IV. On a peculiar pasty form of Silica, from a cavity in Gold-bearing Quartz

Author(s):  
A. French

The alluvium over an area of about 50 square miles around Lead-hills in Lanarkshire, is auriferous. In many places the precious metal may be rendered visible after fifteen or twenty minutes washing with the primitive wooden trough employed by the local gold-seekers. Frequently nuggets have been found weighing from one to four or five pennyweights, and these are often either contained in pieces of loose quartz, or have quartz fragments attached to them; there are therefore good reasons to believe that the gold found in the red stratum of clay lying immediately above the rock has been derived from the numerous quartz veins which traverse the district. The author was one day searching, along with some friends, for gold quartz in situ, and while examining a vein which crosses a gulch in the hills, called the “Gold Scars,” found cavities in the quartz filled with a peculiar pasty substance, which appeared at first sight like minute scales of silver, which had been precipitated from a solution. Our first impression was that it was silver, but its behaviour in water soon cleared away the delusion; it rendered the water exceedingly turbid and white, and the suspended matter was a long time in settling.

1979 ◽  
Vol 16 (3) ◽  
pp. 440-458 ◽  
Author(s):  
R. Kerrich ◽  
B. J. Fryer

The Porcupine District, Abitibi Greenstone Belt, is one of the most extensive areas of Archaean auriferous mineralisation. At least two stages of lode-gold emplacement are recognised: the first stage involves gold-bearing carbonate–chert chemical sediments within the lower mafic volcanic sequence; the second stage is represented by auriferous hydrothermal quartz veins which postdate deformation of the greenstone assemblage and transect diverse host rocks.Rare-earth element (REE) concentrations in the stratiform carbonates are typical of the distinctive patterns recorded for Archaean chemical sediments. Chert in these rocks has a δ18O value averaging 17.1‰, implying exchange from heavier 18/16 ratios during diagenesis and metamorphism. Metabasic volcanic rocks and quartz–feldspar porphyry stocks with background gold abundances have mean whole-rock δ18O values of 9.1‰ and 10.7‰ respectively. This enrichment in 18O relative to primary igneous rocks is attributed to oxygen isotope exchange with seawater at low temperatures during fluid transport through the oceanic crust.Quartz in all of the five hydrothermal vein systems present has a δ18O of 14‰ to 15‰, and quartz-muscovite fractionations are 3.4‰ to 3.8‰. Ambient temperatures of mineralisation are estimated to have been 400 °C to 450 °C, from oxygen isotope thermometers, fluid inclusion filling temperatures, and metamorphic mineral assemblages. The calculated δ18O of the mineralising solutions is~10‰, implying fluids of metamorphic origin. REE patterns in hydrothermal quartz veins suggest that they have been derived from high-temperature solutions in equilibrium with source rocks having relatively flat (chondrite normalised) REE distributions, such as tholeiitic and komatiitic volcanics. Adjacent to hydrothermal veins, quartz in igneous rocks approaches isotopic equilibrium with vein quartz, at 15‰, and whole-rock δ18O values for metabasalts shift to ~11‰, implying extensive water-rock interaction. Strong depletions in heavy REE of metabasic schists adjacent to veins provides further evidence for pervasive hydrothermal alteration. The Eu enrichment of all lode gold deposits analysed at Dome Mine is consistent with the reduced state of the solutions involved in their deposition, as recorded by the predominance of Fe2+. The gold-bearing veins are believed to have formed by focussed flow of fluids outgassed at the greenschist–amphibolite transition. Source volumes for Au in the Porcupine District exceed 600 km3, the carrier fluid volume for mineralisation was 60–90 km3, the Au solute concentration in the low nanogram mL−1 range, and transport distances were of the order of 10 km. Such veins may be the precursors of precious-metal-bearing chemical sediments if fluids debouche into the hydrosphere.


1992 ◽  
Vol 56 (385) ◽  
pp. 545-560 ◽  
Author(s):  
R. J. Bowell

AbstractAt the Ashanti concession, Ghana, gold-bearing quartz veins and disseminated sulphide lodes occur in narrow (1-3 m) shear zones with altered argillites and metatholeiite host rocks. The mineralisation is concealed by up to 10 m of kaolinite-mica forest ochrosol soils, beneath which is a saprolitic zone of leached rock extending down 60-70 m to the hypogene ore zone. In the unweathered hypogene orebody, gold occurs as free grains in quartz, as sub-microscopic inclusions in the disseminated arsenopyrite, as gold tellurides and as aurostibite. The gold is released from the hypogene orebody by physical dissaggregation and chemical dissolution, the latter involving hydroxyl, thiosulphate, cyanide, and fulvate complexing. Dissolution and reprecipitation of the gold appears to have taken place largely in situ with little evidence of supergene enrichment. Consequently, the gold mineralogy of the soils is complex with residual and secondary gold grains exhibiting widely different textural and compositional characteristics. Residually enriched grains display pitted, rounded surfaces and have silver-depleted rims, while supergene gold grains are compositionally homogenous and have unpitted surfaces. The supergene grains display platelet, dendritic, irregular and octahedral habit. A fine grained spongy form of gold has also been observed from weathered telluride-bearing quartz veins. Much of the secondary gold is intergrown with iron oxides and hydroxides. The gold mineralogy of the Ashanti soils appears to be controlled by physico-chemical processes active during the lateritic pedogenesis producing residual and supergene enrichment of gold.


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 272
Author(s):  
Ayman M. Atta ◽  
Mohamed H. El-Newehy ◽  
Meera Moydeen Abdulhameed ◽  
Mohamed H. Wahby ◽  
Ahmed I. Hashem

The enhancement of both thermal and mechanical properties of epoxy materials using nanomaterials becomes a target in coating of the steel to protect it from aggressive environmental conditions for a long time, with reducing the cost. In this respect, the adhesion properties of the epoxy with the steel surfaces, and its proper superhyrophobicity to repel the seawater humidity, can be optimized via addition of green nanoparticles (NPs). In-situ modification of silver (Ag) and calcium carbonate (CaCO3) NPs with oleic acid (OA) was carried out during the formation of Ag−OA and CaCO3−OA, respectively. The epoxide oleic acid (EOA) was also used as capping for Ca−O3 NPs by in-situ method and epoxidation of Ag−OA NPs, too. The morphology, thermal stability, and the diameters of NPs, as well as their dispersion in organic solvent, were investigated. The effects of the prepared NPs on the exothermic curing of the epoxy resins in the presence of polyamines, flexibility or rigidity of epoxy coatings, wettability, and coatings durability in aggressive seawater environment were studied. The obtained results confirmed that the proper superhyrophobicity, coating adhesion, and thermal stability of the epoxy were improved after exposure to salt spray fog for 2000 h at 36 °C.


2021 ◽  
Vol 13 (7) ◽  
pp. 1250
Author(s):  
Yanxing Hu ◽  
Tao Che ◽  
Liyun Dai ◽  
Lin Xiao

In this study, a machine learning algorithm was introduced to fuse gridded snow depth datasets. The input variables of the machine learning method included geolocation (latitude and longitude), topographic data (elevation), gridded snow depth datasets and in situ observations. A total of 29,565 in situ observations were used to train and optimize the machine learning algorithm. A total of five gridded snow depth datasets—Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E) snow depth, Global Snow Monitoring for Climate Research (GlobSnow) snow depth, Long time series of daily snow depth over the Northern Hemisphere (NHSD) snow depth, ERA-Interim snow depth and Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2) snow depth—were used as input variables. The first three snow depth datasets are retrieved from passive microwave brightness temperature or assimilation with in situ observations, while the last two are snow depth datasets obtained from meteorological reanalysis data with a land surface model and data assimilation system. Then, three machine learning methods, i.e., Artificial Neural Networks (ANN), Support Vector Regression (SVR), and Random Forest Regression (RFR), were used to produce a fused snow depth dataset from 2002 to 2004. The RFR model performed best and was thus used to produce a new snow depth product from the fusion of the five snow depth datasets and auxiliary data over the Northern Hemisphere from 2002 to 2011. The fused snow-depth product was verified at five well-known snow observation sites. The R2 of Sodankylä, Old Aspen, and Reynolds Mountains East were 0.88, 0.69, and 0.63, respectively. At the Swamp Angel Study Plot and Weissfluhjoch observation sites, which have an average snow depth exceeding 200 cm, the fused snow depth did not perform well. The spatial patterns of the average snow depth were analyzed seasonally, and the average snow depths of autumn, winter, and spring were 5.7, 25.8, and 21.5 cm, respectively. In the future, random forest regression will be used to produce a long time series of a fused snow depth dataset over the Northern Hemisphere or other specific regions.


2020 ◽  
Vol 12 (28) ◽  
pp. 3600-3607
Author(s):  
Xincheng Jiang ◽  
Wen Liu ◽  
Bin Luo ◽  
Xuke Liu ◽  
Yuting Huang ◽  
...  

Copper foam in situ loaded with precious metal nanoparticles as transmission SEIRAS substrate.


2014 ◽  
Vol 145 ◽  
pp. 838-842 ◽  
Author(s):  
Meng Sun ◽  
Zhan-Jun Li ◽  
Chun-Lin Liu ◽  
Hai-Xia Fu ◽  
Jiang-Shan Shen ◽  
...  

1982 ◽  
Vol 15 ◽  
Author(s):  
W. S. Fyfe

ABSTRACTSelection of the best rock types for radwaste disposal will depend on their having minimal permeability, maximal flow dispersion, minimal chance of forming new wide aperture fractures, maximal ion retention, and minimal thermal and mining disturbance. While no rock is perfect, thinly bedded complex sedimentary sequences may have good properties, either as repository rocks, or as cover to a repository.Long time prediction of such favorable properties of a rock at a given site may be best modelled from studies of in situ rock properties. Fracture flow, dispersion history, and geological stability can be derived from direct observations of rocks themselves, and can provide the parameters needed for convincing demonstration of repository security for appropriate times.


HPB Surgery ◽  
2010 ◽  
Vol 2010 ◽  
pp. 1-7 ◽  
Author(s):  
Robert Kleinert ◽  
Roger Wahba ◽  
Christoph Bangard ◽  
Klaus Prenzel ◽  
Arnulf H. Hölscher ◽  
...  

Background. Radiofrequency (RF-) assisted liver resection devices like the Habib sealer induce a necrotic resection plane from which a small margin of necrotic liver tissue remains in situ. The aim of the present paper was to report our long-time experience with the new resection method and the morphological characteristics of the remaining necrotic resection plane. Methods. 64 RF-assisted liver resections were performed using the Habib sealer. Followup was assessed at defined time points. Results. The postoperative mortality was 3,6% and morbidity was 18%. The followup revealed that the necrotic zone was detectable in all analyzed CT and MRI images as a hypodense structure without any contrast enhancement at all time points, irrespectively of the time interval between resection and examination. Conclusion. Liver resection utilizing radiofrequency-induced resection plane coagulation is a safe alternative to the established resection techniques. The residual zone of coagulation necrosis remains basically unchanged during a followup of three years. This has to be kept in mind when evaluating the follow up imaging of these patients.


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