Iron sulphides at the epithermal gold-copper deposit of Palai-Islica (Almería, SE Spain)

2003 ◽  
Vol 67 (5) ◽  
pp. 1059-1080 ◽  
Author(s):  
F. J. Carrillo Rosúa ◽  
S. Morales Ruano ◽  
P. Fenoll Hach-Alí
Keyword(s):  
Trace Elements ◽  
Volcanic Rocks ◽  
Copper Deposit ◽  
Metastable Solid Solution ◽  
Se Spain ◽  
Quartz Veins ◽  
Type Iv ◽  
Different Types ◽  
Iron Sulphides ◽  
Ore Minerals

AbstractAu-Cu mineralization at Palai-Islica occurs as disseminations in massive silicified volcanic rocks and, more abundantly, in sulphide-bearing quartz veins. The major ore minerals in the deposit are pyrite ± chalcopyrite, sphalerite and galena and there is a great variety of accessory minerals, including Au-Ag alloys and native gold. Pyrite, the most abundant sulphide, is closely associated with gold. Seven different types of pyrite have been distinguished with a variable concentration of different trace elements. Among these, the only one free of trace elements (type IV) is related to Au-Ag alloys. Pyrite associated with these Au-Ag alloys has cubic and pentagonal dodecahedral habits, whereas pyrite with pentagonal dodecahedral habit only is from barren zones. In addition, there is no significant invisible gold in the pyrite, but there is a relatively large amount of Ag in collomorphic pyrite (up to 0.20 wt.%) or type III pyrite (up to 1.47 wt.%). Arsenic is the most abundant trace element in pyrite (up to 6.11 wt.%), present as a metastable solid solution or as a non-stoichiometric element. A variety of marcasite related to the gold levels also has a considerable amount of trace elements (As up to 1.15 wt.%, Sb up to 0.40 wt.%).

scholarly journals Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China

2018 ◽  
Vol 22 (4) ◽  
pp. 301-318
Author(s):  
Huiqing Geng ◽  
Xuexiang Gu ◽  
Yongmei Zhang
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Gold Deposit ◽  
Volcanic Rocks ◽  
Forming Process ◽  
Quartz Veins ◽  
Epithermal Gold Deposit ◽  
Basic Volcanic ◽  
P Type

The Gaosongshan epithermal gold deposit in Heilongjiang, Northeast China, is hosted by the Lower Cretaceous intermediate-basic volcanic rocks. Three auriferous quartz veins including eleven gold orebodies were all discovered in tectonoclastic zones. Genetic mineralogy study including the thermoelectricity, rare earth elements and trace elements of pyrite and rare earth elements of quartz were carried out. Thermoelectric conductive type of pyrite is mainly N-P type. Calculating the thermoelectric parameters XNP and denudation percentage γ of pyrites from orebodies 1-I, 2-II and 2-IV, suggests that gold orebodies are all eroded to their middle-lower parts. The variable range of Co concentrations (51.3-264.0ppm) and Ni concentrations (68.9-258.0ppm) and Co: Ni ratio (0.31-1.90), together with relatively small Sr/Ba ratio in ore-bearing pyrites (0.11-0.50), supports a hydrothermal origin of mineralization at Gaosongshan gold deposit. Compared with volcanic rocks, the chondrite-normalized REE patterns of ore-bearing pyrites and quartz are all LREE enriched with similar ΣLREE/ΣHREE ratio ranging from 7.37-13.68 in ore-bearing pyrites, 4.74-15.37 in ore-bearing quartz and no Ce anomalies. δEu values in ore-bearing pyrites and quartz are 0.65-1.66 (average=0.93) and 0.66-1.62 (average=1.03), respectively. δEu values of volcanic rocks are 0.86­1.07 (average 0.94), suggesting no obvious negative Eu anomalies. Similar REE characteristics of ore-bearing pyrites and quartz and volcanic rocks, together with previous oxygen and hydrogen isotope studies of quartz, suggest that the ore-forming fluids of the Gaosongshan gold deposit were mainly magmatic origin which was associated with andesitic magma and was partly mixed with atmospheric water. Comparing trace elements characteristics of ore-bearing pyrites with volcanic rocks, together with previous S isotopic studies, it is concluded that the ore-forming materials were derived from the surrounding rocks. Slight changes of Y/Ho (23.80­27.28), Zr/Hf (35.41­47.83), Nb/Ta (10.96­18.52) in ore-bearing pyrites indicate that the ore-forming fluid system is relatively stable during the ore-forming process. 

scholarly journals Ore Genesis at the Jinchang Gold–Copper Deposit in Heilongjiang Province, Northeastern China: Evidence from Geology, Fluid Inclusions, and H–O–S Isotopes

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 99 ◽  
Author(s):  
Shunda Li ◽  
Xuebing Zhang ◽  
Lingling Gao
Keyword(s):  
Fluid Inclusions ◽  
Copper Deposit ◽  
Northeastern China ◽  
Heilongjiang Province ◽  
Quartz Veins ◽  
Daughter Mineral ◽  
Rich Liquid ◽  
Three Stages ◽  
Stage 1 ◽  
Late Stages

The Jinchang gold–copper deposit is located in Eastern Heilongjiang Province,Northeastern China. The orebody comprises primarily hydrothermal breccias, quartz veins, anddisseminated ores within granite, diorite, and granodiorite. Three paragenetic stages are identified:early quartz–pyrite–arsenopyrite (Stage 1), quartz–pyrite–chalcopyrite (Stage 2), and latequartz–pyrite–galena–sphalerite (Stage 3). Gold was deposited during all three stages and Stage 1was the major gold-producing stage. Copper is associated with the mineralization but has loweconomic value. Fluid inclusions (FIs) within the deposit are liquid-rich aqueous, vapor-rich aqueous,and daughter-mineral-bearing types. Microthermometric data for the FIs reveal decreasinghomogenization temperatures (Th) and salinities of the ore-forming fluids over time. The Th forStages 1–3 of the mineralization are 421–479, 363–408, and 296–347 °C, respectively. Stage 1 fluidsin vapor-rich and daughter-mineral-bearing inclusions have salinities of 5.7–8.7 and 49.8–54.4 wt%NaCl equivalent, respectively. Stage 2 fluids in vapor-rich, liquid-rich, and daughter-mineral-bearinginclusions have salinities of 1.2–5.4, 9.5–16.0, and 43.3–48.3 wt% NaCl, respectively. Stage 3 fluids inliquid-rich and daughter-mineral-bearing inclusions have salinities of 7.9–12.6 and 38.3–42.0 wt% NaClequivalent, respectively. The estimated trapping pressures are 160–220 bar, corresponding toan entrapment depth of 1.6–1.2 km in the paleo-water table. Oxygen and hydrogen isotope data(δ18OV-SMOW = 8.6‰ to 11.4‰; δDV-SMOW = −92.2‰ to −72.1‰) suggest that the ore-forming fluidswere derived from magmatic fluids during the early stages of mineralization and subsequentlyincorporated meteoric water during the late stages. The sulfide minerals have δ34SVCDT values of0.2‰–3.5‰, suggesting that the sulfur has a magmatic origin. The Jinchang deposit is a typicalgold-rich gold–copper porphyry deposit.

scholarly journals Relief evolution of landslide slopes in the Kamienne Mts (Central Sudetes, Poland) – analysis of a high-resolution DEM from airborne LiDAR

2018 ◽  
Vol 7 (1) ◽  
pp. 1-20 ◽  
Author(s):  
Aleksandra Osika ◽  
Małgorzata Wistuba ◽  
Ireneusz Malik
Keyword(s):  
Cross Sections ◽  
Volcanic Rocks ◽  
Sedimentary Rocks ◽  
Airborne Lidar ◽  
Lidar Data ◽  
Mountain Ridge ◽  
Geological Maps ◽  
Different Types ◽  
Sw Poland ◽  
Landslide Development

Abstract The aim of the study is to reconstruct the development of landslide relief in the Kamienne Mountains (Central Sudetes, SW Poland) based on a DEM from LiDAR data. Analyses of relief and geological maps in ArcGIS 10.5 and of slope cross-sections in Surfer 14 allowed to distinguish different types of landslide relief, developed in latites and trachybasalts lying above claystones and mudstones. The types vary from small, poorly visible landslides to vast landslides with complex relief. They were interpreted as consecutive stages of geomorphic evolution of hillslope-valley topography of the study area. Two main schemes have been established which explain the development of landslide slopes in the Kamienne Mts: (1) upslope, from the base of the slope towards the mountain ridge and (2) downslope, beginning on the top of the mountain ridge. The direction of landslide development depends on the thickness of volcanic rocks in relation to underlying sedimentary rocks. When the latter appear only in the lowest part of the slope, landslides develop upslope. If sedimentary rocks dominate on the slope and volcanic rocks form only its uppermost part, landslides develop downslope. The results show that landsliding leads to significant modifications of relief of the study area, including complete degradation of mountain ridges.

scholarly journals Gold-hosting supracrustal rocks on Storø, southern West Greenland: lithologies and geological environment

2007 ◽  
Vol 13 ◽  
pp. 41-44 ◽  
Author(s):  
Christian Knudsen ◽  
Jeroen A.M. Van Gool ◽  
Claus Østergaard ◽  
Julie A. Hollis ◽  
Matilde Rink-Jørgensen ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
West Greenland ◽  
Metasedimentary Rocks ◽  
Quartz Veins ◽  
Rock Types ◽  
Minimum Age ◽  
Arc Setting ◽  
Basic Volcanic ◽  
Back Arc ◽  
Different Sources

A gold prospect on central Storø in the Nuuk region of southern West Greenland is hosted by a sequence of intensely deformed, amphibolite facies supracrustal rocks of late Mesoto Neoarchaean age. The prospect is at present being explored by the Greenlandic mining company NunaMinerals A/S. Amphibolites likely to be derived from basaltic volcanic rocks dominate, and ultrabasic to intermediate rocks are also interpreted to be derived from volcanic rocks. The sequence also contains metasedimentary rocks including quartzites and cordierite-, sillimanite-, garnet- and biotite-bearing aluminous gneisses. The metasediments contain detrital zircon from different sources indicating a maximum age of the mineralisation of c. 2.8 Ga. The original deposition of the various rock types is believed to have taken place in a back-arc setting. Gold is mainly hosted in garnet- and biotite-rich zones in amphibolites often associated with quartz veins. Gold has been found within garnets indicating that the mineralisation is pre-metamorphic, which points to a minimum age of the mineralisation of c. 2.6 Ga. The geochemistry of the goldbearing zones indicates that the initial gold mineralisation is tied to fluid-induced sericitisation of a basic volcanic protolith. The hosting rocks and the mineralisation are affected by several generations of folding.

scholarly journals Comparative Characteristics of Sensorimotor Reactions of Highly Qualified Athletes with Different Types of Heart Rate Regulation

2021 ◽  
Vol 6 (5) ◽  
pp. 456-464
Author(s):  
A. P. Romanchuk ◽  
◽  
O. V. Guzii ◽  
A. V. Maglyovanyi ◽  
◽  
...  
Keyword(s):  
Heart Rate ◽  
Heart Rate Variability ◽  
Type I ◽  
Sensorimotor Function ◽  
Type Ii ◽  
Highly Qualified ◽  
Rate Regulation ◽  
Type Iv ◽  
Heart Rate Regulation ◽  
Different Types

The purpose of the study was a comparative analysis of sensorimotor reactions in highly trained athletes with different types of heart rate regulation. Materials and methods. 202 highly trained male athletes aged 22.6±2.8 years, who are engaged in acyclic sports – martial arts (karate, taekwondo, kickboxing, boxing, freestyle wrestling, Greco-Roman wrestling, judo, sambo) and games (water polo, soccer) were examined. The experience in sports was 10.3±3.1 years. All studies were conducted in the pre-competition period in the morning. Based on the study of heart rate variability in athletes, the type of heart rate regulation was determined. The basis for determining the types of regulation is the classification of heart rate variability indicators, taking into account their inclusion in certain limits. Heart rate variability indicators that reflect the dual-circuit model of heart rate regulation and are used for diagnosis include: total heart rate variability – total power (ms2), very low frequency (ms2), and stress-index (e.u.), which reflect the various chains of regulatory effects on heart rate. According to certain data types, 4 groups were formed. 1 group (type I) consisted of 42 athletes, 2 (type II) – 28 athletes, 3 (type III) – 88 athletes, 4 (type IV) – 44 athletes. The study of sensorimotor function was performed using the device KMM-3. Results and discussion. It is shown that the most balanced sensorimotor reactions are in athletes with type III regulation of heart rate. The most strain sensorimotor reactions are observed in type II regulation of heart rate, which is reflected in the pronounced central asymmetry of movement control with acceleration to the left against the background of deteriorating accuracy of right (due to flexors) and left (due to extensors) limbs, and the right-hand predominance. Sensorimotor reactions are quite strain in type IV of heart rate regulation, which is characterized by slow reactions at the synaptic and peripheral levels. In type I of heart rate regulation, the disorders observed at the central level of regulation relate to the asymmetry of short-term motor memory processes, which are significantly reduced in the left hemisphere. Conclusion. The study shows that the differences in the regulatory support of heart rate in highly qualified athletes are accompanied by characteristic differences in sensorimotor function. The latter can be useful for the diagnosis and further correction of conditions associated with the development of overexertion and overtraining

The association of trace elements with manganese minerals in Australian soils

Soil Research ◽  
1966 ◽  
Vol 4 (1) ◽  
pp. 29 ◽  
Author(s):  
RM Taylor ◽  
RM McKenzie
Keyword(s):  
Hydrogen Peroxide ◽  
Trace Elements ◽  
Nitric Acid ◽  
Different Types ◽  
The Common ◽  
Manganese Minerals

In widely different types of Australian soils birnessite and lithiophorite appear to be the common forms of occurrence of mineralized manganese. These mineral forms were dissolved out of the soil by hydrogen peroxide acidified to pH 3 with nitric acid and analyses of the extracts were made. It was found that the concentration of trace elements is generally quite high in these minerals. In particular, most of the soil cobalt (average 79%) was contained in or associated with these minerals where they were present.

scholarly journals Fracture Fillings and Implication of Fluid Activities in Volcanic Rocks: Dixi Area in Kelameili Gas Field, Junggar Basin, Northwestern China

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 154 ◽  
Author(s):  
Mingyou Feng ◽  
Tian Liu ◽  
Tong Lin ◽  
Xiaohong Liu ◽  
Ningxin Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Volcanic Rocks ◽  
Junggar Basin ◽  
Hydrothermal Fluids ◽  
Northwestern China ◽  
Volatile Components ◽  
Gas Field ◽  
Weakly Alkaline ◽  
Quartz Veins ◽  
Calcite Veins

The Carboniferous Batamayineishan Formation of the Kelameili Gas Field is a specific weathered crust-related volcanic reservoir that has a significant production rate in the Junggar Basin, Northwestern China, attributed to debatable processes of fluid evolution. The results suggest that various types of fluids occurring in volcanic rocks lead to the filling of quartz and calcite in fractures and their associated alteration haloes. The silica that formed quartz veins was mainly derived from deep hydrothermal fluids, while the carbon dioxide that formed calcite veins originated from sources characterized by mixing and alteration of deep hydrothermal and hydrocarbon fluids. Siliceous hydrothermal fluids rich in sulphur dioxide and other volatile components were driven by a pressure gradient and buoyancy, and circulated both laterally and vertically along the fractures, forming quartz veins and tension fractures under different temperature conditions. Moreover, changes in salinity, pressure, and carbon dioxide of deep fluids, varying from acidic to weakly alkaline, resulted in earlier calcite precipitation in contraction fractures and weathered fractures. Tectonic uplift resulted in the long-term exposure of volcanic rocks, where fresh water mixed with the partially alkaline fluid escaping the basin to form calcite cements, thus retaining the characteristics of a seepage environment in the weathered fractures. Structural fractures occurred due to tectonic movements during the burial period. Filling and leakage of hydrocarbons caused pore fluids to convert from acidic to alkaline, precipitating late sparry calcite in dissolution fractures. Late hydrothermal fluid metasomatism, brought about by infiltration into the permeable zone, caused partial dissolution of local calcite along cleavage cracks.

The Witwatersrand pyrites and metamorphism

1983 ◽  
Vol 47 (345) ◽  
pp. 473-479 ◽  
Author(s):  
D. K. Hallbauer ◽  
K. von Gehlen
Keyword(s):  
Trace Element ◽  
Fluid Inclusions ◽  
Depositional Environment ◽  
Volcanic Rocks ◽  
Source Rocks ◽  
Fine Grained ◽  
Mineral Inclusions ◽  
Ore Minerals ◽  
Hand Specimen

AbstractEvidence obtained from morphological and extensive trace element studies, and from the examination of mineral and fluid inclusions in Witwatersrand pyrites, shows three major types of pyrite: (i) detrital pyrite (rounded pyrite crystals transported into the depositional environment); (ii) synsedimentary pyrite (round and rounded aggregates of fine-grained pyrite formed within the depositional environmen); and (iii) authigenic pyrite (newly crystallized and/or recrystallized pyrite formed after deposition). The detrital grains contain mineral inclusions such as biotite, feldspar, apatite, zircon, sphene, and various ore minerals, and fluid inclusions with daughter minerals. Most of the inclusions are incompatible with an origin by sulphidization. Recrystallized authigenic pyrite occurs in large quantities but only in horizons or localities which have been subjected to higher temperatures during the intrusion or extrusion of younger volcanic rocks. Important additional findings are the often substantial amounts of pyrite and small amounts of particles of gold found in Archaean granites (Hallbauer, 1982) as possible source rocks for the Witwatersrand detritus. Large differences in Ag and Hg content between homogeneous single gold grains within a hand specimen indicate a lack of metamorphic homogenization. The influence of metamorphism on the Witwatersrand pyrites can therefore be described as only slight and generally negligible.

scholarly journals Pyrite Textures, Trace Elements and Sulfur Isotope Chemistry of Bijaigarh Shales, Vindhyan Basin, India and Their Implications

Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 588
Author(s):  
Indrani Mukherjee ◽  
Mihir Deb ◽  
Ross R. Large ◽  
Jacqueline Halpin ◽  
Sebastien Meffre ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Sulfur Isotope ◽  
Volcanic Rocks ◽  
Central India ◽  
High Energy ◽  
Vindhyan Basin ◽  
Mean Values ◽  
Fine Grained ◽  
Sedimentary Pyrite

The Vindhyan Basin in central India preserves a thick (~5 km) sequence of sedimentary and lesser volcanic rocks that provide a valuable archive of a part of the Proterozoic (~1800–900 Ma) in India. Here, we present an analysis of key sedimentary pyrite textures and their trace element and sulfur isotope compositions in the Bijaigarh Shale (1210 ± 52 Ma) in the Vindhyan Supergroup, using reflected light microscopy, LA-ICP-MS and SHRIMP-SI, respectively. A variety of sedimentary pyrite textures (fine-grained disseminated to aggregates, framboids, lags, and possibly microbial pyrite textures) are observed reflecting quiet and strongly anoxic water column conditions punctuated by occasional high-energy events (storm incursions). Key redox sensitive or sensitive to oxidative weathering trace elements (Co, Ni, Zn, Mo, Se) and ratios of (Se/Co, Mo/Co, Zn/Co) measured in sedimentary pyrites from the Bijaigarh Shale are used to infer atmospheric redox conditions during its deposition. Most trace elements are depleted relative to Proterozoic mean values. Sulfur isotope compositions of pyrite, measured using SHRIMP-SI, show an increase in δ34S as we move up stratigraphy with positive δ34S values ranging from 5.9‰ (lower) to 26.08‰ (upper). We propose limited sulphate supply caused the pyrites to incorporate the heavier isotope. Overall, we interpret these low trace element signatures and heavy sulfur isotope compositions to indicate relatively suppressed oxidative weathering on land during the deposition of the Bijaigarh Shale.

Histological Investigation of the Palatine Bone in Prenatal Trisomy 21

2001 ◽  
Vol 38 (5) ◽  
pp. 492-497 ◽  
Author(s):  
Halfdan Lauridsen ◽  
Birgit Fischer Hansen ◽  
Ingermarie Reintoft ◽  
Jean W. Keeling ◽  
Inger Kjær
Keyword(s):  
Trisomy 21 ◽  
Type I ◽  
Histological Investigation ◽  
Type Ii ◽  
Human Fetuses ◽  
Type Iv ◽  
Different Types ◽  
Horizontal Part ◽  
Palatine Bone

Objective: The purpose of the present study was to investigate the horizontal part of the palatine bone in palates from human fetuses with trisomy 21 to improve the phenotypic classification of the genotypic anomaly. Methods: Material from 23 human trisomy 21 fetuses was included in the study. The crown rump lengths of the fetuses ranged from 80 mm to 190 mm, corresponding to about 12 to 21 weeks of gestational age. The material was examined histologically. Results and Conclusions: Histological examination demonstrated four different palatal phenotypes on the basis of the development of the horizontal part of the palatine bone: type I, palatine bone complete; type II, the mesial region of the horizontal part of the palatine bone is lacking; type III, complete absence of the horizontal part of the palatine bone; and type IV, auxiliary bones in the region of the transpalatine suture. This finding shows that different types of malformations may occur in the horizontal part of the palatine bone in human trisomy 21 fetuses.

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