weight of asphalt have been incorporated into an unaged 80/100 asphalt mix in order to improve its performance. The influence of the additives on the physical and rheological properties was evaluated with penetration test, softening point, storage stability, dynamic shear rheometer test (DSR), and Field Emission Scanning Electron Microscope (FESEM). The aging of asphalt binders was simulated in a laboratory by using Rotational Thin Film Oven (RTFO). The results showed that the addition of CSP into virgin binder was decreasing the penetration value and increasing the softening point temperature compared to the original binder. On the rheological effect, for unaged modified binder, higher CSP resulted higher G*/sin δ especially at lower temperature compared to the unaged control binder. Besides, for the aged modified binder, stiffness was lower than the control aged binder for all temperature.

Highly Modified Asphalt Binder for Asphalt Crack Relief Mix

2017 ◽  
Vol 2630 (1) ◽  
pp. 110-117 ◽  
Author(s):  
Matheus S. Gaspar ◽  
Kamilla L. Vasconcelos ◽  
Amanda H. M. da Silva ◽  
Liedi L. B. Bernucci
Keyword(s):  
Hot Mix Asphalt ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Bending Test ◽  
Asphalt Binders ◽  
Reflective Cracking ◽  
Modified Asphalt ◽  
Asphalt Overlay ◽  
Modified Asphalt Binder ◽  
Styrene Butadiene

Reflective cracking is a common issue with respect to rehabilitated asphalt pavements, especially when the rehabilitation is done by applying a hot-mix asphalt overlay on the existing damaged pavement. Several approaches can be adopted to delay reflective cracking. They include an increase of the overlay thickness and the use of a stress relief asphalt mixture (SRAM), which is a fine-graded, flexible, and thin asphalt interlayer. Because the efficiency of a SRAM is highly related to the properties of the asphalt binder used in the mixture, it is of interest to use a highly modified asphalt (HiMA) binder. This paper describes a field test comprising three sections at BR-116 (a heavily trafficked highway in Brazil). One of the rehabilitation strategies used for a cracked asphalt pavement was a 2.5-cm SRAM (produced with a HiMA binder) and 5-cm styrene–butadiene–styrene (SBS) hot-mix asphalt (HMA). The other two strategies were to apply SBS HMA overlays of different thicknesses (7.5 cm and 10.5 cm). The aim was to evaluate and compare the capability of these solutions to control reflective cracking. Rheological properties and multiple stress creep and recovery tests were performed on the asphalt binders, and the semicircular bending test was performed on the asphalt mixtures. The surface conditions were monitored, and the results for each section were compared. After a 29-month period, the section that received the interlayer had the lowest cracked area and showed better resistance than the overlays did to reflective cracking and better maintenance of the original thickness of the pavement.

scholarly journals Study on Ultraviolet Aging Mechanism of Carbon Nanotubes/SBS Composite-Modified Asphalt in Two-Dimensional Infrared Correlation Spectroscopy

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5672
Author(s):  
Xuewen Zheng ◽  
Wenyuan Xu ◽  
Shuangrui Xie
Keyword(s):  
Carbon Nanotubes ◽  
Functional Groups ◽  
Asphalt Binder ◽  
Correlation Spectroscopy ◽  
Two Dimensional ◽  
Uv Aging ◽  
Modified Asphalt ◽  
Correlation Spectrum ◽  
Modified Asphalt Binder ◽  
Sbs Modified Asphalt

In order to explore the influence mechanism of carbon nanotubes on the ultraviolet (UV) aging properties of the SBS-modified asphalt binder, the changes of functional groups in the one-dimensional infrared spectrum and two-dimensional infrared correlation spectrum are studied in this paper. The results show that the UV aging process of the SBS-modified asphalt binder is the process of alkane chain cleavage and reorganization, the formation of oxygen-containing functional groups and decomposition of SBS. The incorporation of carbon nanotubes can reduce the mutual conversion of methyl and methylene functional groups, inhibit the decomposition of butadiene and the destruction of C = C double bonds in SBS. The degradation of SBS during the process of UV aging leads to the change of many functional groups and acceleration of the aging of the SBS-modified asphalt binder. The addition of carbon nanotubes can effectively alleviate the degradation of SBS and the formation of oxygen-containing functional groups at the early stage of UV aging, and reduce the influence of these two changes on other functional groups; thus, improving the anti-aging performance of the SBS-modified asphalt binder.

PHYSICAL PROPERTIES AND STORAGE STABILITY OF GEOPOLYMER MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (7-2) ◽  
Author(s):  
Ahmad Nazrul Hakimi Ibrahim ◽  
Nur Izzi Md. Yusoff ◽  
Norliza Mohd Akhir ◽  
Muhamad Nazri Borhan
Keyword(s):  
Physical Properties ◽  
Storage Stability ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Potential Alternative ◽  
Modified Binder ◽  
And Storage

This study was conducted to investigate the physical properties and storage stability of the 80/100 penetration grade asphalt modified with geopolymer. In this research, fly ash and alkali activators, namely sodium silicate (Na2SiO3) and sodium hydroxide (NaOH), were used as geopolymer components. The penetration, Ring and Ball softening point, ductility, and viscosity tests were conducted to determine the physical properties of geopolymer modified asphalt (GMA). Five samples of asphalt binders with varying percentages of geopolymer, namely 0, 3, 5, 7 and 9%, by weight of asphalt binder were studied. Results show that geopolymer has good compatibility with asphalt binder. The addition of geopolymer into asphalt binder resulted in improved permanent deformation resistance of the modified binder compared to that of the conventional asphalt. In conclusion, geopolymer could be considered as a potential alternative in the modification of the properties of asphalt binder.

Performance of Waste Cooking Oil in Asphalt Binder Modification

2016 ◽  
Vol 700 ◽  
pp. 216-226 ◽  
Author(s):  
Wan Nur Aifa Wan Azahar ◽  
Mastura Bujang ◽  
Ramadhansyah Putra Jaya ◽  
Mohd Rosli Hainin ◽  
Norzita Ngadi ◽  
...  
Keyword(s):  
Water Content ◽  
Asphalt Binder ◽  
Quality Measurement ◽  
Acid Value ◽  
Waste Cooking Oil ◽  
Polymerization Process ◽  
Cooking Oil ◽  
Modified Asphalt Binder ◽  
Modified Binder

Oxidation, hydrolysis and polymerization process during frying activity has caused the alteration value of the waste cooking oil (WCO) properties which is acid value and water content. This parameter is recognized as the quality measurement of waste cooking oil that might be affecting the performance of WCO in binder modification. Therefore, the aim of this paper is to relate the quality of WCO by the determination of the WCO parameter with the performance of WCO in modified binder by physical and rheological binder testing. Based on the finding, the high and good quality of WCO is recorded in December sample with the lowest acid value (1.66 mL/g) and water content (0.01 ml). The high quality of WCO affected the good performance of rheological properties where the higher rutting resistance and temperature failure at 64 °C is achieved by the modified asphalt binder with the addition of WCO in December sample.

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